Patents Represented by Attorney Philip P. McCann
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Patent number: 5195245Abstract: Synthetic fiber safety cutting scissors comprising a pair of first and second elongated scissor blades, each having an inner side and an outer side and a plurality of cutting edges separated by a plurality of non-cutting protrusions, and a gripping means; and a means for pivotally securing said first and second scissor blades to each other with said inner sides facing towards each other such that the said cutting edges cooperate with each other to cut strands of synthetic fiber. It has been found that with the protrusions that foreign objects such as fingers may be prevented from being intersected at the cutting edge.Type: GrantFiled: October 28, 1992Date of Patent: March 23, 1993Assignee: Hoechst Celanese CorporationInventor: Jason R. Malone
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Patent number: 5188456Abstract: The invention provides a fiber testing device for thermomechanical testing of fibers which preferably includes a linear step motor coupled to a first fiber gripping jaw. A second fiber gripping jaw is positioned in linear relation to the first gripping jaw and is coupled to a load cell. Advantageously, the apparatus includes a chamber for maintaining a fiber test specimen in a substantially thermally isolated environment during testing of the fiber. A heating means and a cooling means are connected to the chamber. The heating means and cooling means are controlled by a control means which also controls the position of the linear step motor. The fiber testing device of the invention is capable of performing complicated mechanical and thermal fiber testing protocals without operator involvement except for initiation of the testing sequence.Type: GrantFiled: November 29, 1991Date of Patent: February 23, 1993Assignee: Hoechst Celanese CorporationInventors: Richard A. Burke, James R. Goodall, Michael D. Melton, Roy S. Osborne, Carl D. Patterson
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Patent number: 5180793Abstract: The invention is a polyester and a method for producing a polyester filament which has a combination of flame resistance and low pilling properties. The method comprises forming a polyester polymer from a mixture of two polymers, the first compound being the reaction product of terephthalic acid or dimethyl terephthalate, ethylene glycol, and an oxysilicon compound and the second compound being the reaction product of terephthalic acid or dimethyl terephthalate, ethylene glycol and a phosphinic acid in the amount between 0.5 and 20 mole percent of the terephthalate acid and monomer. In particular, the invention also comprises the enhanced fiber formed by the process, as well as the fabrics having a pilling of about 3 to less than 5 as measured in accordance with ASTM D-3512-82.Type: GrantFiled: December 31, 1991Date of Patent: January 19, 1993Assignee: Hoechst Celanese CorporationInventors: Richard E. Vigneault, William S. Wagner, Klaus Weisskopf, R. Edward Williamson, A. John Woodward
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Patent number: 5167764Abstract: A bonded fibrous wet laid web containing cellulose acetate fibers, a bicomponent fiber including a polyester or polyamide fiber member and a second member having a melting point 20.degree. C. below that of the first member and an aqueous based organic solvent which solubilizes the surface of the cellulose acetate fibers to permit bonding of said cellulose acetate fibers.Type: GrantFiled: December 23, 1991Date of Patent: December 1, 1992Assignee: Hoechst Celanese CorporationInventors: Steven F. Nielsen, Cheryl E. Johnson
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Patent number: 5167765Abstract: A thermally bonded fibrous wet laid web containing a bicomponent fiber including a polyester or polyamide fiber component and a component consisting of a linear low density polyethylene having a density in the range of 0.88 to 0.945 g/cc. A grafted HDPE can be added to the LLDPE to improve adhesion of the bicomponent fiber. The bonded fibrous wet laid web may further include a matrix fiber selected from the group consisting of cellulose paper making fibers, cellulose acetate fibers, glass fibers, polyester fibers, ceramic fibers, mineral wool fibers, polyamide fibers, and other naturally occurring fibres. It has been found that a thermally nonwoven fibrous web made using the foregoing ingredients has improved and unexpected strength, lower web variability and is softer.Type: GrantFiled: July 2, 1990Date of Patent: December 1, 1992Assignee: Hoechst Celanese CorporationInventors: Steven F. Nielsen, Barrie L. Davies
