Patents Represented by Attorney Stephen M. Westbrook
  • Patent number: 4972017
    Abstract: A polymeric film material for the rinse release of wash additives comprises a blend of polyvinyl alcohol and an alkyl cellulose. A metalloid oxide cross-linking agent is present in an amount sufficient to sharply reduce the solubility rate of the film blend in an alkaline wash, yet allow dissolution in a less alkaline rinse. Optionally, a hydrophobic cationic species is included to further reduce the dissolution rate in the wash pH. The films remain intact during normal wash cycles and over a range of typical water temperatures, then rapidly dissolve in the rinse. The film can be used to microencapsulate an additive, or made into a water-soluble pouch, or as a soluble seal for a pouch or container.
    Type: Grant
    Filed: November 10, 1988
    Date of Patent: November 20, 1990
    Assignee: The Clorox Company
    Inventors: William L. Smith, Edward J. Kaufmann, Barry A. Sudbury
  • Patent number: 4964870
    Abstract: The invention provides novel peracid precursors representative of which is the structure: ##STR1## wherein R.sup.1 is alkyl of 1 to 20 carbon atoms; R.sup.2 is OH, --O--R.sup.3, or ##STR2## and X.sup.1, X.sup.2, Y and Z are individually selected from H, SO.sub.3.sup.--, CO.sub.2.sup.--, NO.sub.2, NR.sub.4.sup.5+, halogen, R.sup.6 and mixtures thereof;wherein R.sup.3 of --O--R.sup.3 is alkyl of 1 to 20 carbon atoms; R.sup.4 of ##STR3## is alkyl of 1 to 20 carbon atoms; R.sup.5 of NR.sub.4.sup.5+ is selected from H, alkyl of 1 to 24 carbon atoms and mixtures thereof; and R.sup.6 is alkyl of 1 to 20 carbon atoms.In one embodiment of the invention, the novel peracid precursors are combined with a source of hydrogen peroxide and sufficient quantities of buffer to impact an alkaline pH when the composition is placed in aqueous solution. Preferred embodiments of the invention include wherein R.sup.2 is hydroxy, and R.sup.1 is alkyl of 1 to 20 carbon atoms (monoester); and wherein R.sup.2 is ##STR4## and R.sup.
    Type: Grant
    Filed: June 8, 1989
    Date of Patent: October 23, 1990
    Assignee: The Clorox Company
    Inventors: Ronald A. Fong, Stephen B. Kong
  • Patent number: 4959187
    Abstract: The invention provides novel bleaching compositions comprising peracid precursors with the general structure ##STR1## with R, R', R" and L as defined in the specification. Novel peracids and precursors are also herein disclosed. These peracid precursors provide new, proficient and cost-effective compounds for fabric bleaching.
    Type: Grant
    Filed: October 14, 1988
    Date of Patent: September 25, 1990
    Assignee: The Clorox Company
    Inventors: Ronald A. Fong, Sheldon N. Lewis, Richard J. Wiersema, Alfred G. Zielske
  • Patent number: 4957063
    Abstract: This invention relates to an animal litter to which has been applied on odor-inhibiting amount of a guanidine salt.
    Type: Grant
    Filed: July 25, 1988
    Date of Patent: September 18, 1990
    Assignee: The Clorox Company
    Inventors: Fred A. Heitfeld, Randy L. Wood
  • Patent number: 4957647
    Abstract: The invention provides novel bleaching compositions comprising peracid precursors having oxynitrogen leaving groups. Peracid precursors containing these leaving groups provide new, proficient and cost-effective compounds for fabric bleaching.These compounds have the general structures: ##STR1## where R is a straight or branched chain C.sub.1-20 alkyl, alkoxyl, cycloalkyl and mixtures thereof; R.sup.1 contains at least one carbon atom which is singly bonded directly to N; n is an integer from 1 to 6 and X is methylene or a heteroactom; or ##STR2## wherein n is the same as in (I); but R.sup.2 contains a carbon atom doubly bonded directly to N, and, either X is a heteroatom or nothing, and R is C.sub.4-17 alkyl.
    Type: Grant
    Filed: April 14, 1989
    Date of Patent: September 18, 1990
    Assignee: The Clorox Company
    Inventor: Alfred G. Zielske
  • Patent number: 4946619
    Abstract: A stable bleaching and brightening composition is provided comprising(a) an active halogen source;(b) an amine oxide surfactant;(c) a stilbene sulfonic acid type FWA and(d) a pH adjusting agent; and wherein the ratio of amine oxide:FWA is 3:1 to 10:1.A preferred method for making the composition is to prepare a concentrated surfactant solution of at least 20% surfactant, then dissolve the FWA therein to form a stable premix. The active halogen source, pH adjusting agent and any option ingredients are then combined with the premix. The resulting composition has good brightener and hypochlorite stability, and good brightener solubility.
