Abstract: Concentrates produced by melt processing a branching agent and a polyester carrier are disclosed. The concentrates are useful in melt processing polyesters. The concentrates contain sufficiently high concentrations of a branching agent to minimize the formation of crosslinked compounds in the concentrates. Process for using the concentrate also are disclosed.
Type:
Grant
Filed:
January 30, 1996
Date of Patent:
September 17, 1996
Assignee:
Amoco Corporation
Inventors:
George E. Rotter, Weilong Chiang, Boh C. Tsai, John L. Melquist, Cheryl A. Pauer, Stephen Y. Chen
Abstract: Self-reinforcing, pitch-based carbon articles having an unique combination of excellent thermal conductivity and outstanding mechanical properties are produced by carbonizing acid-treated mesophase pitch fiber, preferably in the form of a preform structure. The carbon articles having varying degrees of porosity are particularly desirable for use in thermal management and stiffness applications, and in carbon vapor infiltration processes employed in making complex solid carbon articles.
Abstract: A process for preparing condensation polymers comprises forming a dispersion of a reaction mixture in a continuous vapor phase, maintaining the dispersion while passing it through a reaction zone, heating the dispersion in the reaction zone to polymerize reactants in the reaction mixture and form a polycondensate.
Type:
Grant
Filed:
February 10, 1995
Date of Patent:
August 27, 1996
Assignee:
Amoco Corporation
Inventors:
Joel A. Richardson, Wassily Poppe, Benjamin A. Bolton, Edward E. Paschke
Abstract: Olefin is formed by displacing alkyl groups of aluminum trialkyl by contacting ethylene with the aluminum trialkyl in an ethylene:aluminum trialkyl mol ratio in the range of 2-8:1 at about 0.degree.-70.degree. C. and at atmospheric up to about 1000 psia pressure, for a reaction time of about 0.5 to about 60 minutes in the presence of a displacement enhancing amount of a nickel- or cobalt-containing displacement catalyst. Despite the fact that the displacement reaction is an equilibrium reaction, the process does not use, as did the prior art, large excesses of ethylene to shift the equilibrium to favor displacement. Consequently, the volumes of ethylene used in the processing are reduced very substantially and yet yields of the desired displaced alpha olefin remain favorable.
Type:
Grant
Filed:
June 2, 1995
Date of Patent:
August 27, 1996
Assignee:
Amoco Corporation
Inventors:
Ronny W. Lin, Robert H. Allen, Andrew D. Overstreet
Abstract: Ethylene is trimerized to form 1-hexene by using a catalyst comprising an aluminoxane and polydentate phosphine, arsine, and/or stibine coordination complex of a chromium salt.
Abstract: A process for producing an internal olefin of the formula ##STR1## where R.sup.1 and R.sup.2 are the same or different and are either a hydrogen or an alkyl and m is an integer of from 0 to 20 comprising contacting a vinyl or vinylidene olefin of the formula ##STR2## where R.sup.1, R.sup.2 and m are as previously defined, with a catalytically effective amount of a mixture of i) an aluminum compound of the formula R.sup.3.sub.n Al(OR.sup.4).sub.p where R.sup.3 and R.sup.4 are the same or different and are alkyl, n is an integer from 0.75 to 2.25, and p is an integer from 0.75 to 2.25, the sum of n and p being 3, and ii) a cobalt (II) salt of an organic carboxylic acid, at a temperature of from about 25.degree. C. to about 250.degree. C. whereby a major amount of said internal olefin is produced and only a minor amount of a tri-substituted internal olefin.
Abstract: This invention provides an improved process for the preparation of an aluminum alkyl chain growth product by the chain growth reaction of alpha-olefins on aluminum alkyl, the improvement comprising catalyzing the chain growth reaction that is a partially oxidized aluminum alkyl.
Type:
Grant
Filed:
February 27, 1995
Date of Patent:
July 16, 1996
Assignee:
Amoco Corporation
Inventors:
Kaung-Far Lin, Carroll W. Lanier, William B. Waites
Abstract: Concentrates produced by melt processing a branching agent and a polyester carrier are disclosed. The concentrates are useful in melt processing polyesters. The concentrates contain sufficiently high concentrations of a branching agent to minimize the formation of crosslinked compounds in the concentrates. Process for using the concentrate also are disclosed.
Type:
Grant
Filed:
June 7, 1995
Date of Patent:
July 16, 1996
Assignee:
Amoco Corporation
Inventors:
George E. Rotter, Weilong Chiang, Boh C. Tsai, John L. Melquist, Cheryl A. Pauer, Stephen Y. Chen
Abstract: An improved heating method and heating nozzle useful in the forming of a two-piece thermoplastic foam cup assembled from two thermoplastic foam pieces on a cup-forming turret machine. The method and apparatus of the invention prevent premature sticking of the foam bottom piece to the foam sidewall piece and result in better sealing of the foam bottom to the sidewall.
Abstract: A molded article having improved weld line strength, fabricated from a polymer blend composition comprising at least one liquid crystalline polymer and at least one additional polymer, wherein the composition has a crystallization rate lower than said at least one liquid crystalline polymer.
