Patents Represented by Attorney Nelson Littell, Jr.
  • Patent number: 4803068
    Abstract: Hair-treatment preparations containing as additive at least one surface-active phosphonic acid corresponding to general formula I, II or III below ##STR1## in which R.sup.1 represents a C.sub.5 -C.sub.21 alkyl, R.sup.2 represents hydrogen or --PO.sub.3 H.sub.2, and R.sup.3 represents hydrogen, hydroxyl, or, if R.sup.2 is --PO.sub.3 H.sub.2, --NH.sub.2, and R.sup.4 represents hydrogen or a lower alkyl group containing from 1 to 4 carbon atoms, or a water-soluble salt thereof, improved the wet combability of hair and reduce its tendency to develop static charges. Octane-1-phosphonic acid, decane-1-phosphonic acid and dodecane-1-phosphonic acid or their salts are particularly effective. The phophonic acids are used in quantities of from 0.05 to 10% by weight, and preferably in quantities of from 0.1 to 2.0% by weight together with anionic tensides.
    Type: Grant
    Filed: October 28, 1987
    Date of Patent: February 7, 1989
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Uwe Ploog, Peter Busch, Klaus Thiele, Horst Hoffkes, Karl Giede
  • Patent number: 4755319
    Abstract: A process for the production of solid, pourable, washing or cleaning agents containing surface-active compounds, builders, and calcium binding compounds, said calcium binding compounds consisting of at least one finely-dispersed water-insoluble silicate compound containing at least some combined water and having a calcium binding power of at least 50 mg CaO/gm of anhydrous active substance and the formula on the anhydrous basis:(M.sub.2/n O).sub.x .multidot.Me.sub.2 O.sub.3 .multidot.(SiO.sub.2).sub.ywhere M is a cation of the valence n, exchangeable with calcium, x is a member of from 0.7 to 1.5, Me is a member selected from the group consisting of aluminum and boron, and y is a number form 0.8 to 6, comprising the steps of mixing said silicate compound, while still moist from its production, with at least part of the remaining components of the washing and cleaning agent and converting the entire mixture of components into a pourable product.
    Type: Grant
    Filed: October 29, 1982
    Date of Patent: July 5, 1988
    Assignee: Henkel Kommanditgellschaft auf Aktien
    Inventors: Heinz Smolka, Milan J. Schwuger
  • Patent number: 4680826
    Abstract: A floor wiper formed from two frame portions which are pivotal with respect to each other, and adapted to be locked by magnetic means, having a pedal disposed on one frame portion, and engaging the other, which pedal is adapted to disengage the magnetic locking means.
    Type: Grant
    Filed: April 1, 1985
    Date of Patent: July 21, 1987
    Assignee: Floordress Reinigungsgeraete
    Inventor: Roland Schunter
  • Patent number: 4637746
    Abstract: A dispensing container for multicomponent adhesives and other materials in which correct proportions, amount or ratios of two or more ingredients may be dispensed from a container while keeping the two or more ingredients from mixing together prior to application of the adhesive ingredients to the work to be glued or during closure of the container after application of the adhesive ingredients to the work. The container preferably comprises a hollow right angle prism divided by a slidable, self-supporting partition or partitions parallel to the longitudinal axis of the prism and pistons or plungers attached to the slidable partition or partitions and a slidable lug operating through a slot in the container wall to slide the partition with the attached plungers upwardly or downwardly to push the adhesive ingredients out of the container or return them into the container.
    Type: Grant
    Filed: May 6, 1981
    Date of Patent: January 20, 1987
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventor: Peter Vierkotter
  • Patent number: 4638092
    Abstract: The invention concerns new organo-boron compounds with strong aerobic initiator action to start polymerizations but with improved stability when in contact with atmospheric oxygen. The boron is connected to the molecule predominantly by boron to carbon and optionally boron to hydrogen bonds. The organo-boron compounds are characterized by the fact that the boron containing radicals are connected to an organic polymer matrix that is at least largely nonreactive when exposed to atmospheric oxygen. The boron containing radicals are preferably directly connected to a carbon atom of the polymer matrix by at least one valence of the respective boron atom. The advantageously viscous-fluid to solid masses that are preferably largely free of solvents contain especially hydro-boron radicals and/or organic boron radicals that can have alkyl, cycloalkyl and/or aryl radicals as substituents.