    Type: Grant
    Filed: July 19, 1988
    Date of Patent: August 7, 1990
    Assignee: The Clorox Company
    Inventor: Jeffrey J. Fisher
  • Patent number: 4919834
    Abstract: The present invention provides a package for a phase stable, liquid nonaqueous detergent, comprising:a plastic, relatively thin-walled container, said container having an end wall and a circumscribing side wall which narrows to a finish, and a liquid detergent contained in said container, said detergent comprising:(a) 20-90% of a liquid portion which comprises an alkoxylated nonionic surfactant;(b) 5-50% of a solids portion which comprises:(i) a builder;(ii) 0-20% of the detergent of an oxidant; said solids being stably suspended in said liquid portion, by means of(c) a phase stabilizing amount of a lower alkylated fused ring polyarylene sulfonate; and(d) 0-5% of a hydrolytic enzyme;whereby the phase stability of said liquid detergent in storage in said container is controlled, by the selection of either:(1) said container being constructed of a homopolymeric resin, said container having a minimum average cross-sectional dimension r/2 of at least about 6.
    Type: Grant
    Filed: September 28, 1988
    Date of Patent: April 24, 1990
    Assignee: The Clorox Company
    Inventors: Loren Chen, Gregory van Buskirk, David Peterson, Robert J. Iliff
  • Patent number: 4900467
    Abstract: A thickened aqueous cleaning composition is viscoelastic, with a long relaxation time to provide a thick solution with consumer-acceptable pour properties. The composition has utility as a drain opening composition or as a hard surface cleaner having a cleaning-effective residence time on non-horizontal surfaces. The composition includes a cleaning active, and a binary thickener comprising a betaine or sulfobetaine having a C.sub.14-18 alkyl, or C.sub.10-18 alkylamino or alkylamido group, and an organic, anionic counterion. The composition preferably has a relaxation time of at least about 5 seconds and a relative elasticity between about 10-500 sec/Pa.
    Type: Grant
    Filed: May 20, 1988
    Date of Patent: February 13, 1990
    Assignee: The Clorox Company
    Inventor: William L. Smith
  • Patent number: 4900469
    Abstract: A thickened cleaning composition for laundry products incorporates low levels of a fluorescent whitening agent or dye, a surfactant, an acidic pH adjusting agent and an insoluble peracid precursor. At the acidic pH, the fluorescent whitening agent precipitates as a colloidal particle, and is stabilized by associating with the surfactant, resulting in thickening. The precursor is stably suspended in its inactive form in the thickener, and provides oxidizing power as the corresponding peracid is formed when added to an alkaline wash or rinse solution. The composition preferably is formulated with an acidic soluble bleach source and most preferably with a peroxygen bleach.
    Type: Grant
    Filed: June 29, 1988
    Date of Patent: February 13, 1990
    Assignee: The Clorox Company
    Inventors: James P. Farr, Daniel T. Carty
  • Patent number: 4891147
    Abstract: The invention provides a phase stable liquid detergent containing at least one insoluble oxidant, comprising:(a) a liquid phase which comprises (i) an effective amount of at least one surfactant selected from the group consisting of anionic, nonionic, cationic, amphoteric, zwitterionic surfactants, and mixtures thereof; (ii) a liquid carrier therefore, comprising organic solvents, water, or a mixture thereof; and(b) an effective amount of a water insoluble oxidant stably suspended in said liquid phase, which maintains oxidative stability, said water insoluble oxidant being an alkaline earth metal peroxide or a Group IIB peroxide.
    Type: Grant
    Filed: November 25, 1988
    Date of Patent: January 2, 1990
    Assignee: The Clorox Company
    Inventors: Robert L. Gray, David Peterson, Loren Chen, Gregory van Buskirk
  • Patent number: 4885105
    Abstract: A PVA film modified with anionic comonomers is provided for use as a water-soluble seal or pouch for alkaline or borate-containing cleaning compositions. The films comprise copolymers of 90-100% hydrolyzed vinyl alcohol with a nonhydrolyzable anionic comonomer, and have molecular weights characterized by a viscosity range of 4-35 cPs. The films are resistant to insolubilization caused by alkaline or borate-containing additives, are storage stable over a wide range of temperature and humidity storage conditions, rapidly and fully solubilize in a wash solution, and do not significantly impair cleaning performance of an additive enclosed within.
