Patents Represented by Attorney Robert A. Gerlach
  • Patent number: 5427900
    Abstract: A photographic element comprising a support having provided thereon a light-sensitive layer and a transparent magnetic recording layer, the magnetic recording layer comprising a transparent polymeric binder, ferro-magnetic particles and tin oxide particles, the magnetic particles having a surface area greater than 30 m.sup.2 /gm and a coverage of from about 1.times.10.sup.-11 mg/.mu.m.sup.3 to about 1.times.10.sup.-10 mg/.mu.m.sup.3, the tin oxide particles having a median diameter of less than 0.15 .mu.m and being present in the transparent magnetic layer in an amount of from 300 to 1200 percent by weight based on the weight of the binder.
    Type: Grant
    Filed: February 8, 1994
    Date of Patent: June 27, 1995
    Assignee: Eastman Kodak Company
    Inventors: Robert O. James, Lawrence A. Rowley, Joseph A. Verdone
  • Patent number: 5426020
    Abstract: This invention describes the use of surfactants of the following types:Type A--Surfactant comprising 6 to 22 carbon atom hydrophobic tail with one or more attached hydrophilic chains comprising at least 8 oxyethylene and/or glycidyl ether groups that may or may not be terminated with a negative charge such as a sulfate group,Type B--Block oligomeric surfactants comprising hydrophobic polyoxypropylene blocks (A) and hydrophilic polyoxyethylene blocks (B) joined in the manner of A--B--A, B--A--B, A--B, (A--B.sub.n .tbd.G.tbd.(B--A).sub.n, or (B--A).sub.n .tbd.G(A--B).sub.n, where G is a connective organic moiety and n is between 1 and 3,Type C--Sugar surfactants, comprising between one to three 6 to 22 carbon atom hydrophobic tail with one or more attached hydrophilic mono or oligosaccharidic chains that may or may not be terminated by a negatively charged group such as a sulfate group.
    Type: Grant
    Filed: August 31, 1993
    Date of Patent: June 20, 1995
    Assignee: Eastman Kodak Company
    Inventors: Pranab Bagchi, Melvin M. Kestner
  • Patent number: 5418128
    Abstract: A coating composition for applying a layer to a photographic element which comprises gelatin, water and from 0.35 to 1 percent by weight based on the total weight of the composition of a surfactant mixture comprising from 20 to 60 percent by weight of a mixture of anionic surfactants, from 30 to 75 percent by weight of a nonionic surfactant and from 3 to 13 percent by weight of a cationic surfactant based on the total weight of surfactant mixture; the mixture of anionic surfactants comprising from 30 to 85 percent by weight of di- and tri-isopropyl naphthalene sulfonate, sodium salts and from 15 to 70 percent by weight of a dioctyl sulfosuccinate, sodium salt; a di-fluoroalkyl sulfosuccinate, sodium salt where alkyl is C.sub.4 -C.sub.6 ; perfluoro-octyl sulfonate(tetraethyl ammonium salt) or a perfluoro-alkyl carboxylate ammonium salt where alkyl is a mixture of C.sub.5 -C.sub.
    Type: Grant
    Filed: March 31, 1994
    Date of Patent: May 23, 1995
    Assignee: Eastman Kodak Company
    Inventor: Michael W. Orem
  • Patent number: 5413903
    Abstract: A silver halide photographic element comprising a support having thereon at least one light-sensitive silver halide emulsion layer and a transparent magnetic recording layer on the substrate, the transparent magnetic recording layer having barium ferrite platelet particles in a transparent binder, the barium ferrite platelet particles being aligned such that the easy axis of the particles is parallel to the substrate.
