Patents Represented by Attorney Steven W. Tan
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Patent number: 5364945Abstract: Anhydride-functional polymerizable monomers having the structure: ##STR1## and polymers and reactive compositions prepared from these monomers are disclosed. The reactive compositions are especially useful in primer and clearcoat/basecoat applications.Type: GrantFiled: January 3, 1994Date of Patent: November 15, 1994Assignee: The Sherwin-Williams CompanyInventors: Rubing Cai, Thomas W. Yokoyama
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Patent number: 5360856Abstract: A hydroxy-functional polymeric dispersant which is substantially free of acid groups, amine groups, and ethylenic unsaturation, the dispersant being especially adapted for dispersing pigments therein and being compatible with a variety of film-forming polymers, said dispersant being the free radical addition polymerization reaction product of a mixture of monomers consisting essentially of:(a) 15-30% by weight styrene; and(b) 15-30% by weight of at least one alkyl methacrylate monomer having 1 to 16 carbon atoms in the alkyl group; and(c) 20-60% by weight of at least one alkyl acrylate monomer having 1 to 16 carbon atoms in the alkyl group; and(d) 7-25% by weight of at least one hydroxy-functional ethylenically unsaturated monomer copolymerizable with monomers (a) (b) and (c);wherein said polymeric dispersant has a weight average molecular weight of 18,000 to 24,000, a number average molecular weight of 4,500 to 7,400, and a polydispersity of 2.9 to 4.2.Type: GrantFiled: February 18, 1994Date of Patent: November 1, 1994Assignee: The Sherwin-Williams CompanyInventors: Rodney M. Harris, Maqsood S. Ahmed, Thomas A. Renner
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Patent number: 5352257Abstract: A baffle assembly for intercepting paint particles passing through a spray booth is disclosed. The baffle assembly includes an inner plate and an outer plate adjacent each end or edge of the inner plate. The inner plate is comprised of a central planar portion, which is oriented substantially perpendicular to the direction of air flow, and having outer ends which are curved in an upstream direction and inwardly toward one another. Each outer plate includes a curved portion which terminates in a semi-circular portion. The inner plate is received and positioned within the outer plates so that each of its outer ends is substantially surrounded by and equidistant from its adjacent outer plate. In this manner, air flows between the inner plate and the outer plate in a first curved direction and then in a second opposite curved direction.Type: GrantFiled: October 8, 1993Date of Patent: October 4, 1994Assignee: The Sherwin-Williams CompanyInventor: Harold R. Powers
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Patent number: 5349080Abstract: An unsaturated ester monomer having the structure: ##STR1## wherein R.sup.1 is hydrogen or methyl; R.sup.2, R.sup.3 and R.sup.4 are each independently lower alkyl of 1 to about 4 carbons; and Z is nothing or is a divalent radical having 1 to about 20 carbons.Type: GrantFiled: January 3, 1994Date of Patent: September 20, 1994Assignee: The Sherwin-Williams CompanyInventor: Rodney M. Harris
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Patent number: 5348992Abstract: This invention relates to aerosol paint and coating compositions comprising non-aqueous dispersions.Type: GrantFiled: January 29, 1993Date of Patent: September 20, 1994Assignee: The Sherwin-Williams CompanyInventors: Paul D. Pearson, Madhukar Rao, Richard F. Tomko
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Patent number: 5340871Abstract: This Invention relates to aerosol paint and coating compositions comprising non-aqueous dispersions.Type: GrantFiled: January 29, 1993Date of Patent: August 23, 1994Assignee: The Sherwin-Williams CompanyInventors: Paul D. Pearson, Madhukar Rao, Richard F. Tomko
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Patent number: 5310780Abstract: Low VOC penetrating compositions for staining and protecting porous substrates such as wood, concrete, cement, brick and the like, comprising aqueous dispersions of polyurethane-ureas.Type: GrantFiled: August 26, 1993Date of Patent: May 10, 1994Assignee: The Sherwin-Williams CompanyInventors: Revathi Tomko, Sanford L. Hertz, Buckel, Jr. Charles T., Mitchell R. Draving
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Patent number: 5288828Abstract: A hydroxy-functional polymeric dispersant which is substantially free of acid groups, amine groups, and ethylenic unsaturation, the dispersant being especially adapted for dispersing pigments therein and being compatible with a variety of film-forming polymers, said dispersant being the free radical addition polymerization reaction product of a mixture of monomers consisting essentially of:(a) 15-30% by weight styrene; and(b) 15-30% by weight of at least one alkyl methacrylate monomer having 1 to 16 carbon atoms in the alkyl group; and(c) 20-60% by weight of at least one alkyl acrylate monomer having 1 to 16 carbon atoms in the alkyl group; and(d) 7-25% by weight of at least one hydroxy-functional ethylenically unsaturated monomer copolymerizable with monomers (a) (b) and (c);wherein said polymeric dispersant has a weight average molecular weight of 18,000 to 24,000, a number average molecular weight of 4,500 to 7,400, and a polydispersity of 2.9 to 4.2.Type: GrantFiled: March 8, 1993Date of Patent: February 22, 1994Assignee: The Sherwin-Williams CompanyInventors: Rodney M. Harris, Maqsood S. Ahmed, Thomas A. Renner
