Abstract: A process has been developed to produce high-quality high explosive (HE) molding powder which is safe, efficient, has a low-cost, and is non-polluting. The method involves utilizing a chemically inert, non-aqueous carrier fluid as a processing liquid to facilitate the coating process.
Abstract: A process for synthesizing novel conjugated amino substituted phenylene pmers is disclosed. The process results in polymers having non-linear optical properties, and the polymers can be converted to electrically conductive polymers. The process involves reacting a novel bis-cycloalkylene sulfonium salt of 2,5,N,N-tetramethylaniline hydrochloride, such as 2,5-(N,N-dimethyl)aniline hydrochloride dimethylene bis-(tetramethylene sulfonium chloride) with alkali metal hydroxide to form a cycloalkylene sulfonium salt precursor polymer, and then heating the precursor polymer under conditions to produce the amino substituted phenylene vinylene polymer, such as poly(2-(N,N-dimethylamino) phenylene vinylene). Another process involves treatment of the bis chlormethyl dimethyl aniline hydrochloride derivative with alkali metal alkoxide.
Type:
Grant
Filed:
May 18, 1995
Date of Patent:
November 26, 1996
Assignee:
The United States of America as represented by the Secretary of the Navy
Inventors:
John D. Stenger-Smith, William P. Norris, Andrew P. Chafin, Scott T. Sackinger