    Type: Grant
    Filed: May 29, 1985
    Date of Patent: January 20, 1987
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventor: Wolfgang Ritter
  • Patent number: 4629477
    Abstract: The invention relates to coagulating compositions for coagulating lacquers, waxes and coating compositions, more especially two-component polyurethane lacquers, which contain a mixture of cyanamide and/or dicyanodiamide and/or calcium cyanamide in an amount of from 1% to 80% by weight in conjunction with substances normally present in coagulating compositions.
    Type: Grant
    Filed: March 28, 1985
    Date of Patent: December 16, 1986
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventor: Juergen Geke
  • Patent number: 4626786
    Abstract: This invention relates to an electrical measuring probe for determining the electrical conductivity of a liquid comprising a measuring zone extending longitudinally through the probe, through which the liquid to be measured flows and to which an electrical current is applied between electrodes, the electrodes having electrical leads remote from the liquid to be measured and those parts of the electrodes remote from the liquid to be measured forming a mechanically stabilizing and electrically conductive insertion or conductor frame of an electrically insulating sleeve which determines the shape of the probe. The insertion frame contains individual conductors in the sleeve distributed axially symmetrically in relation to the longitudinal axis of the probe, and the sleeve is made by injection-molding and consists of a chemically stable thermoplastic.
    Type: Grant
    Filed: November 29, 1983
    Date of Patent: December 2, 1986
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Kay Bodecker, Walter Goth, Robert Scheurl, Hans-Erwin Strasser
  • Patent number: 4624802
    Abstract: The process of scenting, comprising the steps of treating the material to be scented with an application of scenting-effective amount of a scenting agent, the improvement consisting of using a salicylic acid ester having the formula: ##STR1## wherein R is a member having from 5 to 9 carbon atoms selected from the group consisting of cycloalkyl, C.sub.1 -C.sub.4 -alkylcycloalkyl, cycloalkenyl and C.sub.1 -C.sub.4 -alkylcycloalkenyl, and n is an integer from 0 to 3, as said scenting agent; more particularly using cyclohexyl salicylate or cyclopentyl salicylate as said scenting agent; as well as perfumery compositions containing said scenting agents; and salicylic acid ester scenting agents selected from the group consisting of:(a) Cyclopentyl salicylate,(b) 2,2,4-(2,4,4-)trimethylcyclopentyl salicylate in the form of an isomer mixture,(c) 4-isopropylcyclohexyl salicylate,(d) cyclohexylmethyl salicylate,(e) cycloheptyl salicylate(f) cyclooctyl salicylate, and(g) cyclooct-4-enyl salicylate.
    Type: Grant
    Filed: January 2, 1985
    Date of Patent: November 25, 1986
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Ulf-Armin Schaper, Benno Streschnak, Siegfried Bloesl, Walter Sommer
  • Patent number: 4622078
    Abstract: The invention relates to a process for phosphatizing metal surfaces with an acidic phosphatizing solution containing zinc ions, calcium ions, phosphate ions and accelerators and, optionally, other additives, characterized in that, after degreasing and without activation, the metal surfaces are brought into contact at 30.degree. to 65.degree. C. with solutions which contain Zn.sup.2+, Ca.sup.2+, PO.sub.4.sup.3- and, as accelerators, nitrate and/or nitrite and/or chlorate ions and/or an organic nitro compound and/or H.sub.2 O.sub.2 or an inorganic peroxide and which have a pH-value of from 2.2 to 3.8, a ratio of free acid to toal acid of from 1:10 to 1:60 and a ratio by weight of (Ca.sup.2+ +Zn.sup.2+) to PO.sub.4.sup.3- of from 1:>8 to 1:40, and to the use of this process for pretreating the metal surfaces for painting by electrodeposition, particularly by cathodic electrodeposition.