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Patent number: 5162153Abstract: Poly(butylene terephthalate) copolyester advantageous of use as sheath materials in bicomponent fibers are prepared by a process for preparing a high-molecular weight, linear copolyester by condensing 40-85 molar percent of terephthalic acid optionally in the form of a dialkyl ester, half of which component can optionally be replaced by another dicarboxylic acid also optionally in the dialkyl ester form, and 60-15 molar percent of a blend of dimethyl adipate, dimethyl glutarate and dimethyl succinate with an alkanediol of 2-6 carbon atoms in its carbon chain, at an elevated temperature in the presence of a conventional catalyst, in a first condensation stage which is an interesterification or esterification stage and a second condensation stage which is polycondensation stage, whereby a copolyester melt is produce. The process comprises, before or during the first condensation stage, adding 0.005-0.1 molar percent, based on the total acid component, of a C.sub.6 -aryl or C.sub.Type: GrantFiled: May 4, 1992Date of Patent: November 10, 1992Assignee: Hoechst Celanese CorporationInventors: A. Wayne Cooke, Barrie L. Davies
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Patent number: 5158651Abstract: A process for removing inorganic compounds from glycol recovery still bottoms resulting from the manufacture of poly(ethylene terephthalate), the novel process using a small amount of phosphoric acid to precipitate the antimony and then removing the titanium dioxide and antimony compound by a centrifuge. The novel process for removing the inorganic compounds from the recovery polyester bottoms includes the steps of distilling ethylene glycol from the spent glycol until the remaining bottoms have a solids concentration from about 15% to about 45%; adding phosphoric acid to the bottoms to form an antimony compound and removing the antimony and titanium precipitates from the bottoms by a centrifuge.Type: GrantFiled: June 11, 1990Date of Patent: October 27, 1992Assignee: Hoechst Celanese CorporationInventor: Marvin L. Doerr
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Patent number: 5151494Abstract: The invention is a polyester and a method for producing a polyester filament which has a combination of flame resistance and low pilling properties. The method comprises forming a polyester polymer from a mixture consisting essentially of terephthalate acid or dimethyl terephthalate, ethylene glycol, a chain branching agent having a functionality of at least 3 and a phosphinic acid in the amount between 0.5 and 20 mole percent of the terephthalate acid and monomer. In particular, the invention also comprises the enhanced fiber formed by the process, as well as the fabrics having a pilling of about 3 to less than 5 as measured in accordance with ASTM D-3512-82.Type: GrantFiled: January 4, 1991Date of Patent: September 29, 1992Assignee: Hoechst Celanese CorporationInventors: Jerry T. Munday, Theodore D. Meiss
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Patent number: 5145941Abstract: The invention is a polyester and a method for producing a polyester fiber which has a combination of flame resistance and low pilling properties. The method comprises forming a polyester fiber made from a blend of two polyester polymers, one polyester polymer containing an oxysilicon compound and the second polyester polymer containing pentaerythritol and a phosphinic acid in the amount between 0.5 and 20 mole percent of the terephthalate acid and monomer. In particular, the invention also comprises the enhanced fiber formed by the process, as well as the fabrics having a pilling of about 3 to less than 5 as measured in accordance with ASTM D-3512-82.Type: GrantFiled: November 22, 1991Date of Patent: September 8, 1992Assignee: Hoechst Celanese CorporationInventors: Jerry T. Munday, Theodore D. Meiss
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Patent number: 5135697Abstract: The invention is a method of producing a polyester filament which has a superior combination of tensile, dyeability and shrinkage properties. The method comprises forming a polyester copolymer from a mixture consisting essentially of terephthalic acid (TA) or dimethyl terephthalate (DMT), ethylene glycol, adipic acid, and pentaerythritol wherein the adipic acid is added in an amount of between 1.3 and 3.2 weight percent of the terephthalic acid and pentaerythritol is added in the amount from 175 to 700 ppm by weight of terephthatlic acid; forming the filament from the copolymer, drawing the copolymer filament, and heat-setting the drawn filament. The invention also comprises the enhanced fiber formed by the process having an atmospheric dyeability greater than that of an unenhanced PET produced under identical conditions except for the addition of the adipic acid and pentaerythritol, a modulus of greater than 3.0 g/denier, a tenacity from about 5 to 7 g/denier and a hot air shrinkage of less than 10%.Type: GrantFiled: August 28, 1990Date of Patent: August 4, 1992Assignee: Hoescht Celanese CorporationInventors: Joseph A. Roderiguez, Theodore D. Meiss
