Abstract: A process for preparing lithium aluminate of at least 95% gamma phase with surface areas greater than 10 m.sup.2 /g by homogeneously mixing a gamma lithium aluminate with surface area of less than 8 m.sup.2 /g with an aqueous hydrogen peroxide solution having a concentration of 5 to 70% for at least 1/2 hour at a temperature greater than 0.degree. C. and less than 120.degree. C., the treated gamma lithium aluminate is dried by heating to a temperature greater than 200.degree. C. until dry and ground to produce a gamma-lithium aluminate with surface area greater than 10 m.sup.2 /g.
Abstract: A process for the preparation of alkyllithium compounds including 2-alkyl-substituted alkyllithium compounds by reacting in a liquid organic solvent, in an inert atmosphere a C.sub.2 to C.sub.18 saturated, acyclic, primary alkyl halide including 2-alkyl-substituted alkyl halides with a dispersion of particulate lithium and sodium metals in which there is 5 to 50 mole percent sodium based on the lithium content at a temperature of 0.degree. to a temperature up to but not exceeding the decomposition temperature of the product.
Type:
Grant
Filed:
August 22, 1991
Date of Patent:
May 18, 1993
Assignee:
FMC Corporation
Inventors:
Robert C. Morrison, B. Troy Dover, Conrad W. Kamienski
Abstract: Aqueous gel compositions and their use in electrophoresis, and anhydrous compositions useful in the preparation of the aqueous gel compositions.The aqueous gel compositions comprise:A. water,B. at least one di- or tri-hydroxy C.sub.2-4 alkyl ether moiety (preferably glyceryl) substituted agarose, andC. from about 20 to about 400 mM of at least one borate compound per liter of aqueous gel composition.The anhydrous compositions comprise the agarose in powder form and the borate in powder or aqueous solution.
Abstract: The present invention provides a melamine phosphonic acid salt of the general formula (I) ##STR1## in which R is hydrogen, methyl or a negative valency bond, and n is 1 when R is hydrogen or methyl, or 2 when R.sup.1 is a negative valency bond.The salts are useful as flame retardants in polymers.
Abstract: Process for disposal of insoluble tailings that remain when solubilizing uncalcined or calcined trona in the process of producing soda ash, in which tailings are slurried with a saturated or substantially saturated solution of sodium carbonate, sodium bicarbonate and mixtures thereof, pumping said slurry into a well connected to an underground mined-out cavity with sufficient pressure to prevent the build-up of tailings from plugging the bottom of the well opening, dispersing and settling said tailings and a retained portion of the solution in the cavity, removing solution from said cavity and conveying it to the surface, recovering the removed solution for recycle and slurrying of additional tailings, and adding as make-up liquor to replace the solution retained in the cavity, a saturated or substantially saturated solution of sodium carbonate, sodium bicarbonate and mixtures thereof. The preferred solution employed in this process is purge solution which is discarded from a crystallizer circuit.
Type:
Grant
Filed:
July 25, 1991
Date of Patent:
March 9, 1993
Assignee:
FMC Corporation
Inventors:
William R. Frint, Michael M. Bithell, William G. Fischer
Abstract: Electrophoretic resolving gel compositions, discontinuous stacking gel systems containing these and other resolving gel compositions, and kits for preparing such gel systems, comprising one or more polysaccharide hydrogels of which agarose is typical wherein at least one of the gels in the resolving gel composition has been derivatized and at least one of the gels in the resolving gel composition has been depolymerized sufficiently to reduce its casting-effective viscosity.
Type:
Grant
Filed:
June 20, 1991
Date of Patent:
September 1, 1992
Assignee:
FMC Corporation
Inventors:
Samuel Nochumson, Foner P. Curtis, Jonathan H. Morgan, Francis H. Kirkpatrick
Abstract: This invention provides a process for deacidifying paper by contacting the paper with hydrocarbon or halocarbon solutions of certain magnesium and/or zinc alkoxyalkoxides which may have been treated with carbon dioxide to yield low viscosity solutions.
Type:
Grant
Filed:
December 20, 1990
Date of Patent:
April 14, 1992
Assignee:
FMC Corporation
Inventors:
Conard W. Kamienski, Robert S. Wedinger
Abstract: An organometallic composition containing copper(I) comprising:(a) an organometallic composition of the formulaR.sub.T R.sub.R CuLiwherein R.sub.T is a transferable anionic group, R.sub.R is a residual anionic group and containing 0.01 to 1.2 mole equivalents of halide in the form of chloride, bromide or iodide; 0 to 0.12 mole equivalents of magnesium; 0.5 to 7 mole equivalents of a Lewis base and a solvating amount of a liquid hydrocarbon.
Abstract: A process for strengthening the cellulose in materials which have been treated with an alkaline organometallic compound selected from a metal alkyl, metal alkoxide or alkyl metal alkoxide to deacidify the cellulose and which cellulosic material is wet with treatment solvent, by treating the undried cellulosic material with a polar monomer and then drying the cellulose material and polymerizing the monomer by subjecting the treated cellulose to vacuum and heat.
Type:
Grant
Filed:
February 20, 1990
Date of Patent:
March 10, 1992
Assignee:
FMC Corporation
Inventors:
Conrad W. Kamienski, Robert S. Wedinger
Abstract: The present invention discloses and exemplifies alcohol, ether and ester derivatives of difluoroalkanes and difluoroalkenylalkanes having the general formula R--(CH.sub.2).sub.m --CR.sup.2 R.sup.3 --OR.sup.1, in which R is a 1,1-difluoroalkyl or a 1,1-difluoroalkenyl group, composition thereof, and use thereof to control agricultural crop pests.