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Patent number: 5252615Abstract: Coating compositions derived from the alcoholysis of polyethylene terephthalate.Type: GrantFiled: January 23, 1992Date of Patent: October 12, 1993Assignee: The Sherwin-Williams CompanyInventors: Madhukar Rao, Richard F. Tomko, Daniel R. Sayre, William B. Lesney
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Patent number: 5196055Abstract: This invention relates to a two-component, low VOC pretreatment primer comprising:a) an aqueous first component comprising1) a resin,2) a zinc chromate pigment,3) a zinc phosphate pigment, and4) a package stabilizing agent; andb) an aqueous second component comprising a catalyst soution for said first component.Type: GrantFiled: January 23, 1991Date of Patent: March 23, 1993Assignee: The Sherwin-Williams CompanyInventors: William B. Lesney, Frank M. Jachim
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Patent number: 5157100Abstract: A method for extending the pot-life of a curable composition comprising a mixture of at least one active hydrogen-containing material, such as a polyol or polyamine, and a polyisocyanate, which method comprises incorporating within the mixture a pot-life extending amount of a polyanhydride having an average of at least two anhydride groups per molecule.Type: GrantFiled: September 20, 1991Date of Patent: October 20, 1992Assignee: The Sherwin-Williams CompanyInventors: John R. Babjak, Thomas W. Yokoyama
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Patent number: 5104955Abstract: This invention relates to novel hydroxy-functional polyester diluents, and more particularly, to acrylic-modified hydroxy-functional polyester reactive diluents useful for blending with a variety of thermosetting or thermoplastic film-forming polymers. More specifically, the hydroxy-functional polyester reactive diluents are essentially low molecular weight polyesters derived from triols, and a combination of unsaturated monocarboxylic acids and saturated monocarboxylic acids. These hydroxy-functional polyester diluents may be copolymerized with one or more acrylic monomers, i.e. hydroxy-functional acrylic monomers, and blended with a variety of thermosetting or thermoplastic film-forming polymers. These blends of the film-forming polymers and the hydroxy-functional polyester diluents can be crosslinked with conventional crosslinking agents such as isocyanates and used in the formulation of low VOC paint compositions particularly useful as automotive topcoats.Type: GrantFiled: December 19, 1988Date of Patent: April 14, 1992Assignee: The Sherwin-Williams CompanyInventor: John Mathai
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Patent number: 5099787Abstract: A grounding apparatus for supporting an article during manufacture, preferably including a trolley, a hanger assembly and a hook assembly. The trolley is moveable along, and electrically connected to, a conveyor track for transporting the articles. The hook assembly supports the article and comprises an electrically conductive, rotatable, hook and base. The hanger assembly is electrically conductive and secures the hook assembly to the trolley. The hook assembly includes a rotatable hook and base having an electrically conductive brush fixedly attached to the base and contacting the rotating hook and base to electrically connect the hook with the base, and define an electrically conductive path between the article and the trolley.Type: GrantFiled: February 7, 1990Date of Patent: March 31, 1992Assignee: The Sherwin-Williams CompanyInventor: Harold R. Powers
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Patent number: 5098788Abstract: Isocyanate functional polymers useful as crosslinking agents or as moisture curing polymers, which comprise the addition polymerization reaction product of:(a) 1 to 100% by weight of at least one isocyanate functional ethylenically unsaturated monomer which comprises the reaction product obtained by the gradual addition of an ethylenically unsaturated monomer having a single active hydrogen to a diisocyanate selected from the group consisting of isophorone diisocyanate and 2,4 toluene diisocyanate wherein the final molar ratio of active hydrogen containing monomer to diisocyanate is essentially 1 to 1; and(b) 0 to 99% by weight of at least one ethylenically unsaturated monomer which is free of active hydrogen functionality and which is copolymerizable with the ethylenically unsaturated isocyanate functional monomer.Type: GrantFiled: December 26, 1990Date of Patent: March 24, 1992Assignee: The Sherwin-Williams CompanyInventors: Brian C. Petrie, Thomas W. Druetzler, Rodney M. Harris
