Abstract: The present invention is a cyanato group containing phenolic resin, and method to prepare the resin. The resin of the present invention is stable and has a long shelf life. This is indicated by the gel time of greater than 1 minute, preferably greater than 2 minutes, more preferably greater than 10 minutes. The resin has substantially no smoke generation during gel time measurement at 155.degree. C.
Abstract: The invention provides novel blends and processes for producing such blends which include a polyamide, an olefinic acid copolymer or salt thereof, and a maleated ethylene/propylene rubber, wherein such novel blends may be processed by conventional extrusion and molding techniques, do not require a separate curing step or procedure in the overall production process, and which produces articles which have some physical characteristics similar to those exhibited by thermoplastic elastomers. The inventive compositions exhibit feature excellent resistance to zinc chloride solutions and are formable in a single melt blending step.
Type:
Grant
Filed:
April 15, 1994
Date of Patent:
May 30, 1995
Assignee:
AlliedSignal Inc.
Inventors:
Charles D. Mason, Harold W. Tuller, Thomas J. Krollick
Abstract: Disclosed are compositions and process for the improving the rate or crystallization of polyamide containing compositions which comprise two polyamides having dissimilar melting temperatures, said process comprising the steps of heating the two polyamides to a temperature which is above the melting point of the polyamide having the lower melting temperature but below the melting temperature of the polyamide having the higher melting temperature, as well compositions made in accordance with the process. Preferred polyamides include polycaprolactam and polyhexamethylene adipamide, poly(tetramethylenediamine-co-adipic acid) and further, the inventive compositions may optionally include optional additional constituents. The process provided for improved nucleation without the necessity of inorganic nucleation promoters or agents, and articles made in accordance to the process exhibit good physical properties.
Type:
Grant
Filed:
March 14, 1994
Date of Patent:
May 9, 1995
Assignee:
AlliedSignal Inc.
Inventors:
Charles D. Mason, Nicolas Vanderkooi, Jr.
Abstract: New process for blowing molding polyamide compositions, employing a composition comprising a polyamide and one or more cyanate components, specifically cross-linking cyanates which form a triazine upon curing.
Type:
Grant
Filed:
September 1, 1992
Date of Patent:
April 4, 1995
Assignee:
AlliedSignal Inc.
Inventors:
Yash P. Khanna, Rakesh Kumar, John P. Sibilia
Abstract: Photoinitiators having a terminal fluoroalkyl moiety are useful for photopolymerizing and photocuring fluorinated as well as non-fluorinated monomers, especially fluorinated acrylic monomers.
Abstract: This invention relates to an improved polyester composition that has a wide temperature range of crystallization. The composition comprises a polyester and a chemically reacting crystallization modifier having the following formula:H.sub.2 N--R.sup.1 --O--(R.sup.2 --O).sub.x --R.sup.3 --NH.sub.2whereinR.sup.1 and R.sup.3 are independently selected from the group consisting of alkylene units having from about 2 to about 6 carbon atoms;R.sup.2 is a hydrocarbon radical of 2-6 carbon atoms; andx is from 1 to 100.
Type:
Grant
Filed:
November 23, 1992
Date of Patent:
February 14, 1995
Inventors:
Gerald J. Dege, Murali K. Akkapeddi, Harold W. Tuller, Nicholas Vanderkooi, Jr.
Abstract: A process for forming extended chain polyesters and block or graft polyesters or copolyesters which comprises the steps of (a) forming an intimate mixture of one or more polyesters, and an effective amount of one or more chain extension reagents, which are phosphorous (III)-containing compounds, and (b) heating said mixture for a time and at a temperature sufficient to form said extended chain, or graft or block copolyester or polyester; wherein the polyester used in step (a) contains no or substantially no substances which comprise elements from groups VA and VIA of the periodic table in elemental form; and wherein preferably, said polyesters conatain one or more elements belonging to groups IIA, IIIA, IVA, VB, IIB, IIIB, IVB, VIII and the lanthanides.
Abstract: Disclosed are compositions and process for the improving the rate of crystallization of polyamide containing compositions which comprise two polyamides having dissimilar melting temperatures, said process comprising the steps of heating the two polyamides to a temperature which is above the melting point of the polyamide having the lower melting temperature but below the melting temperature of the polyamide having the higher melting temperature, as well compositions made in accordance with the process. Preferred polyamides include polycaprolactam and polyhexamethylene adipamide, and the said compositions may optionally include further constituents. The process provided for improved nucleation without the necessity of inorganic nucleation promoters or agents, and articles made in accordance to the process exhibit good physical properties.
Type:
Grant
Filed:
March 24, 1994
Date of Patent:
October 25, 1994
Assignee:
AlliedSignal Inc.
Inventors:
Charles D. Mason, Nicholas Vanderkooi, Jr.
Abstract: The invention relates to a process for forming chain extended polymers and graft and block polymers and copolymers which comprises the steps of: (a) forming an intimate mixture of one or more polymers and one or more effective phosphorus (III) chain extension reagent compounds; wherein at least one of said effective chain extension reagents has bonded to the phosphorus (III) atom at least one group which is a nitrogen-containing heteroaromatic moiety that is bonded through a nitrogen of the heteroaromatic moiety to the phosphorus (III) atom by a single bond; and (b) heating said mixture for a time and at a temperature sufficient to form said extended chain polymer or copolymer. Further embodiments relate to polymers and copolymers prepared in accordance with the process of this invention as well as articles formed from these polymers and polymer compositions comprising the polymeric materials of this invention.