Patents Represented by Attorney Raymond W. Barclay
  • Patent number: 4177192
    Abstract: Succinimides of aminoaryl sulfonic acid salts provide exceptional detergency, viscosity control and anticorrosion properties to lubricants and greases and to other fluid compositions useful in hydraulic systems. Ammonium, alkylammonium, alkali metal, alkaline earth metal and groups IB, IIB, VIB, VIIB, VIII metal salts of aminoaryl sulfonic acid salts, and the salts of sulfanilic acid in particular, can be reacted with alkenyl or alkylsuccinic anhydride, acid or ester, in which the alkenyl or alkyl group may contain from 8 to about 500 carbon atoms, to yield the products of this invention. These products are understood to be novel. Suitable modifications of the aforementioned are the succinimides of di(aminoaryl sulfonic acid) salts, aniline disulfonic acid salts and corresponding aminonaphthalene sulfonate salts which are also useful in the compositions of this invention.
    Type: Grant
    Filed: April 22, 1977
    Date of Patent: December 4, 1979
    Assignee: Mobil Oil Corporation
    Inventors: El-Ahmadi I. Heiba, Robert E. Kinney, George E. Stead
  • Patent number: 4177163
    Abstract: Novel catalyst support, catalyst and process for hydrodemetalizing sulfur and metal-contaminated hydrocarbon oils such as residual petroleum fractions or whole crudes. The process may be used to prepare feedstocks suitable for fluid catalytic cracking. The novel catalyst support is alumina modified with rare earth oxide.
    Type: Grant
    Filed: March 8, 1978
    Date of Patent: December 4, 1979
    Assignee: Mobil Oil Corporation
    Inventors: Stephen M. Oleck, Howard S. Sherry
  • Patent number: 4177079
    Abstract: Asphaltic compositions comprising waste material are obtained by heating a mixture of solid organic waste, sulfur, and a liquefaction solvent to a temperature of 300.degree. F. to 1000.degree. F. to provide asphaltic pitch-like compositions which are useful as paving binders and coating compositions. The method for producing paving compositions is compatible with current petroleum refining technology and affords a low-cost method of waste disposal.
    Type: Grant
    Filed: April 20, 1978
    Date of Patent: December 4, 1979
    Assignee: Mobil Oil Corporation
    Inventor: Wilton F. Espenscheid
  • Patent number: 4175944
    Abstract: The invention provides a novel process for the removal of fluorine during the production of fertilizer by precipitating the ion during the ammoniation step and recovering same by pyrolysis.To recover the fluorine the fertilizer is first separated out as a filtrate and the precipitate is heated to evolve ammonium fluoride, which heating is done in an ammonia atmosphere.
    Type: Grant
    Filed: June 26, 1978
    Date of Patent: November 27, 1979
    Assignee: Mobil Oil Corporation
    Inventor: George C. Johnson
  • Patent number: 4176083
    Abstract: A stripper arrangement is provided in a regenerated catalyst standpipe for removing or displacing combustion flue gas products with fuel gas products of hydrocarbon conversion freed of hydrogen sulfide.
    Type: Grant
    Filed: August 25, 1978
    Date of Patent: November 27, 1979
    Assignee: Mobil Oil Corporation
    Inventors: Stephen J. McGovern, Klaus W. Schatz, Fred S. Zrinscak, Sr.
  • Patent number: 4176161
    Abstract: Oxidation of suitable feedstock is provided wherein such feedstock is subjected to oxidation conditions in the presence of a catalytic amount of a solid containing, at least in part, a synthetic amorphous solid prepared by hydrolyzing and polymerizing in the presence of water a silane having the formula R(Si)X.sub.3, wherein R is a non-hydrolyzable organic group, X is a hydrolyzable group and (Si) is selected from the group consisting of ##STR1## and ##STR2## and calcining the polymerized product, said silane being admixed with a second compound, R'.sub.n MY.sub.m, wherein R' is selected from the group consisting of the same groups as R, Y is selected from the group consisting of the same groups as X and oxygen, M is at least one member selected from the group consisting of elements of Groups IIIA, IVA, IVB, VA, VB, VIB, VIIB and VIII of the Periodic Table, m is any number greater than 0 and up to 8 and n is from 0 to any number less than 8.
