Abstract: Uranium di(poly-substituted cyclopentadienyl)-hydride complexes, as well as certain uranium (IV) and rare earth metal complexes, can be employed to catalyze the dimerization of propylene to form selectively 4-methyl-1-pentene.
Abstract: Compositions useful as corrosion inhibitors for high density brines at high temperatures comprise phosphonium salts, such as triphenyldocosyl phosphonium chloride.
Type:
Grant
Filed:
October 3, 1983
Date of Patent:
February 3, 1987
Assignee:
The Dow Chemical Company
Inventors:
Mark E. Soderquist, Ramaiah Muthyala, William A. Larson, Peter A. Doty
Abstract: Hydroxyaromatic compounds are amido-alkylated or cyano-alkylated to form the corresponding compounds by:(a) heating said compounds with an alkylating agent in the presence of water and a catalyst, e.g., benzyltrimethylammonium chloride;(b) adding an alkaline agent, e.g., NaOH, to the heated mixture of (a); and(c) continuing to heat the resulting mixture until the corresponding amido- or cyano-alkylated compound is formed.Fully or partially amido-alkylated compositions are useful in the preparation of copolymers with epoxy resins.
Abstract: Thermotropic polymers containing ester linkages and having liquid crystalline properties in the molten state are prepared with certain aromatic diols, such as tetramethyl dihydroxy biphenyls having halogen substituents meta to the oxygen atoms.
Abstract: An isomeric mixture of C- and O-allylated aromatic compounds is prepared by contacting an allyl halide, a hydroxyaromatic reactant, an alkaline agent, water and a quaternary salt catalyst. This mixture may be thermally isomerized to obtain the C-allylated compounds in high yield.
Abstract: Selectively produce methane under Fischer-Tropsch conditions using a catalyst consisting essentially of ruthenium supported on an oxide of tantalum, niobium, vanadium or mixtures thereof, the support preparation including calcination at a temperature such that essentially no crystalline metal oxide is detectable by X-ray diffraction prior to deposition of the catalytic metal.
Abstract: Prepare p-isopropenyl phenol and other alkenyl aromatic compounds by contacting a dihydroxydiphenyl alkane or a related substituted diaromatic alkane with an alkaline catalyst and at least one gas under supercritical conditions such that p-isopropenyl phenol or the corresponding related alkenyl aromatic compound is produced.
Abstract: A catalyst composition comprising a catalytic metal and a support, the support being prepared by depositing a metal alkoxide salt on a core support, then calcining the support.
Type:
Grant
Filed:
September 28, 1984
Date of Patent:
December 17, 1985
Assignee:
The Dow Chemical Company
Inventors:
Clayton D. Wood, Philip E. Garrou, Iwao Kohatsu, Edward F. Gleason
Abstract: Prepare 4-amino-1,3-dicyano-2-methyl-1,3-pentadiene and related substituted aminodienes by contacting .beta.-aminocrotononitrile and related substituted aminoalkenes with a base acceptor in a solvent under mild conditions.
Abstract: A novel imidazolinium salt is prepared by (1) reacting N-aminoalkyl-imidazoline, N-hydroxyalkyl-imidazoline, or N-substituted-imidazoline with an .alpha.,.beta.-unsaturated ester of a carboxylic acid, (2) reacting the resulting ester imidazoline with a primary or secondary amine and (3) quaternizing the resulting amido imidazoline product by reacting it with an alkylating agent. This imidazolinium salt is useful as a fabric softening agent.
Abstract: Photocurable compositions containing a polyethylenically unsaturated resin compound and a monoethylenically unsaturated diluent are cured to form compositions containing essentially no polymerizable ethylenically unsaturated compounds by:(a) admixing with the composition at least about 0.1 weight percent, based upon the weight of the composition, of an electron-rich, aromatic promoter; and(b) exposing the admixture of (a) to a sufficient amount of radiant energy to essentially completely polymerize the ethylenically unsaturated components of the composition.For example, a composition consisting of the diacrylate of a bisphenol A and epichlorohydrin condensation adduct in a dicyclopentadiene acrylate diluent is vinyl polymerized in the presence of 1,4-dimethoxybenzene with electromagnetic radiation such that less than 0.2 percent unreacted dicyclopentadiene acrylate monomer is present in the resulting cured composition.