Abstract: This invention relates to N'-substituted-N,N'-disubstitutedhydrazines of formula I ##STR1## wherein X and X' are independently O, S, or NR; A' and B' are independently substituted or unsubstituted aryl or aromatic heterocycle; wherein F is alkyl, alkenyl, or aralkyl; and wherein E is a tertiary carbon containing organic radical having a total of at least four carbon and halogen atoms but not more than six halogen atoms, or a non-tertiary carbon containing non-haloalkyl organic or organometallic radical having at least five atoms other than hydrogen, oxygen and halogen which are useful as insecticides, compositions containing those compounds, methods of producing the compounds, and methods of their use. More particularly, the invention relates to insect growth regulating compounds and compositions, and methods of using such compounds and compositions. Compounds of the present invention are particularly suitable for controlling plant-destructive insects in crops of cultivated plants, ornamentals and forestry.
Type:
Grant
Filed:
May 22, 1995
Date of Patent:
January 11, 2000
Assignee:
Rohm and Haas Company
Inventors:
Adam Chi-Tung Hsu, Harold Ernest Aller, Dat Phat Le, Donald Wesley Hamp, Barry Weinstein, Raymond August Murphy
Abstract: Polymers of (N-lower alkyl)dimethylglutarimide or (N-hydrogen)dimethylglutarimide are resistant to surface crazing, molecular weight degradation and yellowing on exposure to ultraviolet light, by inclusion of a hindered amine stabilizer.
Type:
Grant
Filed:
January 11, 1991
Date of Patent:
December 17, 1996
Assignee:
Rohm and Haas Company
Inventors:
Leslie A. Cohen, Darnell DeGraff, Harry C. Fromuth, Theodore D. Goldman
Abstract: A process for the preparation of an .alpha.,.beta.-unsaturated C.sub.3 -C.sub.6 carboxylic acid of greater than 98% purity, which combines fractional distillation and melt crystallization procedures.
Type:
Grant
Filed:
March 28, 1994
Date of Patent:
June 4, 1996
Assignee:
Rohm and Haas Company
Inventors:
William Bauer, Jr., Robert M. Mason, Rita K. Upmacis
Abstract: A method is provided for using selected photoactive compounds in acid hardening photoresists to produce thermally stable, high resolution images with near ultraviolet exposing radiation. These photoactive compounds can be used as photosensitizers for halogen-containing photoacid generators which by themselves do not otherwise generate sufficient acid upon exposure to near ultraviolet radiation to catalyze the crosslinking of acid hardening resins. The photoactive compounds are selected from the group consisting of phenothiazine, derivatives of phenothiazine, and phenoxazine.
Abstract: This invention relates to insecticidal compositions containing six-membered heterocyclic derivatives of N'-substituted-N,N'-diacylhydrazines, methods of using such compositions and novel six-membered heterocyclic derivatives of N'-substituted-N,N'-diacylhydrazines.
Abstract: Compounds of the formula: ##STR1## wherein X is O or S; R and R.sup.1 are substituted or unsubstituted alkyl, alkenyl, alkynyl or cycloalkyl or R and R.sup.1 may be joined to form a heterocyclic ring; R.sup.2 is substituted or unsubstituted cycloalkyl; and n is 0, 1 or 2 are disclosed as well as their postemergence and preemergence selective herbicide use against both monocot and dicot weeds in crops such as sugarbeets, cotton, soybeans and rice.
Abstract: A tubular test chamber of square cross-section minimizes reflection of stray light from the interior surface of the test chamber onto the detector during measurement by an optical system which is based upon right angle light scattering by the dust particles of a test sample. A rotary solenoid is utilized to open a trap door through which a sample is dropped into the test chamber during energization so that the internal spring of the solenoid can be used to bias the door closed upon deenergization thereof. The electronic circuitry which supports the measurement process provides an output in the form of a single "characteristic number" for each sample measured and has a novel feedback circuit used in auto-zeroing of the device.
Type:
Grant
Filed:
June 24, 1992
Date of Patent:
April 12, 1994
Assignee:
Rohm and Haas Company
Inventors:
Edward M. Sioma, James Litterio, Wen H. Chia
Abstract: A compound of the formula ##STR1## wherein R.sub.1 is an organic radical having at least 2 carbon atoms;R.sub.2 is an organic radical; andA=CO, CH.sub.2, or CHR.sub.3 where R.sub.3 is unsubstituted or substituted alkyl; andZ.sub.1 and Z.sub.2 are independently selected from hydrogen, halogen, and (C.sub.1 -C.sub.4) alkyland use as a fungicide and biocide.
Type:
Grant
Filed:
February 10, 1992
Date of Patent:
April 5, 1994
Assignee:
Rohm and Haas Company
Inventors:
Barry Weinstein, Philip Robinson, Katherine E. Flynn, Cherylann Schieber
Abstract: This invention provides an improved adhesive layer for multi-layer films and bottles, the adhesive layer being a graft copolymer of a polyolefin backbone with a methyl methacrylate graft. The graft copolymer sufficiently improves the compatibility between barrier resins and polyolefins to permit the production of monolithic or single layer bottles comprised of a blend of those three components. The resultant products have improved physical properties while retaining acceptable permeability to gases.