    Type: Grant
    Filed: February 10, 1978
    Date of Patent: November 27, 1979
    Assignee: Mobil Oil Corporation
    Inventors: Thomas O. Mitchell, Darrell D. Whitehurst
  • Patent number: 4175043
    Abstract: A novel product formed by forming the metal salt of the product of reaction between a dialkyl or diaryl phosphorodithioic acid and a sulfurized olefin possesses among other things, good antiwear and antioxidant activity. Organic compositions containing a minor amount thereof also possess good lubricating characteristics.
    Type: Grant
    Filed: September 21, 1978
    Date of Patent: November 20, 1979
    Assignee: Mobil Oil Corporation
    Inventor: Andrew G. Horodysky
  • Patent number: 4175211
    Abstract: A process for converting relatively ash-free solid polymeric wastes to more valuable liquid, solid, and gaseous products which comprises mixing rubber and/or plastic wastes at high temperatures in a refractory petroleum stream and catalytically cracking the mixture.
    Type: Grant
    Filed: March 1, 1978
    Date of Patent: November 20, 1979
    Assignee: Mobil Oil Corporation
    Inventors: Nai Y. Chen, Tsoung-Yuan Yan
  • Patent number: 4175114
    Abstract: As synthesized by previous methods, ZSM-5 or ZSM-11 zeolites are crystallized in the presence of substantial amounts of a nitrogen-containing compound. When synthesized in this way, they contain an organic ammonium cation as well as a metal cation such as sodium. To obtain a more active form, the sodium ion must be exchanged out. Such exchange, especially with ZSM-5 and ZSM-11, is difficult unless there is calcination of the zeolite to remove the obstructing organo compounds. By making these zeolites in the presence of (1) seeds of the desired zeolite, (2) mixtures of them with ammonium hydroxide and/or alcohol, (3) the alcohol per se or (4) mixtures of the alcohol with ammonium hydroxide, a product substantially deficient in organic ammonium cation is obtained. These products can be exchanged directly without any calcination.
    Type: Grant
    Filed: October 13, 1977
    Date of Patent: November 20, 1979
    Assignee: Mobil Oil Corporation
    Inventors: Charles J. Plank, Edward J. Rosinski, Mae K. Rubin
  • Patent number: 4175047
    Abstract: Synthetic esters or mixtures thereof, containing a free hydroxyl group in the molecule, are useful as lubricants for internal combustion engines, preferably in combination with synthetic hydrocarbon fluids. The composition, when used to lubricate an internal combustion engine, reduces the fuel consumed by such engine.
    Type: Grant
    Filed: September 25, 1978
    Date of Patent: November 20, 1979
    Assignee: Mobil Oil Corporation
    Inventors: John W. Schick, Joan M. Kaminski
  • Patent number: 4175046
    Abstract: A synthetic lubricating composition is provided comprising a major proportion of a base oil and a minor proportion of a plurality of additives, added for the purpose of substantially improving properties of such composition other than viscosity index. The base oil comprises (1) a mixture of at least two fatty acid esters of specified characteristics with regard to viscosity and (2) a hydrogenated oligomer of an alpha olefin of 6 to 12 carbon atoms. The resulting blend of base oil and additives has a viscosity index which differs from that of the base oil by no more than 20.
    Type: Grant
    Filed: September 20, 1978
    Date of Patent: November 20, 1979
    Assignee: Mobil Oil Corporation
    Inventors: Pierre M. Coant, George W. Munns, Jr.
  • Patent number: 4174356
    Abstract: Hydrogenation-dehydrogenation of suitable feedstock is provided wherein such feedstock is subjected to hydrogenation-dehydrogenation conditions in the presence of a catalytic amount of a solid containing, at least in part, a synthetic amorphous solid prepared by hydrolyzing and polymerizing in the presence of water a silane having the formula R(Si)X.sub.3, wherein R is a nonhydrolyzable organic group, X is a hydrolyzable group and (Si) is selected from the group consisting of ##STR1## and calcining the polymerized product, said silane being admixed with a second compound, R'.sub.n MY.sub.m, wherein R' is selected from the group consisting of the same groups as R, Y is selected from the group consisting of the same groups as X and oxygen, M is at least one member selected from the group consisting of the elements of Groups IIIA, IVA, VA, IVB, VB, VIB, VIIB and VIII of the Periodic Table, m is any number greater than 0 and up to 8 and n is from 0 to any number less than 8.