Type:
Grant
Filed:
July 28, 1994
Date of Patent:
February 20, 1996
Assignee:
Amoco Corporation
Inventors:
Paul J. Huspeni, John F. Petry, Roger W. Nelson, Steven R. Dunkle
Abstract: A process for preparing condensation polymers comprises forming a dispersion of a reaction mixture in a continuous vapor phase, maintaining the dispersion while passing it through a reaction zone, heating the dispersion in the reaction zone to polymerize reactants in the reaction mixture and form a polycondensate.
Type:
Grant
Filed:
July 26, 1994
Date of Patent:
January 2, 1996
Assignee:
Amoco Corporation
Inventors:
Joel A. Richardson, Wassily Poppe, Benjamin A. Bolton, Edward E. Paschke
Abstract: Disclosed is a multi-layer sheet in a which a foamed thermpolastic core layer is extrusion coated with a multi-resin reclaim-containing layer, and an EVOH or acrylonitrile barrier layer is laminated to the multi-resin layer. The multi-resin layer is formulated to contain at least about 5 weight percent, and preferably about 8 to about 16 weight percent, based on the weight of the layer, of an adhesive resin to reduce the tendency of the barrier layer to delaminate from the multi-resin layer over time. The preferred adhesive is EMA.
Type:
Grant
Filed:
July 30, 1993
Date of Patent:
October 31, 1995
Assignee:
Amoco Corporation
Inventors:
David C. Lindemann, Weilong L. Chiang, Melvin L. Luetkens, Jr., Robert D. Pischke, John C. Schubert
Abstract: Solution spun fiber obtained from resin comprising an amide-imide polymer having repeating units of the following general formula: ##STR1## wherein the fiber has tenacity of at least about 1.5 grams per denier, and elongation of at least about 10%.
Type:
Grant
Filed:
January 14, 1994
Date of Patent:
October 17, 1995
Assignee:
Amoco Corporation
Inventors:
Howard B. Yokelson, Stefanos L. Sakellarides, Raymond T. Behrends
Abstract: Polyamide filaments stabilized with a copper-containing stabilizer and a polyolefin synergist exhibit substantially improved dry heat stability. The filaments withstand processing at elevated temperatures and are particularly useful in applications where extended exposure to elevated temperatures in air is contemplated.
Abstract: Disclosed is a process for obtaining polyester articles, including foamed articles, containing low levels of extractable branching agent. The process comprises: (1) forming a molten mixture comprising (i) a major amount of a first resin composition comprising polyester and from 0 up to about 1 wt. % of a compound capable of branching the polyester, and (ii) a minor amount of a second polyester resin composition comprising at least about 50 wt. % polyester resin and greater than about 2 wt. % of a compound capable of branching the polyester, wherein the relative amounts of (i) and (ii) are such that said molten mixture comprises from about 0.1 wt. % to about 1 wt. % of said branching compound; (2) adding a blowing agent to the molten mixture; and (3) extruding the resultant mixture to obtain a foam. The invention is also directed to the second composition used in the above process, and foamed polyester articles obtained from the process.
Type:
Grant
Filed:
May 12, 1994
Date of Patent:
August 29, 1995
Assignee:
Amoco Corporation
Inventors:
George E. Rotter, John L. Melquist, Weilong Chiang, Boh C. Tsai, John J. Kelly
Abstract: Impact-modified polyphthalamide resins are improved in ductility and rigidity when blended with polypropylene and a carboxylated polyolefin resin. The blends exhibit an excellent balance of ductility and rigidity.
Type:
Grant
Filed:
March 3, 1994
Date of Patent:
July 25, 1995
Assignee:
Amoco Corporation
Inventors:
Glenn P. Desio, Ruth A. Montag, George A. Corbin
Abstract: The improved infrared source comprises a fiber-reinforced resin matrix composite having low infrared surface reflectivity and a quarter-wave optical coating on a surface of the composite to increase the reflectivity in a portion of the infrared and provide the surface with dichroic reflection characteristics.
Abstract: Filled and unfilled polyamide compositions of improved toughness comprise a blend of a polyamide comprising recurring aliphatic terephthalamide units, a functionalized polyolefin and a functionalized block copolymer comprising styrene polymer blocks and rubber blocks comprising ethylene/propylene ethylene/butylene or ethylene/pentylene polymer blocks or a combination thereof.
Abstract: A sizing formulation adapted for use with carbon fiber yarn comprising an aqueous dispersion of a film-forming, heat-reactive resin having a Tg below about -50.degree. C. and a water-dispersible ethoxylated alkyl phenol provides yarn having improved resistance to abrasion, less breakage and low fuzz formation, permitting substantial handling of the fiber in fabrication and weaving operations with reduced losses. In addition, the sizing may be readily removed thermally without the production of noxious byproducts when deemed necessary for use in further processing and impregnation operations.
Abstract: A process and fabric for controlling soil erosion which comprises an erosion control mat formed of a scrim having a lightweight web secured thereto to be utilized by applying the erosion control mat to a soil surface. A method of producing such erosion control mat is also disclosed.
Type:
Grant
Filed:
July 29, 1993
Date of Patent:
October 25, 1994
Assignee:
Amoco Corporation
Inventors:
Gerald A. Romanek, Roger E. Moon, Mark L. Marienfield, Sukhdev S. Guram