Abstract: Filaments are produced from polymers having an inherent viscosity of at least 0.7 measured in concentrated sulfuric acid and containing in the polymer chain at least 50 percent of the repeating units: ##STR1## by melting the polymer and heating the melt to a temperature of from about 20.degree. C. to about 80.degree. C. above the melting point of the polymer, passing the melt through a filter pack having a filtering area of at least about 8 in.sup.2 and a total volume of at least about 1.2 in.sup.3 per pound of polymer extruded per hour, and containing inert, irregularly shaped particles having a mesh size of about 25 to 140 to provide a pressure drop at least about 800 psig., extruding the melt through spinning openings of desired shape to form filaments and passing the filaments immediately upon extrusion through a heating zone maintained at a temperature of about 200.degree. to 320.degree. C. and having a length of about 3 to 12 inches.
Abstract: Poly(2-methyl-1,5-pentylene) terephthalamide is discussed herein. It is manufactured in a process starting with a nylon salt made from terephthalic acid and 2-methyl-1,5-pentylene diamine and an excess amount of the diamine. The polymer is spun to form monofilaments. The monofilaments may be used, among other things, to form dryer screens for use in a paper forming process.
Type:
Grant
Filed:
February 11, 1991
Date of Patent:
May 12, 1992
Assignee:
Hoechst Celanese Corporation
Inventors:
Robert B. Rashbrook, Clyde W. Alexander, Edward C. Bland
Abstract: Adhesion between carbon fibers and thermoplastic matrix materials, used in carbon fiber composite materials, is promoted by the use of a bridging agent. The composite material includes: a plurality of carbon fibers; a thermoplastic matrix material intermingled among the plurality of carbon fibers; and a bridging agent adhering the plurality of carbon fibers to the thermoplastic matrix material. The bridging agent includes compounds having multifunctional groups that are capable of chemically bonding with a functional group of the carbon fiber and a functional group of the thermoplastic matrix material; but it excludes multifunctional amine compounds having metal-oxygen bonds.
Abstract: Polyester polyols are prepared by reacting a multifunctional adduct (e.g., maleic anhydride (MA)) and tall oil fatty acid, (TOFA), and then esterifying/transesterifying the MA/TOFA reaction product with an excess of aromatic polyester polyols (preferably such polyols are produced from dimethyl terephthalate (DMT) process residue and polyhydric alcohols). The polyester polyols may be used in the manufacture of rigid polyurethane (PUR) and rigid urethane-modified polyisocyanurate (PUR/PIR) foams.
Abstract: A process for the production of cellulose ester fibrets wherein a solution of the cellulose ester is contacted with a non-solvent for the cellulose ester in a precipitation zone under shearing conditions, and a solvent-nonsolvent mixture is separated from the formed fibrets and recycled to the precipitation zone.
Abstract: Molded article having improved thermal resistance and strength formed from a homogeneous mixture comprising from about 5 to 75 percent by weight polybenzimidazole and from about 95 to 25 percent by weight of a polyaryleneketone. These articles are obtained by injection molding techniques.
Type:
Grant
Filed:
April 13, 1989
Date of Patent:
December 3, 1991
Assignee:
Hoechst Celanese Corporation
Inventors:
Edwardo Alvarez, Lorenzo P. DiSano, Bennett C. Ward
Abstract: A solution polybenzimidazole which is resistant to phase separation contains: a polybenzimidazole; a solvent capable of dissolving the polybenzimidazole; and a minor amount of ammonium acetate.
Type:
Grant
Filed:
June 8, 1990
Date of Patent:
November 19, 1991
Assignee:
Hoechst Celanese Corporation
Inventors:
Robert B. Sandor, Theodore S. Thornburg
Abstract: Cellulose ester microparticles with unique properties are made by a process having the following steps:(a) dissolving a cellulose ester in a liquid comprising a solvent for the cellulose ester and a non-solvent for the cellulose ester, thereby forming a dope;(b) spheronizing the dope thereby forming fine droplets of the dope;(c) dropping the droplets for a finite amount of time; and(d) precipitating the droplets in a bath containing a precipitant.