    Type: Grant
    Filed: February 20, 1985
    Date of Patent: November 11, 1986
    Assignee: Gerhard Collardin GmbH
    Inventors: Reinhard Opitz, Manfred Breuer
  • Patent number: 4605563
    Abstract: A synergistic effect on the viscosity behavior of oils is obtained by the addition of a combination of from 0.1% to 10% by weight of a high-melting glyceride of saturated fatty acids (C.sub.14 -C.sub.24) melting above 50.degree. C. (A) and from 0.2% to 10% by weight of a highly dispersed, pyrogenic silica (B), the weight ratio of (A) to (B) amounting to between 20:80 and 80:20. A distinct increase in viscosity may be obtained with relatively small additions of from 0.1% to 1.0% by weight of (A) and from 0.2% to 2% by weight of (B); additions of 1% by weight of (A) and 2% by weight of (B) in a ratio by weight of (A) to (B) of from 25:75 to 50:50 are required to obtain a pasty consistency.
    Type: Grant
    Filed: October 19, 1984
    Date of Patent: August 12, 1986
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Christian Heine, Reinhold Wust
  • Patent number: 4582230
    Abstract: The invention relates to a metering device for insertion into the mouth of a liquid container comprising an elongated cylinder having a cylindrical outlet opening extending beyond the mouth of said liquid container and one or more openings at the other end communicating with the interior of said liquid container, a metering chamber in said elongated cylinder, toward said outlet opening, a ball valve chamber in said elongated cylinder and a ball valve between the interior of the container and the metering chamber. The ball valve consisting of a valve ball and its seat is situated at the inlet opening of the metering chamber on the container side. In order always to obtain the same metered quantity irrespective of the tilting speed and the hydrostatic pressure which is determined by the filling level of the container, the valve ball is connected by a piston rod to a piston mounted for displacement in the cylindrical outlet opening of the metering chamber.
    Type: Grant
    Filed: October 11, 1983
    Date of Patent: April 15, 1986
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventor: Peter Vierkotter
  • Patent number: 4578207
    Abstract: A two component tablet for cleaning and disinfecting toilet flush tanks which adhere to the tank and will not be washed away and/or decomposed comprising extruded component A consisting essentially of (a) 25 to 50% by weight of an alkylbenzene sulfonate, (b) 0 to 40% by weight of inorganic alkali metal salts, (c) 0 to 10% by weight of at least one plasticizer, (d) 5 to 20% by weight of at least one disintegration rate regulator selected from the group consisting of fatty acid ethanolamides, fatty acid diethanolamides and stearic acid, (e) 0 to 50% of a chlorine releasing compound or acid and (f) 0 to 30% by weight of a complexing agent with the sum of (e) and (f) being greater than 5% and component B consisting essentially of (a') 30 to 55% by weight of an alkylbenzene sulfonate (b') 15 to 45% by weight of inorganic alkali metal salts, (c') 0 to 10% by weight of at least one plasticizer, (d') 10 to 15% by weight of at least one disintegration rate regulator selected from the group consisting of fatty acid eth
    Type: Grant
    Filed: December 14, 1983
    Date of Patent: March 25, 1986
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Bernd-Dieter Holdt, Ronald Menke, Gerd Praus, Petra Hasselbach
  • Patent number: 4563398
    Abstract: A blank useful in the production of a tampon for feminine hygiene consist of a length of cottonwool or rayon staple or combination of it strip wrapped in a moisture-pervious, fluff-free covering material. According to the invention, a covering material consisting at least partly of thermoplastic fibers is used and is sealed at its exposed edges to enclose the length of cottonwool strip in a fluffproof form.
    Type: Grant
    Filed: September 27, 1983
    Date of Patent: January 7, 1986
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventor: Scarlet Sustmann
  • Patent number: 4560493
    Abstract: This invention relates to a liquid residue reducing composition. More particularly, this invention relates to a liquid residue reducing composition which comprises an aqueous solution containing an effective amount of octane-1-phosphonic acid or a water-soluble salt thereof and to the method of using said composition.
    Type: Grant
    Filed: December 26, 1984
    Date of Patent: December 24, 1985
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Rolf Scharf, Ferdinand Koch, Hans-Joachim Schlussler
  • Patent number: 4560085
    Abstract: The packaging container consists of a mechanically stabilizing case of paper, cardboard and/or metal with inserted sealing liner, which sealing liner is in the form of a plastic bubble with a neck part shaped from it and extending above the case. Both elements are manufactured separately and coupled together with the aid of an adapter cover. This is lockingly connected with the neck of the sealing liner and adapted to an opening in the case, into which it can lock. It is slipped over the sealing liner preform before the stretching and inflating of the liner and is secured against shifting by means of fixing cams.