    Type: Grant
    Filed: February 10, 1978
    Date of Patent: November 13, 1979
    Assignee: Mobil Oil Corporation
    Inventors: Thomas O. Mitchell, Darrell D. Whitehurst
  • Patent number: 4174285
    Abstract: Lubricant compositions containing oleaginous materials and, in amounts sufficient to impart antioxidation properties thereto, additives selected from the group consisting of ethers and esters of 1-hydroxybenzotriazole.
    Type: Grant
    Filed: September 5, 1978
    Date of Patent: November 13, 1979
    Assignee: Mobil Oil Corporation
    Inventor: Milton Braid
  • Patent number: 4172843
    Abstract: An improved method is disclosed for converting synthesis gas to hydrocarbon mixtures wherein the syngas is contacted with a special catalyst comprising a crystalline zeolite having a silica-to-alumina ratio of greater than 200 (including zeolites containing essentially no alumina) and an (R.sub.2 O+ M.sub.2 /.sub.n O): SiO.sub.2 ratio of less than 1.1:1 where M is a metal other than a metal of Group IIIA, n is the valence of said metal, and R is an alkyl ammonium radical, said organosilicate being characterized by a specified x-ray diffraction pattern. In a specific embodiment of this invention, synthesis gas is contacted with a catalyst comprising an intimate mixture of said crystalline zeolite catalyst and iron-containing, Fischer-Tropsch catalyst to produce a liquid hydrocarbon product having a boiling range of less than 400.degree. F.
    Type: Grant
    Filed: July 21, 1978
    Date of Patent: October 30, 1979
    Assignee: Mobil Oil Corporation
    Inventors: Francis G. Dwyer, William E. Garwood
  • Patent number: 4171260
    Abstract: This invention provides a method for reducing the level of thiophenic sulfur compounds in a heavy carbonaceous oil feed which involves contacting the oil feed with a C.sub.1 -C.sub.4 alkanol in the presence of a non-acidic zeolite catalyst.The reaction equilibrium in the process favors the displacement of thiophene sulfur atoms by oxygen atoms.
    Type: Grant
    Filed: August 28, 1978
    Date of Patent: October 16, 1979
    Assignee: Mobil Oil Corporation
    Inventors: Malvina Farcasiu, Eric J. Y. Scott
  • Patent number: 4167486
    Abstract: Lubricating oils containing olefin polymerizable acid esters and dimers and/or trimers thereof have been found to increase fuel economy in internal combustion engines. This is done by deposition of the additive on the lubricated surface.
    Type: Grant
    Filed: July 20, 1978
    Date of Patent: September 11, 1979
    Assignee: Mobil Oil Corporation
    Inventor: Carleton N. Rowe
  • Patent number: 4163028
    Abstract: Isomerization of xylenes in admixture with ethyl benzene by contact with a zeolite catalyst such as ZSM-5 is improved by use of zeolite having a silica/alumina ratio of at least 500 at a temperature above about 800.degree. F. At these conditions, conversion of ethyl benzene follows a different reaction path which permits high conversion of ethyl benzene to benzene without loss of xylenes by disproportionation.
    Type: Grant
    Filed: June 5, 1978
    Date of Patent: July 31, 1979
    Assignee: Mobil Oil Corporation
    Inventors: Samuel A. Tabak, Roger A. Morrison
  • Patent number: 4162225
    Abstract: Lubricant compositions containing oleaginous materials and, in amounts sufficient to impart resistance to oxidation thereto, adducts of benzotriazole compounds and substituted acrylonitrile.
    Type: Grant
    Filed: April 17, 1978
    Date of Patent: July 24, 1979
    Assignee: Mobil Oil Corporation
    Inventor: Milton Braid
  • Patent number: 4162224
    Abstract: Novel oil-soluble compounds and lubricating compositions containing them are provided containing an antiwear or antioxidant improving amount of a solubilized borate of a bis-oxazoline resulting from reaction of an alkyloxazoline, boric acid and a substituted phenol.
    Type: Grant
    Filed: January 28, 1977
    Date of Patent: July 24, 1979
    Assignee: Mobil Oil Corporation
    Inventor: Robert F. Bridger
  • Patent number: RE30157
    Abstract: Mixtures of C.sub.8 aromatic hydrocarbons are contacted in vapor phase with acid zeolite ZSM-5. The xylene content is thereby isomerized and the ethyl benzene content of the charge is converted in a manner which results in net increase of aromatic rings.
    Type: Grant
    Filed: December 19, 1977
    Date of Patent: November 20, 1979
    Assignee: Mobil Oil Corporation
    Inventor: George T. Burress