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Patent number: 5134222Abstract: Poly(butylene terephthalate) copolyester advantageous of use as sheath materials in bicomponent fibers are prepared by a process for preparing a high-molecular weight, linear copolyester by condensing 40-85 molar percent of terephthalic acid optionally in the form of a dialkyl ester, half of which component can optionally be replaced by another dicarboxylic acid also optionally in the dialkyl ester form, and 60-15 molar percent of a blend of dimethyl adipate, dimethyl glutarate and dimethyl succinate with an alkanediol of 2-6 carbon atoms in its carbon chain, at an elevated temperature in the presence of a conventional catalyst, in a first condensation stage which is an interesterification or esterification stage and a second condensation stage which is a polycondensation stage, whereby a copolyester melt is produce. The process comprises, before or during the first condensation stage, adding 0.005-0.1 molar percent, based on the total acid component, of a C.sub.6 -aryl or C.sub.Type: GrantFiled: December 23, 1991Date of Patent: July 28, 1992Assignee: Hoechst Celanese CorporationInventors: A. Wayne Cooke, Barrie L. Davies
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Patent number: 5102713Abstract: A blend of low shrinkage polyester fibers and high shrinkage polyester fibers is described. In particular, the blend includes high shrinkage PET copolymers having boiling water shrinkages from 6 to 11 percent and low shrinkage PET copolymer fibers having a shrinkage of less than 3 percent. Saxony carpets made from the blend consistently have better initial tuft end point definition and, in most cases, better bulk than corresponding saxony polyester carpets made from conventional polyester fibers.Type: GrantFiled: September 5, 1990Date of Patent: April 7, 1992Assignee: Hoechst Celanese CorporationInventors: James A. Corbin, Allen J. Hopkins, Michael C. Whited
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Patent number: 5082731Abstract: A process for producing a copolyester by copolymerizing the monomers from the ester interchange of a lower dialkyl ester of terephthalic acid and glycol and the direct esterification of a dicarboxylic acid and glycol using a novel catalyst system. The novel catalyst composition includes from about 20 ppm to about 150 ppm manganese; from about 50 ppm to about 350 ppm lithium; preferably from about 10 ppm to about 70 ppm cobalt; and from about 200 ppm to about 400 ppm antimony, all amounts being based upon the expected yield of the copolyester.Type: GrantFiled: January 24, 1991Date of Patent: January 21, 1992Assignee: Hoechst Celanese CorporationInventors: Anthony W. Cooke, Monika E. Bader
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Patent number: 5030515Abstract: A method for bonding a rubber substrate to a metal substrate wherein a primer composition is first applied to the surface of said metal substrate and the rubber substrate is then bonded to the primer composition-containing metal substrate surface using a rubber-to-metal bonding adhesive, the improvement comprising employing as the primer composition a mixture comprising an epoxidized diene polymer having a molecular weight of about 500 to 30,000 and a resole type phenolic resin, in a weight ratio of about 2 to 100 parts of said diene polymer per 100 parts of said resole type phenolic resin.Type: GrantFiled: January 16, 1990Date of Patent: July 9, 1991Assignee: Lord CorporationInventors: Hiroyoshi Ozawa, Masazumi Izawa, Akihiko Kasuya