    Type: Grant
    Filed: October 12, 1993
    Date of Patent: May 9, 1995
    Assignee: Eastman Kodak Company
    Inventor: Frederick J. Jeffers
  • Patent number: 5411844
    Abstract: A coating composition for applying a layer to a photographic element and the resulting photographic element comprising gelatin, water and from 0.3 to 1 gm/100 gms of the composition of a surfactant mixture of 15 to 70 percent by weight of a dioctyl sulfosuccinate, sodium salt or di-fluoroalkylsulfosuccinate, sodium salt, from 35 to 75 percent by weight of a nonylphenoxy polyglycidyl alcohol, and from 3 to 14 percent by weight of perfluoro-octyl sulfonamido, N-hydrogen, N-propylene trimethylammonium iodide based on the total weight of the surfactant mixture; when a dioctyl sulfosuccinate, sodium salt is used, the minimum amount thereof is 0.15 gm/100 gm of coating composition.
    Type: Grant
    Filed: March 31, 1994
    Date of Patent: May 2, 1995
    Assignee: Eastman Kodak Company
    Inventor: Michael W. Orem
  • Patent number: 5405907
    Abstract: A photographic paper having a print retaining layer including a granular tooth providing ingredient in a binder polymer having a T.sub.g of 30.degree. to 65.degree. C. which is the addition product of from about 30 to about 98 mol percent of an alkylmethacrylate wherein the alkyl group has from 3 to 8 carbon atoms, from about 2 to about 10 mol percent of an alkali metal salt of a ethylenically unsaturated sulfonic or carboxylic acid, from 0 to about 65 mol percent of a vinyl benzene monomer and from 0 to about 5 mol percent of a crosslinking agent containing two ethylenically unsaturated bonds.
    Type: Grant
    Filed: August 5, 1991
    Date of Patent: April 11, 1995
    Assignee: Eastman Kodak Company
    Inventors: Wayne A. Bowman, Larry D. Hagemeier
  • Patent number: 5405741
    Abstract: A process is provided for preparing improved aqueous gelatin compositions for improved coatings, particularly light sensitive photographic coatings, wherein a viscosity increasing amount of a copolymer of an alkali metal or ammonium salt of a sulfonic acid containing polymer with an unsaturated monomer, particularly a copolymer of acrylamide and sodium-2-acrylamido-2-methylpropanesulfonate, is added to an aqueous gelatin composition at a point immediately before any point which requires a high viscosity after and a low viscosity before the addition.
    Type: Grant
    Filed: June 8, 1993
    Date of Patent: April 11, 1995
    Assignee: Eastman Kodak Company
    Inventors: James E. Conroy, Nayyir F. Irani
  • Patent number: 5397826
    Abstract: A coating composition for applying a transparent magnetic recording layer to a support which comprises a polymeric binder, ferromagnetic particles and a dispersing medium for the polymeric binder, the dispersing medium comprising (a) a compound having the formula ##STR1## where R is alkyl having 1 to 8 carbon atoms, phenyl or benzyl;R' is hydrogen, methyl or ethyl; andR" is alkyl having 1 to 5 carbon atoms; and(b) methylene chloride, or lower alkyl ketones or mixtures of methylene chloride and lower alkyl ketones.
    Type: Grant
    Filed: December 22, 1993
    Date of Patent: March 14, 1995
    Assignee: Eastman Kodak Company
    Inventor: Ronald M. Wexler
  • Patent number: 5395743
    Abstract: A photographic element comprising a support, having at least a silver halide light-sensitive layer and a transparent magnetic recording layer, the transparent magnetic layer having ferromagnetic particles in a polymeric binder, ferromagnetic particles having a size of at least 30 m.sup.2 /gm and being present in the transparent magnetic layer in a coverage of from about 1.times.10.sup.-11 mg/.mu.m.sup.3 to about 1.times.10.sup.-10 mg/.mu.m.sup.3, the polymeric binder containing up to about 25 weight percent based on the weight of the polymeric binder of a dispersant-cobinder comprising a poly(C.sub.2-4 -alkyleneimine) carrying at least two mono- or poly(carbonyl-C.sub.1-7 -alkyleneoxy) groups.