    Type: Grant
    Filed: March 31, 1988
    Date of Patent: December 5, 1989
    Assignee: The Clorox Company
    Inventors: Chihae Yang, Edward J. Kaufmann
  • Patent number: 4874537
    Abstract: The present invention provides a stable liquid, substantially nonaqueous, detergent comprising, by weight percent:(a) 20-90% of a liquid portion which comprises an alkoxylated nonionic surfactant;(b) a solids portion which comprises:(i) 5-50% of a builder;(ii) 0-20% of an oxidant; said solids being stably suspended in said liquid portion, by means of(c) a phase stabilizing amount of a lower alkylated fused ring polyarylene sulfonate; and(d) 0-5% of a hydrolytic enzyme.Further desirable adjuncts may be added to the liquid compositions of this invention.
    Type: Grant
    Filed: September 28, 1988
    Date of Patent: October 17, 1989
    Assignee: The Clorox Company
    Inventors: David Peterson, Loren Chen, Robert J. Iliff
  • Patent number: 4865759
    Abstract: A dry bleach product is based upon diperacid, particularly diperoxydodecanedioic acid. The dry product comprises separate granular, particulate and beaded components wherein the granular component is diperacid stabilized with an exotherm control agent, diluent and a binder that includes unneutralized polymeric acid. The beaded component is fragrance admixed with a water soluble starch; the particulate components include an agglomerated extender or bulking agent, a pH control agent, and protected fluorescent whitening agents, all as separate particulate components. The water content of the granular diperacid is carefully controlled, as is the ratio of exotherm control agent to diperacid.
    Type: Grant
    Filed: November 21, 1988
    Date of Patent: September 12, 1989
    Assignee: The Clorox Company
    Inventors: Thomas S. Coyne, Daniel H. Klapprott, Eric A. Lutkin, Frances E. Mitchell, Ute H. Riggin, Dale S. Steichen, Suzanne M. Thompson
  • Patent number: 4863633
    Abstract: This invention relates to a storage and shipping system comprising corrugated containers which house plastic vessels or bottles used to hold fragranced liquid bleaches in which the shipping and storage containers are stacked on top of one another. In the stacks in all of the shipping and storage containers except for the topmost one, the plastic vessels will share some of the vertical component of the compression load caused by the shipping and storage container directly located above a given shipping and storage container. The compression load can cause stress-cracking in the vessels or bottles if strongly wetting surfactants are used to disperse the fragrances.
    Type: Grant
    Filed: August 7, 1987
    Date of Patent: September 5, 1989
    Assignee: The Clorox Company
    Inventors: David W. Colborn, G. Edward Campbell, William L. Smith, Chung-Lu Hsieh, Donald K. Swatling, Peter C. Arbogast
  • Patent number: 4858758
    Abstract: A transparent, durable container for housing and delivering a free-flowing granular dry oxidant bleach composition, the container being constructed of a heteropolymeric plastic which maximizes transmission of water vapor for minimum decomposition of the oxidant bleach stored within the container. The selected plastic has a water vapor transmission rate of at least about 2 g/day/100 in..sup.2 /mil. thickness. The container may include a fragrancing means located remote from the container. The fragrancing means is isolated from the bleach composition by an apertured barrier which allows the fragrance to contact the bleach composition but does not allow the bleach composition to contact the fragrancing means.
    Type: Grant
    Filed: December 12, 1988
    Date of Patent: August 22, 1989
    Assignee: The Clorox Company
    Inventors: Frances E. Mitchell, G. Edward Campbell, Dale S. Steichen
  • Patent number: 4851139
    Abstract: A stable, isotropic fabric softening composition includes relatively high levels of a 2-n-alkyl-4-isothiazoline-3-one to provide immediate and residual mildewstatic activity on fabrics treated therewith. The composition also includes a quaternary ammonium or imidazolinium fabric softener having an iodine value of between about 20 and 70, an organic solvent matrix and optionally, a fatty acid soap, surfactant and pH adjusting agent, all to the promote the isotropic quality of the composition.
    Type: Grant
    Filed: August 26, 1987
    Date of Patent: July 25, 1989
    Assignee: The Clorox Company
    Inventors: Sheldon N. Lewis, Clement K. Choy, Eugene A. Mizusawa, Tracey L. Casella
  • Patent number: D307549
    Type: Grant
    Filed: August 4, 1986
    Date of Patent: May 1, 1990
    Assignee: The Clorox Company
    Inventors: Theodore L. Beaver, G. Edward Campbell
  • Patent number: D307550
    Type: Grant
    Filed: August 4, 1986
    Date of Patent: May 1, 1990
    Assignee: The Clorox Company
    Inventors: Theodore L. Beaver, G. Edward Campbell
  • Patent number: D309420
    Type: Grant
    Filed: October 7, 1986
    Date of Patent: July 24, 1990
    Assignee: The Clorox Company
    Inventor: Theodore L. Beaver
  • Patent number: D311136
    Type: Grant
    Filed: December 4, 1986
    Date of Patent: October 9, 1990
    Assignee: The Clorox Company
    Inventors: Jimmie D. Barker, Vincent M. Shortino