Patents Represented by Attorney Tod A. Waldrop
  • Patent number: 8349215
    Abstract: The invention relates to the use of salts of compound of the formula (1) and amines of the formula (2), where R1 means C8- to C30-Alkyl or C8- to C30-Alkenyl, R2 means hydrogen or a group of the formula -(A-O)x—H, R3, R4 mean hydrogen, C1- to C4-Alkyl or a group of the formula -(A-O)x—H, A means C2- to C4-Alkylene, and x means a number from 1 to 10, as water-soluble or water-dispersible corrosion inhibitors.
    Type: Grant
    Filed: December 10, 2008
    Date of Patent: January 8, 2013
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Dirk Leinweber, Alexander Roesch, Michael Feustel
  • Patent number: 8350092
    Abstract: The invention relates to a process for preparing ?-aminoacetals substantially in racemic form, comprising a step of oxidizing optically enriched ?-aminoacetals to the corresponding oximes, in the presence of a catalyst, and a step of reducing the oximes thus obtained.
    Type: Grant
    Filed: May 21, 2008
    Date of Patent: January 8, 2013
    Assignee: Clariant Specialty Fine Chemicals (France)
    Inventors: Muriel Albalat, Geraldine Primazot, Didier Wilhelm, Jean-Claude Vallejos
  • Patent number: 8350080
    Abstract: A method is described for producing acyl glycinate salts of formula (II) in which R1 represents a saturated linear or branched alkyl radical comprising 1 to 21 carbon atoms or a monounsaturated or polyunsaturated linear or branched alkenyl radical comprising 2 to 21 carbon atoms, and B represents a cation, and/or the corresponding protonated acyl glycinic acid. Said method is characterized in that one or more fatty acid monoethanol amides of formula (I) in which R1 has the meaning indicated above is/are oxidized with oxygen in the presence of an optionally supported bimetallic catalyst consisting of gold and a metal from group VIII of the periodic table in the alkaline medium in order to obtain one or more acyl glycinate salts of formula (II). In order to produce the protonated acyl glycinic acids, the acyl glycinate salt/s of formula (II) is/are additionally reacted with an acid.
    Type: Grant
    Filed: January 7, 2009
    Date of Patent: January 8, 2013
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Peter Klug, Achim Stankowiak, Oliver Franke, Franz-Xaver Scherl, Ulf Pruesse, Nadine Decker, Klaus-Dieter Vorlop
  • Patent number: 8350058
    Abstract: The invention relates to a method for producing alkenyl succinic anhydrides of formula (1), in which R represents a C4 to C250 alkylene radical that can be linear or branched. The method involves the reaction of maleic acid, maleic anhydride, fumaric acid or esters thereof and an alkene which contains 4-250 carbon atoms at from 150 to 250° C. in the presence of a synergistic mixture of a primary antioxidant, a secondary antioxidant, and a metal deactivator.
    Type: Grant
    Filed: December 3, 2005
    Date of Patent: January 8, 2013
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Dirk Leinweber, Tobias Rau
  • Patent number: 8338483
    Abstract: The invention relates to a method for producing acylglycinates of formula (I) wherein R1 represents a linear or branched, saturated alkanoyl group having between 6 and 30 carbon atoms, or a linear or branched, mono- or polyunsaturated alkenoyl group having between 6 and 30 carbon atoms, and Q+ represents a cation selected from the alkali metals Li+, Na+ and K+, characterised in that glycine comprises fatty acid chloride R1Cl, wherein R1 which has the meaning given in formula (I), is provided in water and in presence of a basic alkali compound, the cations Q+ are selected from Li+, Na+ and K+, but in the absence of organic solvents, is reacted at between 30-35 DEG C, and the proportion of fatty acid chloride R1Cl containing acyl groups R1 having 18 or more carbon atoms, in relation to the total amount of used fatty acid chloride, is less than 2.0% in wt.
    Type: Grant
    Filed: November 14, 2008
    Date of Patent: December 25, 2012
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Peter Klug, Franz-Xaver Scherl
  • Patent number: 8298402
    Abstract: The present invention relates to alkylphenol-aldehyde resins containing oligo- or polymers having a repeat structural unit of the formula where R1 is a branched alkyl or alkenyl radical which has from 10 to 40 carbon atoms and bears at least one carboxyl, carboxylate and/or ester group, R2 is hydrogen or R1 R3 is hydrogen or an alkoxy group of the formula -(A-O)m—H, A is a C2- to C4-alkylene group, m is from 1 to 100, R4 is hydrogen, a C1- to C11-alkyl radicals or a carboxyl group, R5 is C1-C200-alkyl or -alkenyl, O—R6 or O—C(O)—R6, R6 is C1-C200-alkyl or -alkenyl, n is from 1 to 100 and k is 1 or 2.
