Abstract: The present invention relates to a radiation curable and developable polyurethane which is characterized by having a carboxy group in its main chain and a acryloyl group in its side chain and comprising the following repeat units (I), (II), and (II) in a random arrangement: wherein R1, R2, R3, R4, and T are defined in the specification. The polyurethane has a weight molecular weight measured by GPC in a range of from 3,000 to 400,000; an acid value in a range of from 5 to 120 mgKOH/g. The present invention also relates to a radiation curable and developable composition containing the polyurethane.
Type:
Grant
Filed:
March 20, 2008
Date of Patent:
May 3, 2011
Assignee:
AGI Corporation
Inventors:
Wei Hsiang Huang, Ying Jen Chen, Jui Ming Chang, Chun Hung Kuo, Hong Ye Lin, Li Chung Chang
Abstract: This invention provides a novel process for preparing soluble phthalocyanines by microwave irradiation in the absence of any organic solvent. Three different starting materials, i.e. t-butylphthalic anhydride, t-butyl phthalonitrile and metal-free H2Pc (tetra-t-butylphthalocyanine) have been adopted, respectively. The starting material with proper metal compound, such as chloride or acetate were irradiated in a commercial microwave oven for a period of 1 to 30 minutes at a power of 200˜900 W. This process is noted to reduce drastically reaction time of MPc formation from 8˜24 hours to 10˜30 minutes due to its unique heating by microwave irradiation. Sandwiched type MPc2 (such as Lu Pc2) can be produced only through metal replacement from metal-free phthalocyanine by microwave irradiation.
Type:
Grant
Filed:
June 26, 2001
Date of Patent:
December 10, 2002
Assignees:
Agi Corporation, National Tsing Hua University
Inventors:
Andrew Teh Hu, Tsai-Wie Tseng, Herng-Dar Hwu, Lung-chang Liu, Chung-Chun Lee, Ming-Chia Lee, Jun-Rong Chen