Abstract: The invention relates to novel urease inhibited fertilizer compositions containing urea and a urease inhibiting amount of one or more phosphoric triamide compounds, and methods and composition for inhibiting the urease catalyzed hydrolysis of urea through use of such compounds.
Type:
Grant
Filed:
January 16, 1984
Date of Patent:
July 23, 1985
Assignee:
Allied Corporation
Inventors:
Jaroslav F. Kolc, Michael D. Swerdloff, Milorad M. Rogic, Larry L. Hendrickson, Michael Van Der Puy
Abstract: Batteries wherein at least one of the anode and cathode is a conjugated backbone polymer and in which the electrolyte contains at least one sultone or sulfonate solvent. Preferred solvents such as propane sultone and butane sultone impart stability to the battery and permit the polymer, such as polyacetylene, to be highly oxidized or reduced without degradation.
Type:
Grant
Filed:
November 30, 1983
Date of Patent:
July 9, 1985
Assignee:
Allied Corporation
Inventors:
James F. Wolf, Suzanne M. Savner, MacRae Maxfield, Lawrence W. Shacklette
Abstract: This invention relates to a process for conditioning the surfaces of natural and synthetic plastic materials for electroless plating of a metal coating thereon by exposing such materials to an atmosphere comprising ozone, contacting said exposed materials with a conditioning solvent, such as an aqueous solution of sodium, potassium or lithium hydroxide, and thereafter rinsing said contacted materials with an aqueous solution of one or more surfactants.
Abstract: A process of preparing chromium (III) compounds from chromate and/or dichromate salts by forming a mixture of such salts, an acid, water and a reducing agent. Additional acid is added to the mixture which is then cooled selectively precipitating the salt of the anion of the acid and the cation of the chromate and/or dichromate salts which is separated from the solution containing the desired chromium (III) compound.
Abstract: The invention relates to novel urease inhibited fertilizer compositions containing urea and a urease inhibiting amount of hydroxamic acid or diaminophosphinyl compounds, and methods and composition for inhibiting the activity of urease through use of such compounds.
Type:
Grant
Filed:
June 16, 1983
Date of Patent:
July 9, 1985
Assignee:
Allied Corporation
Inventors:
Jaroslav F. Kolc, Michael D. Swerdloff, Milorad M. Rogic, Larry L. Hendrickson
Abstract: Novel catalytic electrode in which the oxidation catalyst is protected from unfavorable redox potentials by an insulation/rectification matrix composed of a polymeric matrix containing an insulating and rectifying effective amount of a dispersed redox conductor.
Type:
Grant
Filed:
July 5, 1983
Date of Patent:
June 18, 1985
Assignee:
Allied Corporation
Inventors:
George J. Samuels, Thomas A. Schmitkons, Terry L. Streeter, Royce W. Murray
Abstract: This invention relates to novel fluorinated compounds derived from 3,3',4,4'-benzophenone tetracarboxylic dianhydride that are useful as surface modifiers for various fibers. The novel compounds contain two fluorinated ester derived from fluorinated alcohols and two esters derived from oxirane compounds.
Abstract: The invention relates to novel urease inhibited fertilizer compositions containing urea and a urease inhibiting amount of novel poly-phosphorodiamide compounds.
Type:
Grant
Filed:
June 6, 1983
Date of Patent:
May 21, 1985
Assignee:
Allied Corporation
Inventors:
Michael D. Swerdloff, Jaroslav F. Kolc, Milorad M. Rogic, Larry L. Hendrickson
Abstract: Novel urease inhibiting aminophenol compounds and urea based fertilizer compositions including such compounds, and methods and compositions for inhibiting the activity of urease through use of a urease inhibiting effective amount of one or more of the aforementioned aminophenol compounds.
Type:
Grant
Filed:
June 8, 1983
Date of Patent:
May 14, 1985
Assignee:
Allied Corporation
Inventors:
Jaroslav F. Kolc, Michael D. Swerdloff, Milorad M. Rogic, Larry L. Hendrickson
Abstract: The invention relates to novel urease inhibited fertilizer compositions containing urea and a urease inhibiting amount of one or more aryl phosphoric triamide and aryl phosphorodiamidate compounds, and to methods and compositions for inhibiting the activity of urease through use of such compounds.
Type:
Grant
Filed:
June 8, 1983
Date of Patent:
May 14, 1985
Assignee:
Allied Corporation
Inventors:
Michael D. Swerdloff, Jaroslav F. Kolc, Milorad M. Rogic, Larry L. Hendrickson
Abstract: Novel urease inhibiting phosphorodiamide compounds, urea based fertilizer compositions including such compounds, and methods and composition for using said compounds to inhibit the catalytic activity of urease.
Type:
Grant
Filed:
March 16, 1983
Date of Patent:
May 14, 1985
Assignee:
Allied Corporation
Inventors:
Louis G. Anello, Michael Van Der Puy, Larry L. Hendrickson, Milorad M. Rogic, Michael D. Swerdloff, Jaroslav F. Kolc
Abstract: The invention relates to novel urease and/or nitrification inhibited fertilizer compositions containing; and methods and compositions for inhibiting urease and/or nitrification through use of a urease and/or nitrification inhibiting amount of novel phosphoric triamide compounds.
Type:
Grant
Filed:
June 8, 1983
Date of Patent:
May 14, 1985
Assignee:
Allied Corporation
Inventors:
Jaroslav F. Kolc, Michael D. Swerdloff, Milorad M. Rogic, Larry L. Hendrickson
Abstract: Novel urease inhibiting phosphoroamide compounds and urea based fertilizer compositions including such compounds, and methods and compositions for inhibiting the activity of urease through use of a urease inhibiting effective amount of one or more of the aforementioned phosphoroamide compounds.
