Abstract: Trimethylolpropane of high purity is efficiently made by mixing the aldol reaction product of formaldehyde and n-butyraldehyde with at least about 20 wt % of a lower alcohol prior to hydrogenation. The alcohol addition also promotes hydrogenolysis of by-product esters at pressures below 3000 psig and allows recovery of high purity product by simple distillation.
Type:
Grant
Filed:
August 2, 1996
Date of Patent:
June 9, 1998
Assignee:
Aristech Chemical Corporation
Inventors:
Jeffrey S. Salek, Joseph Pugach, Carole L. Elias, Leonard A. Cullo