    Type: Grant
    Filed: September 22, 2006
    Date of Patent: October 30, 2012
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Matthias Krull, Carsten Cohrs, Heidi Rausch
  • Patent number: 8293690
    Abstract: The invention relates to dispersions comprising I) at least one polymer that is effective for mineral oils as a cold extrusion improver and is soluble in oil, II) at least one organic solvent that cannot be mixed with water, III) water, IV) at least one alkanolamine salt of a polycyclic carboxylic acid as a dispersing agent, and V) possibly at least one organic solvent that can be mixed with water.
    Type: Grant
    Filed: June 28, 2007
    Date of Patent: October 23, 2012
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Michael Feustel, Matthias Krull, Christoph Kayser, Mario Loew
  • Patent number: 8293910
    Abstract: The invention relates to a one-pot reaction for the production of 3,7-diaza-bicyclo[3.3.1]nonane compounds, wherein in a first step a dicarboxylic acid ester is reacted with a pyridine aldehyde and a primary amine. The piperidone created in this manner is reacted with formaldehyde and a further primary amine in a second step. It is essential to the invention that both reaction steps are carried out in a one-pot variation in a C1-C4 alcohol as the solvent, and that the reaction water created is removed by means of distillation.
    Type: Grant
    Filed: August 17, 2009
    Date of Patent: October 23, 2012
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Melanie Sajitz, Steve Laborda, Peter Naumann, Michael Wessling
  • Patent number: 8283298
    Abstract: Mineral oil distillates having an aromatics content of less than 21% by weight, a water content of less than 150 ppm and a conductivity of at least 50 pS/m, and comprising from 0.1 to 200 ppm of at least one alkylphenol-aldehyde resin (constituent I) which includes a structural element of the formula in which R5 is C1-C200-alkyl or C2-C200-alkenyl, O—R6 or O—C(O)—R6, R6 is C1-C200-alkyl or C2-C200-alkenyl and n is from 2 to 100, and from 0.1 to 200 ppm of at least one polar oil-soluble nitrogen compound (constituent II), excluding those mineral oil distillates in which between 0.001 and 10 ppm of an oil-soluble, organic sulfonic acid-ammonium salt are present.
    Type: Grant
    Filed: July 28, 2006
    Date of Patent: October 9, 2012
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Matthias Krull, Werner Reimann
  • Patent number: 8262927
    Abstract: The invention provides a process for working up glycol-containing aircraft deicers, by (1) removing the suspended impurities from the used aircraft deicer, (2) treating the product thus obtained in such a way that the thickeners present therein are no longer capable of gel formation, (3) before or after step (2) establishing a pH of >7, (4) and then fractionally distilling off the glycols.
    Type: Grant
    Filed: December 2, 2009
    Date of Patent: September 11, 2012
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Bernhard Kropac, Wolfgang Kerbl, Erich Gatter
  • Patent number: 8205753
    Abstract: This invention relates to the use of a compound of the formula (I) where R1 is a hydrocarbon group having 1-40 carbon atoms, R2 is an aliphatic hydrocarbon group having 2-4 carbon atoms, and also R3 is an alkoxy group, n is in the range from 1 to 50, and m is 1 or 2, as flotation reagent in silicate flotation R1—O—R2—NH(2-m)—[(R3)n—H]m??(I).
    Type: Grant
    Filed: February 26, 2007
    Date of Patent: June 26, 2012
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Klaus-Ulrich Pedain, Tobias Rau
  • Patent number: 8187581
    Abstract: The invention provides surfactant-containing cosmetic, dermatological, and pharmaceutical agents comprising at least one water-soluble or water-swellable copolymer obtainable by free-radical copolymerization of A) acryloyldimethyltaurine and/or acryloyldimethyltaurates, B) if desired, one or more further olefinically unsaturated, noncationic comonomers, C) if desired, one or more olefinically unsaturated, cationic comonomers, D) if desired, a silicon-containing component(s), E) if desired, a fluorine-containing component(s), F) if desired, one or more macromonomers, G) the copolymerization taking place if desired in the presence of at least one polymeric additive, H) with the proviso that component A) is copolymerized with at least one component selected from one of the groups D) to G).
    Type: Grant
    Filed: December 21, 2007
    Date of Patent: May 29, 2012
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Matthias Löffler, Roman Morschhäuser, Christoph Kayser
  • Patent number: 8172089
    Abstract: The invention relates to the use of a compound of formula R—N-[A-NH2]2??(1) wherein R represents a linear or branched alkyl group or alkenyl group having 6 to 20 carbon atoms while A represents a C2 to C4 alkylene group, as collector in silicate flotation.
    Type: Grant
    Filed: April 16, 2007
    Date of Patent: May 8, 2012
    Assignee: Clarient Finance (BVI) Limited
    Inventors: Klaus-Ulrich Pedain, Tobias Rau, Michael Patzke
  • Patent number: 8163784
    Abstract: The present invention relates to biocidal compositions comprising at least one biocidal active substance and at least one solvent from the group of polyglycol monobutyl ethers, and to their use as preservatives and disinfectants. More specifically, the invention provides compositions comprising a) at least one biocidal active substance b) at least one solvent according to the formula I R—(O—CH2—CH2)x—O—H??(I) in which R is a linear or branched butyl group and x is a number from 3 to 10.
