Abstract: A composition for and method of dispersing particles of hydraulic cement in a slurry of hydraulic cement in water, wherein the composition is the reaction product of a ketone, an aldehyde, a cyanide and, optionally, a sulfite. The dispersant properties of the composition can be enhanced by further reacting the composition with hydroxide.
Abstract: Retarded acid soluble well cement compositions which set into hard substantially impermeable masses and methods of using such compositions for forming removable cement plugs or seals in subterranean zones are provided. The compositions are comprised of magnesium oxychloride cement and a set retarder comprised of a water soluble borate and a sugar.
Type:
Grant
Filed:
December 23, 1992
Date of Patent:
January 25, 1994
Assignee:
Halliburton Company
Inventors:
Patty L. Totten, Bobby G. Brake, Edward F. Vinson
Abstract: Improved set retarded cement compositions and methods of using such compositions which are substantially non-thinning at high temperatures and which can include fresh or salt water are provided. The compositions are comprised of hydraulic cement, sufficient water to form a pumpable slurry, a set retarder and a delayed viscosifying agent which yields viscosity at high temperatures comprised of a treated depolymerized galactomannan gum.
Type:
Grant
Filed:
November 9, 1992
Date of Patent:
December 28, 1993
Assignee:
Halluburton Company
Inventors:
Patty L. Totten, Donald W. Lindsey, Bobby J. King
Abstract: The present invention provides improved soil-cement compositions and methods of forming subterranean cementitious masses using the compositions. The soil-cement compositions are basically comprised of hydraulic cement, water present in the compositions in amounts sufficient to form slurries of the solids therein, a dispersant comprised of a mixture of sodium dihydrogen phosphate buffer, ferrous lignosulfonate, ferrous sulfate and tannic acid and soil present in an amount whereby the volume ratio of cement, water and dispersant to soil in the compositions is in the range of from about 0.3:1 to about 2.1:1.
Abstract: Set retarded ultra fine cement compositions which remain pumpable for a predictable period of time at temperatures up to about 240.degree. F. are provided. The compositions are basically comprised of an ultra fine hydraulic cement, sufficient water to form a pumpable slurry and a set retarder comprised of a methylenephosphonic acid derivative.
Abstract: The present invention provides set retarding additives, set retarded hydraulic cement compositions including such additives and methods of using the cement compositions for cementing zones in wells. The set retarding additives are graft polymers comprised of a backbone sugar having one or more pendant polymerized or copolymerized vinyl compounds grafted thereto.
Abstract: This invention relates to a method of terminating the undesirable flow of water from a highly permeable portion of a portion of or a fracture in a subterranean formation into a wellbore, which method involves the use of a hydraulic cement consisting of discrete particles having a particle size not greater than about 30 microns. The cement, which is utilized in a slurry of a hydrocarbon liquid and a surfactant, has a low density, good thixotropic properties and, in one embodiment, expansive characteristics.
Type:
Grant
Filed:
April 3, 1992
Date of Patent:
August 24, 1993
Assignee:
Halliburton Company
Inventors:
Jeffrey A. Dahl, E. Dwyann Dalrymple, James R. Stanford
Abstract: A new method is provided for improved degradation of metal-crosslinked polymer gels which are useful in oil and gas well treating operations. In this method an esterified carboxylated chelator is added to the gel. At elevated temperatures, the esterified chelator undergoes hydrolysis to form an acid and an active ligand which subsequently removes the crosslinking metal ion from the gel and hydrolyses the polymer.
Abstract: A new method is provided for improved degradation of metal-crosslinked polymer gels which are useful in oil and gas well treating operations. In this method an esterified carboxylated chelator is added to the gel. At elevated temperatures, the esterified chelator undergoes hydrolysis to form an acid and an active ligand which subsequently removes the crosslinking metal ion from the gel and hydrolyses the polymer.
Abstract: Retarded acid soluble well cement compositions which set into hard substantially impermeable masses and methods of using such compositions for forming removable cement plugs or seals in subterranean zones are provided. The compositions are comprised of magnesium oxychloride cement and a set retarder comprised of a water soluble borate and a sugar.