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Patent number: 5042773Abstract: A merchandise display device for supporting merchanise, advertising materials or the like, having a one-piece deformable body with a support portion for engagement with a support member, such as a paint can, and a display portion for supporting the merchandise, advertising materials or other display items. A fastener clip is also provided for securing the body member in a folded display position, and for maintaining the support member and display items in clamping engagement with the body member. The support and display portions are formed by juxtaposed first and second halves of the body member, when the body member is folded together and the clip or clips are engaged with free halves of the body member in display position. The first and second halves of the body member are substantially mirror images of one another. A central axis divides the first and second halves and intersects a mid-point at the fold in the body member in the display position.Type: GrantFiled: January 3, 1990Date of Patent: August 27, 1991Assignee: The Sherwin-Williams CompanyInventor: Norman A. Johansen
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Patent number: 5039732Abstract: Air-drying, water-reducible, acid-functional polyurethanes are obtained by reacting:(i) a fatty amide diol obtained by the reaction of a fatty acid or fatty acid derivative and an N,N-dialkanol amine; and(ii) a diisocyanate; and(iii) an acid-functional compound which also has two active hydrogen groups, other than acid groups, which are reactive with the dissocyanate.Type: GrantFiled: December 30, 1988Date of Patent: August 13, 1991Assignee: The Sherwin-Williams CompanyInventor: Kartar S. Arora
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Patent number: 5004828Abstract: This invention relates to novel hydroxy-functional polyester diluents, and more particularly, to acrylic-modified hydroxy-functional polyester reactive diluents useful for blending with a variety of thermosetting or thermoplastic film-forming polymers. More specifically, the hydroxy-functional polyester reactive diluents are essentially low molecular weight polyesters derived from triols, and a combination of unsaturated monocarboxylic acids and saturated monocarboxylic acids. These hydroxy-functional polyester diluents may be compolymerized with one or more acrylic monomers, i.e. hydroxy-functional acrylic monomers, and blended with a variety of thermosetting or thermoplastic film-forming polymers. These blends of the film-forming polymers and the hydroxy-functional polyester diluents can be crosslinked with conventional crosslinking agents as isocyanates and used in the formulation of low VOC paint compositions particularly useful as automotive topcoats.Type: GrantFiled: April 27, 1987Date of Patent: April 2, 1991Assignee: The Sherwin-Williams CompanyInventor: John Mathai
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Patent number: 4983716Abstract: This invention relates to high solids alkyds, non-aqueous dispersions, and coating compositions containing those alkyds and non-aqueous dispersions, having non-volatile materials contents greater than about 75% NVM, with very low volatile organic contents of less than 305 g/l, which exhibit excellent stability, viscosity and tack-free and dry times when formulated as air dry coating compositions.Type: GrantFiled: January 16, 1990Date of Patent: January 8, 1991Assignee: The Sherwin-Williams CompanyInventors: Madhukar Rao, Richard F. Tomko, Daniel R. Sayre
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Patent number: 4983266Abstract: This invention relates to an electrodeposition process which comprises electrodepositing onto a conducting substrate a coating composition comprising a self-crosslinking polymeric resin which has an average of at least two pendent hydroxy functional groups and an average of at least two pendent ester groups of the general formula: ##STR1## wherein R.sup.1 and R.sup.2 are independently hydrogen, alkyl, substituted alkyl or aryl groups; n is from about 1 to about 5; X is nitrogen, sulfur or phosphorus; and when X is nitrogen or phosphorus, R.sup.3 is hydrogen, lower alkyl, or an aryl group; R.sup.4 is lower alkyl or an aryl group; and when X is sulfur, R.sup.4 is nothing and R.sup.3 is either hydrogen, lower alkyl or aryl.Type: GrantFiled: December 27, 1988Date of Patent: January 8, 1991Assignee: The Sherwin-Williams CompanyInventors: Goutam Gupta, Sherman J. Mels
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Patent number: 4983676Abstract: Isocyanate functional polymers useful as crosslinking agents or as moisture curing polymers, which comprise the addition polymerization reaction product of:(a) 1 to 100% by weight of at least one isocyanate functional ethylenically unsaturated monomer which comprises the reaction product obtained by the gradual addition of an ethylenically unsaturated monomer having a single active hydrogen to a diisocyanate selected from the group consisting of isophorone diisocyanate and 2,4 toluene diisocyanate wherein the final molar ratio of active hydrogen containing monomer to diisocyanate is essentially 1 to 1; and(b) 0 to 99% by weight of at least one ethylenically unsaturated monomer which is free of active hydrogen functionality and which is copolymerizable with the ethylenically unsaturated isocyanate functional monomer.Type: GrantFiled: December 30, 1988Date of Patent: January 8, 1991Assignee: The Sherwin-Williams CompanyInventors: Brian C. Petrie, Thomas W. Druetzler, Rodney M. Harris