Type:
Grant
Filed:
June 9, 1983
Date of Patent:
May 14, 1985
Assignee:
Allied Corporation
Inventors:
Michael D. Swerdloff, Jaroslav F. Kolc, Milorad M. Rogic, Larry L. Hendrickson
Abstract: A cell and process is provided for the production of fluorine comprising electrolyzing a liquid mixture of fluorides of alkali metal, ammonium and hydrogen fluoride. The cell anode comprises a stock of anode plates with internal passages or it may comprise a carbon shape provided with grooves and passages and fitted to a central conductor which conducts current from the exterior of the cell to the carbon anode plates within the cell. The anode having a substantially expanded working surface has the capability of removing fluorine internally. A louvered cathode permits most of the hydrogen to be vented away from the zone between the electrodes through which current passes thus reducing the ohmic voltage loss. The cathode, rather than being louvered, can be expanded metal or punched sheet or gauze. The anode, cathode and barrier may be cylindrical in form although other shapes, for instance rectangular or square in cross section or even of hexagonal section, may be used if desired.
Type:
Grant
Filed:
December 27, 1983
Date of Patent:
April 16, 1985
Assignee:
Allied Corporation
Inventors:
Alexander M. Saprokhin, David J. Friedland, Richard M. Baran, Jung T. Kim, Lynn E. McCurry
Abstract: Solid hydroxylammonium sulfate is reacted with an alcohol solution of an alkali metal hydroxide or alkoxide to produce an alcoholic hydroxylamine liquid phase and a sulfate-containing solid phase. The liquid phase is used for further reactions such as oximations and hydroxamic acid production. The different bases behave differently with regard to suitable and preferable solvents and temperatures.
Abstract: Novel .beta.-oximinoalkylphosphonic acid ester derivatives of general formula B are prepared from the corresponding .alpha.-halo oxime A: ##STR1## wherein R.sup.1 is a substituent selected from the group consisting of H and C.sub.1 -C.sub.20 alkyl, cycloalkyl and aryl substituents;R.sup.2 is a substituent selected from the group consisting of H and C.sub.1 to C.sub.20 linear alkyl and aryl substituents;R.sup.3 is a substituent selected from the group consisting of H and C.sub.1 to C.sub.20 alkyl, cycloalkyl, 1-alkoxy alkyl, aryl, acyl, N-substituted carbamoyl, N,N-disubstituted carbamoyl and nitrogen- , oxygen- , sulfur- , and phosphorus-containing heterocyclic substituents;R.sup.4 is an alkyl substituent of C.sub.1 to C.sub.20 aryl; andX is a substituent selected from the group consisting of Cl, Br, I.In a specific reaction, the .alpha.-halo oxime derivative is dissolved in an excess of trialkyl phosphite, greater than 3 molar equivalents is preferred. The preference for the .alpha.
Type:
Grant
Filed:
July 26, 1982
Date of Patent:
March 26, 1985
Assignee:
Allied Corporation
Inventors:
David S. Soriano, Timothy R. Demmin, Martin A. Robinson
Abstract: This invention relates to a process for conditioning the surfaces of natural and synthetic plastic materials for electroless plating of a metal coating thereon by exposing such materials to an atmosphere comprising an effective amount of ozone and thereafter contacting said exposed materials with an effective amount of a conditioning solvent, such as an aqueous solution of sodium, potassium or lithium hydroxide.
Type:
Grant
Filed:
August 8, 1983
Date of Patent:
March 19, 1985
Assignee:
Allied Corporation
Inventors:
Albert A. Birkmaier, Gary A. Harpell, Bruce E. Kurtz, Gordhanbhai N. Patel, Rustom P. Poncha, Adam L. Skovrinski, James M. Lesco
Abstract: A process for the production of oximes which comprises contacting, in the vapor phase, a primary saturated aliphatic or alicyclic amine of 2 to 12 carbon atoms with an elemental oxygen gas in the presence of an effective amount of a catalyst comprising an alumina or oxygen-containing tungsten substance on a metal oxide support using temperatures between about 130.degree. and 230.degree. C. at atmospheric pressure is disclosed. Preferred alumina catalysts are alumina xerogels, .gamma.-alumina and acidic, fluorinated alumina. Preferred oxygen-containing tungsten catalysts are WO.sub.3 on .gamma.-alumina or WO.sub.3 on alumina xerogels.
Abstract: Polyacetylene doped with potassium or rubidium cations (and optionally with other alkali metal cations) is heat treated at 60.degree.-400.degree. C., preferably 100.degree.-250 .degree. C., to achieve greatly enhanced room temperature conductivity. Products with relative conductivities 150%, 300%, 450% or more of the conductivity prior to heat treating are obtained, with room-temperature conductivities of 300 S/cm, 450 S/cm, or higher.
Type:
Grant
Filed:
March 16, 1983
Date of Patent:
March 5, 1985
Assignee:
Allied Corporation
Inventors:
Philippe G. Delannoy, Granville G. Miller, Helmut Eckhardt, Ray H. Baughman
Abstract: The invention relates to novel urease inhibited fertilizer compositions containing urea and a urease inhibiting amount of one or more organo boron acid compounds, and to a method and composition for inhibiting the catalytic activity of urease through use of such compounds.
Type:
Grant
Filed:
April 7, 1983
Date of Patent:
July 31, 1984
Assignee:
Allied Corporation
Inventors:
Michael Van Der Puy, Ralph C. Gatrone, Martin A. Robinson, Larry L. Hendrickson