Type:
Grant
Filed:
July 31, 1992
Date of Patent:
June 22, 1993
Assignee:
Halliburton Company
Inventors:
Patty L. Totten, Bobby G. Brake, Edward F. Vinson
Abstract: Low density well cement compositions which set into hard substantially impermeable masses, but which are removable by dissolution in acid, and methods of utilizing such compositions for forming removable cement plugs or seals in subterranean zones are provided. The compositions are comprised of pumpable foamed slurries of magnesium oxychloride cement.
Abstract: Methods of completing a well bore having a conduit disposed therein where portions of the well bore and conduit are positioned substantially horizontally in a subterranean producing formation are provided. A hardenable resin composition coated particulate solid material is placed in the annulus between the sides of the well bore and the conduit, and the resin composition is caused to harden whereby the particulate material is consolidated into a hard permeable mass. An aqueous cement slurry is introduced into the permeable consolidated particulate material whereby horizontal sections thereof are isolated which allows tests and/or treatments in selected portions of the horizontal well to be performed.
Abstract: A method of treating a clay-containing subterranean formation with an aqueous fluid is disclosed. The method features the use of quaternary ammonium compounds as additives to control formation damage caused by contacting the formation with the aqueous fluid.
Abstract: A method of temporarily reducing fluid loss into a subterranean formation from a well bore penetrating the formation by way of at least one perforation is provided. A first soluble particulate solid material is introduced into the formation by way of the perforation having a particle size whereby it bridges on the face of the formation and fills the perforation but allows fluid flow therethrough. A second soluble particulate solid material is introduced into the well bore having a particle size such that it bridges on the first particulate solid material and forms a seal over the perforation within the well bore.
Abstract: The present invention relates to methods of preparing and using substantially debris-free gelled aqueous well treating fluids containing a cellulose gelling agent. The preparation methods comprise the steps of forming a gelled aqueous fluid and then mixing an amine phosphonate compound therewith to cause the hydration of unhydrated gelling agent remaining therein.
Abstract: Improved set retarded cement compositions and methods of using such compositions which are substantially non-thinning at high temperatures and which can include fresh or salt water are provided. The compositions are comprised of hydraulic cement, sufficient water to form a pumpable slurry, a set retarder and a delayed viscosifying agent which yields viscosity at high temperatures comprised of a treated depolymerized galactomannan gum.
Type:
Grant
Filed:
September 27, 1991
Date of Patent:
February 9, 1993
Assignee:
Halliburton Company
Inventors:
Patty L. Totten, Donald W. Lindsey, Bobby J. King
Abstract: The water permeability and the production of salt water from a subterranean oil bearing formation is reduced by introducing a viscous aqueous polymer composition into the formation which will subsequently form a crosslinked gel therein, and thereafter introducing a hydrocarbon cement slurry into the formation.
Abstract: A gelable silicate solution prepared by mixing fumed silica and an alkali metal hydroxide with water is provided. The silicate solution is used to form a seal or plug in one or more subterranean formations or in a well bore penetrating the formations by pumping the solution into a desired location in the well bore or formations and allowing the silicate solution to gel therein.
Abstract: Well completion methods utilizing rubber latex compositions are provided. The compositions are comprised of an aqueous suspension of rubber, a vulcanizing agent and a vulcanization activator, and are placed in a subterranean formation or a well bore at a desired location therein and allowed to vulcanize whereby a solid rubber plug or seal is formed.
Type:
Grant
Filed:
June 27, 1991
Date of Patent:
November 3, 1992
Assignee:
Halliburton Company
Inventors:
David D. Onan, Garland W. Davis, Roger S. Cromwell
Abstract: A composition for and method of performing primary cementing operations is disclosed. The method comprises the use of a water slurry of a thixotropic cementing composition which rapidly develops sufficient static gel strength to reduce if not eliminate annular gas migration.