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Patent number: 5025538Abstract: An apparatus for crimping a continuous tow of textile material including a pair of molding rollers for initial molding and pulling of the tow, a pair of crimping rollers for molding and feeding the two to a stuffer box crimper wherein the tow is crimped. The novel pair of molding rollers includes the two spaced rotatable rollers cooperating with a side plate at each end of the nip between the rollers to define a rectangular space. Tow material is passed through the space wherein the tow is pressed and molded to the rectangular configuration. After the initial molding, the tow is passed through the pair of crimping rollers and fed into the stuffer box wherein the tow is crimped. Using the novel apparatus to crimp the tow drastically improves the uniformity of the crimped tow and the processibility or the tow. Furthermore, the novel apparatus allows for a significant reduction in the forces applied to the molding rollers and crimping rollers resulting in the reduction of filament distortion in the tow material.Type: GrantFiled: March 30, 1990Date of Patent: June 25, 1991Assignee: Hoechst Celanese CorporationInventor: Lotfy L. Saleh
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Patent number: 5019449Abstract: A spinneret having octagonally-shaped orifices for producing yarn filaments having a characteristic cross-section and improved cross-sectional fidelity. The filament cross-section is characterized by generally symmetrical rectangular sub-sections each having four lobes and joined one to the other by a central bridging portion connecting the short facing sides of the sub-sections. This cross-section has increased surface area and remains substantially constant throughout the length of the filament whereby reduced air pressure is required when using the filament in air jet looms.Type: GrantFiled: March 10, 1987Date of Patent: May 28, 1991Assignee: Celanese Fibers, Inc.Inventors: Wade J. Truesdale, Bryan B. Moore, Greg F. Benjock
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Patent number: 4990594Abstract: A process for producing a copolyester by copolymerizing the monomers from the ester interchange of a lower dialkyl ester of terephthalic acid and glycol and the direct esterification of a dicarboxylic acid and glycol using a novel catalyst system. The novel catalyst composition includes from about 20 ppm to about 150 ppm manganese; from about 50 ppm to about 350 ppm lithium; preferably from about 10 ppm to about 70 ppm cobalt; and from about 200 ppm to about 400 ppm antimony, all amounts being based upon the expected yield of the copolyester.Type: GrantFiled: March 7, 1990Date of Patent: February 5, 1991Assignee: Hoechst Celanese CorporationInventors: Anthony W. Cooke, Monika E. Bader
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Patent number: 4968286Abstract: A lightweight, flexible coupling suitable for transmitting torque and accommodating axial and angular misalignment between drive and driven members. The coupling includes at least one reinforcing rim disposed between a pair of hubs having a plurality of projecting pins about which are secured filaments that are coated with a flexible matrix material. The filaments are geodesically wrapped from the hub one side of the reinforcing ring and then to the hub on the opposite side of the reinforcing ring. The driven and driven members are respectively attached to the projecting pins.Type: GrantFiled: March 3, 1988Date of Patent: November 6, 1990Assignee: Lord CorporationInventor: Dennis P. McGuire
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Patent number: 4964623Abstract: A fluid filled resilient bushing assembly for vibration control in the radial and axial directions or combinations thereof, particularly adapted for use in a suspension system, which comprises an elongate inner rigid member and an elongate outer rigid sleeve member, a resilient member interposed between the inner and outer members. The resilient member together with the outer member defines two circumferentially and axially-spaced chambers and a restricted passageway connecting the chambers. The chambers and passageway contain an incompressible fluid. By axially and circumferentially spacing the chambers, the desired damping in the axial and radial direction is obtained.Type: GrantFiled: December 7, 1987Date of Patent: October 23, 1990Assignee: Lord CorporationInventor: Richard P. Thorn
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Patent number: 4914149Abstract: A coating composition comprising about 50 to 30% by weight of a blocked isocyanate-functional urethane prepolymer, 2 to 25% by weight of at least one organic solvent-soluble phenolic resin, 0.5 to 18% by weight of a halogenated resin selected from the group consisting of halogenated rubber, halogenated polyolefins and halogenated vinyl halide polymers and an inert solvent in an amount sufficient to provide an adhesive primer having a solid content of 10 to 70% by weight.Type: GrantFiled: August 15, 1988Date of Patent: April 3, 1990Assignee: Lord CorporationInventors: Kenneth E. Fleming, Douglas H. Mowrey