Abstract: Chlorophosphorus compounds are produced in a loop apparatus wherein chlorine is added to a recycling medium comprising chlorophosphorus compound and elemental phosphorus.

Abstract: Surfactant mixtures are prepared in a fluid "G" phase of more than 50% concentration, the mixtures comprise different surfactant products selected respectively from at least two of the following classes, that is to say alkyl sulphates, alkyl ether sulphates, olefin sulphonates, alkyl benzene sulphonates, alkyl sulphosuccinates, alkyl ether sulphosuccinates, alkyl sulphosuccinamates, paraffin sulphonates, fatty carboxylates, alkyl ether carboxylates, alkyl phosphates, alkyl ether phosphates, alkyl phenol sulphates, alkyl phenyl ether sulphates, alkyl phenyl ether sulphonates, fatty ester sulphonates, fatty acid sulphonates, acyl sarcosinates and acyl taurides.

Abstract: An improved process for manufacturing tetrakis (hydroxymethyl) phosphonium amide condensation product without the formation of a precipitate. Urea or thiourea is added to the tetrakis (hydroxymethyl) phosphonium salt having an anion formed from a dibasic or tribasic or polybasic acid. The said salt is in aqueous solution. The pH of the aqueous solution of said salt is adjusted to the range of 4-6.5 when the urea or thiourea is added to the salt. The proportion of said salt to said urea or thiourea is 1:0.05-0.5 (molar). The sulphuric acid salt is preferred. The process produces an improved aqueous product substantially free of insolubles.

Abstract: When preparing hop extract containing iso-alpha-acids, improved yield of iso-alpha-acids is obtained by contacting a solution of extracted alpha-acids in a water-immiscible non-polar liquid with a sufficiently strong aqueous solution of acid to provide a pH of less than 1 in an aqueous phase that separates from the non-polar liquid. After contacting with the acid, the alpha-acids are isomerized such as by forming alpha acid salts and heating the salts.

Abstract: Aluminium polishing solutions containing phosphoric, nitric and sulphuric acids provide etched finishes if the proportion of sulphuric acid is increased. The invention inhibits such etching by addition to the bath of an aromatic ring compound in which at least 2 hetero atoms are conjugated with the ring such as benztriazole.

Abstract: Mixtures of amphoteric and anionic surfactants are obtained as concentrated aqueous systems in the G phase.

Abstract: In the manufacture of detergent powders containing alkoxylated alcohols, the problem arises that the alcohols cannot be spray-dried with the rest of the constituents. The invention provides a method of incorporating the alcohols into the spray-dried powder in such a way that staining of the packages does not occur. This is done by adding the alcohols in the form of a solution which combines with the residual water in the powder to form a gel.

Abstract: Alkyl sulphates are prepared in a high concentration by mixing together an alkyl sulphuric acid and ammonium or an amine in the presence of sufficient water to maintain the product in the G phase above the minimum concentration at which gel formation is encountered.

Abstract: Wet process phosphoric acid may be purified by solvent extraction to produce a product of greater purity and concentration than has hitherto been attainable by employing an acyclic hexanone, preferably methyl isobutyl ketone as the solvent. Preferably the extraction of the acid into the ketone and the release into water are carried out in 2 actual or theoretical counter-current stages. Alternatively the release may be carried out into an aqueous solution of a base.

Abstract: Aluminium polishing solutions containing phosphoric, nitric and sulphuric acids provide etched finishes if the proportion of sulphuric acid is increased. The invention inhibits such etching by addition to the bath of an aromatic ring compound, in which at least 2 hetero atoms are conjugated with the ring such as benztriazole.

Abstract: Tricycloalkyltin halides, e.g. tricyclohexyltin chloride, which is an intermediate for making the biocide tricyclohexyl tin hydroxide, are made by adding a solution of the cyclo alkyl magnesium halide in an ether to a solution of stannic halide in a liquid diluent, the weight percentage of stannic halide to diluent being less than 25%.

Abstract: Phosphate values can be recovered from an organic extract which is formed by contact of wet process phosphoric acid and a water immiscible solvent, in a process in which the extract is treated with an inorganic base or a dihydrogen phosphate salt to give an acid free solvent and an aqueous solution of phosphoric acid and phosphate salt with a cation to P usually in the 0.1 - 0.5 : 1 region. The aqueous solution represents a concentrated soluble phosphate source for subsequent neutralization and conversion to e.g. tripolyphosphates.

Abstract: Aralkylene-phenol resins may be cured by reaction with 5 - 90% of condensates of formaldehyde and a nitrogen containing compound, e.g. melamine to give cured products having high temperature strength and/or a high comparative tracking index.

Abstract: A process for flameproofing cellulosic textile fibres which comprises impregnating the fabric with an aqueous solution containing a pre-condensate of urea and a THP salt together with any excess of the THP salt necessary to make up a ratio of urea to THP lying between 0.05:1 and 0.25:1 molar, the solution being neutralized by the addition of an alkali or base to a pH in the range 5 to 8, and treating the impregnated fibres with ammonia to form a cross-linked polymer.

Abstract: It is known to attempt to plate chromium from a solution containing trivalent chromium salts and organic complexants. The invention provides an aqueous chromium electroplating system containing trivalent chromium together with both a formate or acetate and a bromide. Optionally the solution also contains ammonium, borate, chloride, sulphate and alkali metal ions and a wetting agent. The invention has the advantage of providing a solution with commercially acceptable covering and throwing power whose effluent can easily be purified to acceptable standards.

Abstract: It is known to attempt to plate chromium from a solution containing trivalent chromium salts and organic complexants. The invention provides an aqueous chromium electroplating system containing trivalent chromium, together with both a formate or acetate and a bromide. Optionally the solution also contains ammonium, borate, chloride, sulphate and alkali metal ions and a wetting agent. The invention has the advantage of providing a solution with commercially acceptable covering and throwing power whose effluent can easily be purified to acceptable standards.

Abstract: Aluminium polishing solutions containing phosphoric, nitric and sulphuric acids provide etched finishes if the proportion of sulphuric acid is increased. The invention inhibits such etching by addition to the bath of an aromatic ring compound, in which at least 2 hetero atoms are conjugated with the ring such as benztriazole. .Iadd.