    Type: Grant
    Filed: September 6, 2006
    Date of Patent: April 24, 2012
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Uwe Falk, Michael Marcus Walter
  • Patent number: 8153567
    Abstract: The invention provides for the use of at least one oil-soluble polyoxyalkylene compound, this polyoxyalkylene compound being an oil-soluble ester, ether or ether/ester of alkoxylated polyols having at least three repeat alkoxy units derived from alkylene oxides having from 2 to 5 carbon atoms per OH group of the polyol which bears at least two aliphatic hydrocarbon radicals having from 12 to 30 carbon atoms for improving the response behavior of mineral oil cold flow improvers in middle distillates which comprise at least one ashless, nitrogen-containing detergent additive which is an oil-soluble amphiphilic compound which comprises at least one alkyl or alkenyl radical which is bonded to a polar group, the alkyl or alkenyl radical comprising from 10 to 500 carbon atoms and the polar group comprising 2 or more nitrogen atoms.
    Type: Grant
    Filed: December 22, 2006
    Date of Patent: April 10, 2012
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Matthias Krull, Robert Janssen, Werner Reimann
  • Patent number: 8148530
    Abstract: The present invention relates to a process for the preparation of 3,7-diazabicyclo[3.3.1]nonane compounds. According to the invention, in a first step, a dicarboxylic acid ester is reacted with a pyridine aldehyde and a primary amine. The piperidone which forms is reacted in a second stage with formaldehyde and a further primary amine. It is essential to the invention that, in the first reaction stage, a C2-C4-alcohol is used as solvent and, in the second reaction stage, a C3-C4-alcohol is used as solvent.
    Type: Grant
    Filed: June 10, 2006
    Date of Patent: April 3, 2012
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Michael Wessling, Barbara Duecker, Nicole Nitschke
  • Patent number: 8133852
    Abstract: The invention provides compositions comprising at least one alkylphenol resin (constituent I) and, based on the alkylphenol resin, from 0.05 to 10% by weight of at least one salt of an aromatic base and of a sulfonic acid (constituent II).
    Type: Grant
    Filed: July 28, 2006
    Date of Patent: March 13, 2012
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Matthias Krull, Klaus Mikulecky, Carsten Cohrs, Hildegard Freundl
  • Patent number: 8123930
    Abstract: The invention thus provides crude oils and products which have been produced therefrom and comprise distillation residues, comprising at least one alkylphenol-aldehyde resin having a repeat structural unit of the formula where R1 is a branched alkyl or alkenyl radical which has from 10 to 40 carbon atoms and bears at least one carboxyl, carboxylate and/or ester group, R2 is hydrogen or R1 R3 is hydrogen or an alkoxy group of the formula -(A-O)m—H, A is a C2- to C4-alkylene group, m is from 1 to 100, R4 is hydrogen, a C1- to C11-alkyl radical or a carboxyl group, R5 is C1-C200-alkyl or -alkenyl, O—R6 or O—C(O)—R6, R6 is C1-C200-alkyl or -alkenyl, n is from 1 to 100 and k is 1 or 2, the use of the alkylphenol-aldehyde resin for splitting emulsions of water and crude oils or products derived therefrom, the use of the alkylphenol-aldehyde resin for improving the cold flowability of crude oils and products derived therefrom, and the use of the alkylphenol-aldehyde resin as an asphaltene dispersant in crude
    Type: Grant
    Filed: September 22, 2006
    Date of Patent: February 28, 2012
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Carsten Cohrs, Matthias Krull, Michael Feustel, Heidi Rausch
  • Patent number: 8101804
    Abstract: A subject-matter of the present invention is a novel process for the synthesis of (E)-stilbene derivatives targeted at obtaining in particular resveratrol and piceatannol.
    Type: Grant
    Filed: July 25, 2007
    Date of Patent: January 24, 2012
    Assignee: Clariant Specialty Fine Chemicals (France)
    Inventors: Alain Schouteeten, Sébastien Jus, Jean-Claude Vallejos
  • Patent number: 8101785
    Abstract: The invention relates to a method for producing fatty acid alkanol amides by reacting at least one amine that contains at least one primary or secondary amino group and at least one hydroxyl group with at least one fatty acid to form an ammonium salt, said ammonium salt being subsequently converted into the alkanol amide by means of microwave radiation.
    Type: Grant
    Filed: October 5, 2007
    Date of Patent: January 24, 2012
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Matthias Krull, Roman Morschhaeuser, Peter Klug, Alexander Lerch, Christoph Kayser, Helmut Ritter, Sarah Schmitz