Type:
Grant
Filed:
June 3, 1991
Date of Patent:
November 12, 1991
Assignee:
Hoechst Celanese Corporation
Inventors:
Thomas L. Steiner, Kenneth A. Domeshek, William Stitt, Jesse L. Riley, Lance J. Deutsch
Abstract: Cellulose ester microparticles with unique properties are made by a process having the following steps:(a) dissolving a cellulose ester in a liquid comprising a solvent for the cellulose ester and a non-solvent for the cellulose ester, thereby forming a dope;(b) spheronizing the dope thereby forming fine droplets of the dope;(c) dropping the droplets for a finite amount of time; and(d) precipitating the droplets in a bath containing a precipitant.
Type:
Grant
Filed:
April 24, 1989
Date of Patent:
September 10, 1991
Assignee:
Hoechst Celanese Corporation
Inventors:
Thomas L. Steiner, Kenneth A. Domeshek, William Stitt, Jesse L. Riley, Lance J. Deutsch
Abstract: A process for producing zero pilling polyester filaments, staple, yarn and fabrics is disclosed. The process steps include: providing a polyester polymer containing a structure opener and a monomer containing a sulfonate group; forming the polymer into fibers; hydrolyzing those fabrics; and arresting the hydrolysis by the addition of a metal ion source.
Abstract: Microparticle of cellulose acetate and derivatives thereof characterized by being water soluble, having a large interior void space and having a plurality of open exterior surface pores. These water soluble microparticles can be loaded with a chemical selected from the group consisting of pharmaceuticals, dyes, flavorings, agriculturals, solid catalysts and fragrances.
Type:
Grant
Filed:
August 15, 1989
Date of Patent:
March 5, 1991
Assignee:
Celanese Fibers Inc.
Inventors:
Thomas L. Steiner, Dana T. Minnick, Kenneth A. Domeshek, Donald H. Lester, Jr.
Abstract: Water soluble cellulose acetate composition having improved processability and tensile properties suitable for application as films, coatings and fibers and comprising one or more lower molecular weight water soluble cellulose acetate components and one or more higher molecular weight water soluble cellulose acetate components, and wherein the lower molecular weight water soluble cellulose acetate components have solution viscosities at least 20 percent of that of the higher molecular weight water soluble cellulose acetate components. An exemplary composition comprises from about 85 to 98 percent by weight of a lower molecular weight water soluble cellulose acetate component having a solution viscosity of form about 5 to 50 cps and from about 15 to 2 percent by weight of a higher molecular weight water soluble cellulose acetate component having a solution viscosity of greater than 100 cps.
Abstract: A filter for a smoking article includes: a flavorant; a hollow fiber made of a thermoplastic, the flavorant dispersed in the thermoplastic; and a filter plug in which the fiber is embedded. Additionally, the hollow fiber may be sheathed with a layer of cellulose acetate.
Abstract: A blanket with a weighted perimeter and a method of its use are disclosed herein. This blanket is used as a safety device which can prevent injury to a person cutting baling straps, that surround baled materials and that are under tension, by dampening the whiplash of the straps when cut.
Abstract: Microparticle of cellulose acetate and derivatives thereof characterized by being water soluble, having a large interior void space and having a plurality of open exterior surface pores. These water soluble microparticles can be loaded with a chemical selected from the group consisting of pharmaceuticals, dyes, flavorings, agriculturals, solid catalysts and fragrances.
Type:
Grant
Filed:
December 8, 1987
Date of Patent:
December 19, 1989
Assignee:
Celanese Fibers, Inc.
Inventors:
Thomas L. Steiner, Dana T. Minnick, Kenneth A. Domeshek, Donald H. Lester, Jr.