    Type: Grant
    Filed: December 22, 1993
    Date of Patent: March 7, 1995
    Assignee: Eastman Kodak Company
    Inventors: Mary C. Brick, Robert O. James, Donald J. Majka, Ronald M. Wexler
  • Patent number: 5393650
    Abstract: This invention describes the use of surfactants of the following types:Type A--Surfactant comprising 6 to 22 carbon atom hydrophobic tail with one or more attached hydrophilic chains comprising at least 8 oxyethylene and/or glycidyl ether groups that may or may not be terminated with a negative charge such as a sulfate group.Type B--Block oligomeric surfactants comprising hydrophobic polyoxypropylene blocks (A) and hydrophilic polyoxyethylene blocks (B) joined in the manner of A--B--A, B--A--B, A--B, (A--B.sub.n .tbd.G.tbd.(B--A).sub.n, or (B--A).sub.n .tbd.G(A--B).sub.n, where G is a connective organic moiety and n is between 1 and 3.Type C--Sugar surfactants, comprising between one to three 6 to 22 carbon atom hydrophobic tail with one or more attached hydrophilic mono or oligosaccharidic chains that may or may not be terminated by a negatively charged group such as a sulfate group.
    Type: Grant
    Filed: June 27, 1994
    Date of Patent: February 28, 1995
    Assignee: Eastman Kodak Company
    Inventors: Pranab Bagchi, Melvin M. Kestner
  • Patent number: 5385704
    Abstract: The invention provide an improved polyethylene terephthalate photographic film base having excellent dimensional stability, optical clarity and mechanical strength while also possessing a crystalline configuration that enables finishing by cutting, chopping or perforating techniques at reduced fracture resistance with decreased generation of dirt.
    Type: Grant
    Filed: July 27, 1993
    Date of Patent: January 31, 1995
    Assignee: Eastman Kodak Company
    Inventors: Andy H. Tsou, Jehuda Greener, Gary D. Smith, Gary M. Mosehauer
  • Patent number: 5385968
    Abstract: An aqueous coating composition for applying a print retaining antistatic layer consisting essentially of an aluminum modified colloidal silica and an antistatic agent in a binder polymer, the binder polymer consisting essentially of an addition product of from about 30 to 78 mol % of an alkyl methacrylate wherein the alkyl group has from 3 to 8 carbon atoms, from about 2 to about 10 mol % of an alkali metal salt of an ethylenically unsaturated sulfonic acid and from 20 to about 65 mol % of a vinyl benzene, the polymer having a glass transition point of from 30.degree. to 65.degree. C.
    Type: Grant
    Filed: June 8, 1993
    Date of Patent: January 31, 1995
    Assignee: Eastman Kodak Company
    Inventors: Wayne A. Bowman, Mario D. DeLaura, Norman S. Edgett
  • Patent number: 5384376
    Abstract: A novel organic/inorganic hybrid material has been discovered comprising a functionalized silsesquioxane and an organic component having reactive endgroups wherein the organic backbone of the organic component is selected from polyimides, polyquinoxolines, polyether ketones, polyether sulfones, and polyesters. The hybrid materials are useful as films that may be employed as reinforced plastics, lightweight metal replacements, and as coatings.
    Type: Grant
    Filed: December 23, 1992
    Date of Patent: January 24, 1995
    Assignee: Eastman Kodak Company
    Inventors: Scott E. Tunney, Gary A. Rakes, Bradley K. Coltrain
  • Patent number: 5384192
    Abstract: A structure comprising an inorganic oxide substrate having thereon an organic polymer layer, characterized in that interposed between the substrate and the organic polymer layer there is an adhesion promoting layer of a block or graft copolymer, one component of which is compatible with the organic polymer and a second of which is a poly(vinyl phenol) component that is capable of hydrogen bonding with the inorganic oxide substrate is disclosed. In preferred embodiments, the substrate is a semiconductor material and the adhesion promoter facilitates the adhesion of a photoresist or protective coating.