Type:
Grant
Filed:
July 8, 1992
Date of Patent:
April 5, 1994
Assignee:
Rohm and Haas Company
Inventors:
Casmir S. Ilenda, Thomas M. Frantz, William T. Freed
Abstract: A class of 6-arylpyrimidines which is useful in the control of weeds is of the general formulae: ##STR1## wherein R.sup.2 is selected from hydrogen, halo, substituted or unsubstituted alkyl, haloalkyl, polyhaloalkyl, haloalkenyl, polyhaloalkenyl, haloalkynyl, polyhaloalkynyl, alkenyl, alkynyl, alkoxy, alkylthio, alkoxycarbonylalkyl, cyano, alkoxyalkyl, alkoxycarbonyl, cycloalkyl, aralkyl, alkylamino, dialkylamino, or dialkylaminocarbonyl group; R.sup.3 is an alkyl, alkenyl, alkynyl, or haloalkyl group; R.sup.5 is an alkyl, alkenyl, alkynyl, alkenynyl, or alkoxyalkyl, group; R.sup.6 is an aryl group (e.g. aromatic ring); and X is oxygen or sulfur. R.sup.2 and R.sup.3 may form a fused ring.
Abstract: Compounds of the formula: ##STR1## wherein X is hydrogen, halo, trihalomethyl, alkyl, nitroor cyano; X.sup.1 is hydrogen, halo, or trihalomethyl; R.sup.1 and R.sup.2 are hydrogen, alkyl phenyl or benzyl; n is 1 to 5, and Z is halo, cyano, nitro, trihalomethyl, methylthio, methylsulfinyl, methylsulfonyl, acetyl, phenyl, or heterocycle, and compositions containing these compounds exhibit herbicidal activity.
Abstract: This invention pertains to phosphosulfonates, having the general formula ##STR1## wherein Y is phenyl, naphthyl, benzyl, a (C.sub.5 -C.sub.8)cycloalkyl, a 5-membered heteroaromatic ring, a 6-membered heteraromatic ring, a fused 5,6-membered heteroaromatic ring, or a fused 6,6-membered heteroaromatic ring; andX is oxygen or sulfur; andR.sup.1 and R.sup.2 are each independently selected from substituted or unsubstituted alkyl, alkoxy, alkylthio, alkenyloxy, alkynyloxy, haloalkoxy, cyanoalkoxy, alkoxyalkoxy, cycloalkyloxy, cycloalkylalkoxy, alkylideneiminooxy, chloro, amino, phenyl or phenoxy; or R.sup.1 and R.sup.2 are both alkoxy, taken together with the phosphorus atom to form a 6-membered oxygen-containing ring; compositions containing these compounds and their use as herbicides.
Type:
Grant
Filed:
April 1, 1992
Date of Patent:
December 21, 1993
Assignee:
Rohm and Haas Company
Inventors:
Robert E. Rosen, Damian G. Weaver, Jane W. Cornille, Lori A. Spangler
Abstract: Compounds of the formula ##STR1## are fungicides and herbicides when Z is alkyl, cycloalkyl, aryl, or aralkyl; Q is a triazolyl; X is an aryl group or a heterocyclic group; and W is a variety of functional groups.
Abstract: Glutarimide polymers having an acid and anhydride content lower than the acid and/or anhydride content normally present in the glutarimide polymers. Blends of the reduced acid and anhydride glutarimide polymers with thermoplastic materials are disclosed. A process for altering the properties of imide polymers by reducing or substantially removing acid and anhydride levels normally present in the imide polymer is also disclosed.
Type:
Grant
Filed:
January 10, 1991
Date of Patent:
November 23, 1993
Assignee:
Rohm and Haas Company
Inventors:
Michael P. Hallden-Abberton, Newman M. Bortnick, Leslie A. Cohen, William T. Freed, Harry C. Fromuth
Abstract: This invention relates to novel (2-aryl-2-substituted)ethyl-1,2,4-triazoles and the enantiomorphs, acid addition salts and metal salt complexes thereof, as well as their method of preparation and their use as highly active broad-spectrum systemic fungicides.
Abstract: A polymer support catalyst containing polymerized units of a polymerizable chelated metal species coordinated to one or more polydentate ligands to provide three or more chelate bonds to the metal atom.
Type:
Grant
Filed:
February 21, 1992
Date of Patent:
September 7, 1993
Assignee:
Rohm and Haas Company
Inventors:
John C. Dobson, Christine McDade, Mario G. L. Mirabelli, Jeremia J. Venter
Abstract: A novel graft copolymer capable of imparting to a polyolefin when blended therewith high tensile modulus and high sag resistance without increasing melt viscosity, and a method of making the same. The graft copolymer is a polyolefin having a relatively high weight-average molecular weight methacrylate polymer grafted thereto. The graft copolymer is formed by dissolving or swelling a non-polar polyolefin in an inert hydrocarbon solvent, heating to dissolve the polyolefin, and while stirring the mixture, adding a methacrylate monomer, together with an initiator to produce a constant, low concentration of radicals, to form a graft copolymer with a high molecular weight polymer chain covalently bonded or grafted to the polyolefin backbone. The graft copolymer can be separated from the solvent, isolated by volatilizing the solvent, for example in a devolatilizing extruder, and extruded into a desired shape such as a sheet, tube or the like. This graft copolymer can be blended with a poolyolefin matrix.
Type:
Grant
Filed:
January 31, 1992
Date of Patent:
July 20, 1993
Assignee:
Rohm and Haas Company
Inventors:
Casmir S. Ilenda, Newman Bortnick, William J. Work