    Type: Grant
    Filed: September 19, 1983
    Date of Patent: December 24, 1985
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Dieter vom Hofe, Klaus Meyer
  • Patent number: 4558073
    Abstract: The present invention relates to one component polyurethane foam compositions which comprise mixtures of prepolymers of a polyol and an excess of isocyanate; the usual adjuvants for polyurethane foams, an expanding gas under pressure and a polysiloxane compound with antifoam activity stored in a valved pressure vessel.
    Type: Grant
    Filed: July 25, 1984
    Date of Patent: December 10, 1985
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Hermann Kluth, Jurgen Wegner
  • Patent number: 4552702
    Abstract: Lower alkyl esters of higher fatty acids with improved processing properties, particularly sulfonation, are obtained by subjecting lower alkyl esters of higher fatty acids of plant and/or animal origin, or said fatty acids per se, in the presence of esterification catalysts and/or carboxylic acid anhydrides, to a brief temperature treatment above 150.degree. C., and separating simultaneously and/or subsequently, preferably by distillation, the purified lower alkyl esters of higher fatty acids or the purified higher fatty acids from the treated material and the purified higher fatty acids are then esterified with lower alkanols.
    Type: Grant
    Filed: July 12, 1982
    Date of Patent: November 12, 1985
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Karl Schmid, Horst Baumann
  • Patent number: 4552681
    Abstract: This invention relates to a granular, free-flowing detergent component which dissolves rapidly in water and which has a powder density of from 550 to 900 g/l, consisting of synthetic, essentially nonionic surfactants, inorganic supports, other organic washing aids, and water bound by adsorption and in hydrate form. The detergent component is produced by spray-drying, and more than 50% by weight thereof consists of droplet-like to rodlet-like particles having an average diameter of from about 0.02 to 1.5 mm, an average length of from about 0.1 to 5 mm, and a ratio of average diameter to average length of from about 1:1.2 to 1:10, optionally coated with a finely divided water-soluble or water-dispersible solid material as a fluidity improving agent.
    Type: Grant
    Filed: December 6, 1984
    Date of Patent: November 12, 1985
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Otto Koch, Herbert Reuter, Wolfgang Seiter
  • Patent number: 4551517
    Abstract: The invention relates to two-component polyurethane adhesive preparations in which the resin component is an oleochemical polyol. The oleochemical polyols used are ring-opened products of the reaction of epoxidized fatty alcohols, fatty acid esters (particularly triglycerides) or fatty acid amides with alcohols. The oleochemical polyols may be varied within wide limits in regard to their OH-functionality and so formulated with the hardener polyisocyanate components that the adhesives satisfy the relevant requirements. Reaction products of epoxidized triglycerides with monohydric alcohols are a particularly effective substitute for castor oil.
    Type: Grant
    Filed: December 12, 1984
    Date of Patent: November 5, 1985
    Assignee: Henkel KGaA
    Inventors: Julius Herold, Hermann Kluth, Alfred Meffert, Manfred Leder
  • Patent number: 4548729
    Abstract: Foam-inhibiting compositions for use in an aqueous solution containing polyethylene glycol ethers corresponding to the following formulaR.sup.1 --O--(CH.sub.2 CH.sub.2 O).sub.n --R.sup.2in which R.sup.1 represents a linear or branched alkyl or alkenyl radical containing from 8 to 18 carbon atoms, R.sup.2 represents an alkyl radical containing from 4 to 8 carbon atoms and n is a number of from 7 to 12, mixtures of the same with a polyglycerol polyethylene glycol alkyl ether of 1 part by weight of polyglycerol having a hydroxyl number in the range of from 900 to 1200 adducted with from 4 to 20 parts by weight of ethylene oxide and etherified at the free hydroxyl groups with alkyls having from 4 to 8 carbon atoms, and their use as foam-inhibiting additives for low-foam cleaning agents.
    Type: Grant
    Filed: April 18, 1984
    Date of Patent: October 22, 1985
    Assignee: Henkel KGaA
    Inventors: Karl Schmid, Horst Baumann, Jurgen Geke, Hans-Gunther Germscheid, Werner Ludecke, Robert Piorr, Christian Rossmann, Rolf Scharf, Hans-Joachim Schlussler