    Type: Grant
    Filed: March 11, 1993
    Date of Patent: January 24, 1995
    Assignee: Eastman Kodak Company
    Inventors: Timothy E. Long, Bradley K. Coltrain, David M. Teegarden
  • Patent number: 5378577
    Abstract: Photographic elements having at least one light-sensitive layer and at least one layer having polymeric matte particles surrounded by a layer of colloidal inorganic particles.
    Type: Grant
    Filed: October 30, 1992
    Date of Patent: January 3, 1995
    Assignee: Eastman Kodak Company
    Inventors: Dennis E. Smith, John L. Muehlbauer
  • Patent number: 5371211
    Abstract: Cellulose esters of polycarboxylic acids, and their salts, such as the hydrogen cellulose ester of succinic acid, and the potassium salts thereof, are known to be useful in the preparation of conductive layers in composite such as photographic films. This invention comprises the discovery that such esters and salts provide improved conductive layers, if made from amorphous cellulose obtained by deacylating a material (such as cellulose acetate) using a lower alcohol as the deacylating agent, and an alkali metal alkoxide as the catalyst. Thus, the conductivity of potassium cellulose succinate (KCS) is improved, if made from a cellulose produced as described above. Furthermore, gelatin/KCS coating solutions made from improved KCS coating solutions of this invention have lower viscosities; this makes them much more suitable for roll coating, a support to be coated such as by a skim pan--air knife technique.
    Type: Grant
    Filed: December 4, 1990
    Date of Patent: December 6, 1994
    Assignee: Eastman Kodak Company
    Inventor: Jan W. H. Faber
  • Patent number: 5366855
    Abstract: An imaging element comprising a support, a light-sensitive layer and an antistat layer, the antistat layer being overcoated with a protective layer of a coalesced layer of film-forming colloidal polymeric particles and non-film-forming colloidal polymeric particles.
    Type: Grant
    Filed: March 31, 1994
    Date of Patent: November 22, 1994
    Assignee: Eastman Kodak Company
    Inventors: Charles C. Anderson, Yongcai Wang
  • Patent number: 5366544
    Abstract: A coating composition for applying a vanadium pentoxide antistatic layer on a photographic element comprising from about 0.02 to about 0.08 percent by weight of vanadium pentoxide, from about 0.04 to about 1.6 percent by weight of a cellulose acetate binder polymer, said binder polymer having an acetyl content of from about 15 percent to about 35 percent by weight and the balance a solvent mixture of from 7.5 to 70 percent by weight of a C.sub.1 -C.sub.2 dialkyl ketone, from 10 to 60 percent by weight of a C.sub.1 -C.sub.4 alkanol and from 3 to 50 percent of water based on the weight of the solvent mixture.
    Type: Grant
    Filed: May 27, 1993
    Date of Patent: November 22, 1994
    Assignee: Eastman Kodak Company
    Inventors: Raymond T. Jones, Jack J. Holt
  • Patent number: 5360706
    Abstract: Imaging elements comprising a support, at least one imaging layer and an antistat layer, said antistat layer comprising vanadium pentoxide in a binder, said binder being a polyesteranionomer and coating compositions for forming such antistat layers.
    Type: Grant
    Filed: November 23, 1993
    Date of Patent: November 1, 1994
    Assignee: Eastman Kodak Company
    Inventors: Charles C. Anderson, Gerald M. Leszyk, Kenneth L. Tingler
  • Patent number: 5356468
    Abstract: Coating composition, antistat layer and photographic element having a V.sub.2 O.sub.5 antistat layer, the layer containing an amount of cellulose nitrate to prevent precipitation of the V.sub.2 O.sub.5 in the presence of film base.
    Type: Grant
    Filed: May 27, 1993
    Date of Patent: October 18, 1994
    Assignee: Eastman Kodak Company
    Inventors: Charles T. Havens, Raymond T. Jones, John M. Fukushima, Jack J. Holt