Type:
Grant
Filed:
June 30, 1989
Date of Patent:
January 14, 1992
Assignee:
FMC Corporation
Inventors:
Clinton J. Peake, Thomas G. Cullen, Anthony J. Martinez
Abstract: Process for disposing of insoluble tailings that remain when solubilizing uncalcined or calcined trona in the process of producing soda ash, in which the tailings are slurried with water or waste solutions of sodium carbonate and/or sodium bicarbonate, pumping the slurry into a well connected to an underground mined-out cavity with sufficient pressure to prevent build-up of tailings from plugging the bottom of the well opening, dispersing and settling said tailings in the cavity, removing a liquor from said cavity whose concentration of sodium carbonate and/or sodium bicarbonate has been increased and recovering such enriched liquor for use in the manufacture of sodium-containing chemicals such as soda ash.
Type:
Grant
Filed:
August 29, 1990
Date of Patent:
August 27, 1991
Assignee:
FMC Corporation
Inventors:
William R. Frint, Michael M. Bithell, William G. Fischer
Abstract: An environmentally improved process is provided to fade denim fabric either as the woven fabric or after being made up into garments. The denim fabric may optionally be uniformly faded, or faded in a random pattern and stone washed. The effluent from the process does not have the disadvantage of the high COD of conventional processes.
Type:
Grant
Filed:
December 15, 1989
Date of Patent:
April 9, 1991
Assignee:
FMC Corporation
Inventors:
Robert H. Tieckelmann, Randy A. Bull, Lisa M. Kurschner
Abstract: A process is described for the separation and recovery of phosphorus from phosphorus-dirt mixtures by adding a quaternary ammonium compound to the mixture, while it is under an aqueous cover, agitating same, and separating a lower phosphorus phase from an upper dirt phase. The mixtures are treated prior to addition of the quaternary ammonium compound, where required, by lowering their dirt to phosphorus levels sufficiently low to permit them to be destabilized.
Type:
Grant
Filed:
May 7, 1990
Date of Patent:
March 26, 1991
Assignee:
FMC Corporation
Inventors:
Alan S. Michaels, Wayne H. Lee, Theodore F. Munday
Abstract: This invention concerns organometallic amide compositions particularly bimetallic organoamides in liquid hydrocarbon solutions in which one metal is an alkali metal the other an alkaline earth metal, zinc or copper and particularly lithium magnesium bis-diorganoamides, such as lithium magnesium bis-diisopropylamide and processes for preparation of such amides. These novel bimetallic amides have increased solubility in liquid hydrocarbon solvents and improved thermal and precipitation stability at temperatures of 0.degree. C. to 40.degree. C.
Type:
Grant
Filed:
February 25, 1988
Date of Patent:
March 26, 1991
Assignee:
Lithium Corporation of America
Inventors:
Vijay C. Mehta, Terry L. Rathman, Conrad W. Kamienski, Robert C. Morrison, Randy W. Hall
Abstract: Novel synthesis of dihalovinylcyclopropanecarboxylates, including potent insecticides, are described. The processes begin with the reaction between an alkenol and an orthoester to produce a .gamma.-unsaturated carboxylate, followed by the catalyzed addition of a carbon tetrahalide to the double bond and dehydrohalogenation to produce a cyclopropane derivative.
Abstract: Process for producing granular tetrasodium pyrophosphate having a bulk density of about 0.73 to about 0.84 g/ml and a dissolving time of about three minutes or less by heating crystalline disodium orthophosphate dihydrate at a slow heating rate, not over about 5.degree. C. per minute, until its temperature reaches about 130.degree. C. and then calcining it at about 350.degree. C. to about 550.degree. C. until it is converted to tetrasodium pyrophosphate.
Abstract: The excessive wear and formation of ring-like cavities in carbon crucibles used to contain iron-based compositions that are heated in a plasma furnace to a temperature of from about 2000.degree. C. to aboout 2700.degree. C. are reduced or eliminated by adding carbon particles to the crucible in amounts of at least about 6 weight percent of the melt, and preferably in amounts exceeding the solubility of carbon in the heated melt.
Abstract: A process for producing organometallic compositions by reacting an organohalide with a mixture of two metals; one being an alkali metal, the other being selected from magnesium, calcium, barium and zinc in a hydrocarbon solvent containing 0.5 to 2.0 moles of a Lewis Base per mole of organohalide.
Abstract: Pesticidal mono-, di-, and tri-2-fluoroethyl ethers of the formula R.sup.1 R.sup.2.sub.m Ar(OCH.sub.2 CH.sub.2 F).sub.n, compositions thereof and their insecticidal, acaricidal and nematicidal uses are described and claimed.
Type:
Grant
Filed:
August 28, 1989
Date of Patent:
October 2, 1990
Assignee:
FMC Corporation
Inventors:
David M. Roush, Donald A. Shaw, Michael L. Jones, Jun H. Chang
Abstract: The present invention relates to a process for corn regeneration from tissue culture which comprises the steps of(a) culturing corn tissue on a callus induction medium comprising the hormone picloram, mineral salts, vitamins, and sucrose to produce embryogenic callus;(b) subculturing the embryogenic callus on a callus maintenance medium comprising the hormone picloram, mineral salts, vitamins, and sucrose for callus maintenance;(c) subculturing the embryogenic callus on regeneration medium comprising mineral salts, vitamins, and sucrose to produce plantlets; and(d) subculturing the plantlets on maturation medium comprising mineral salts, vitamins, and sucrose for root and shoot development.