Abstract: A quantity of electrons that will be used in the ionization event in an FTICR MS is preprogrammed. When the number of electrons produced reaches that number, the electron beam is turned off. This approach assures that the same number of electrons are used for every measurement and eliminates the variations due to fundamental characteristics of the electron sourcere and the variations in temperature due to changing ambient conditions.

Abstract: The total number of ions created br obtained during an ionization or ion introduction event in a Fourier transform ion cyclotron resonance mass spectrometer are determined either by using an on-resonance experimental technique or an off-resonance experimental technique. Both techniques exploit ion magnetron motion. In the on-resonance technique the spectrometer is excited in the magnetron mode and the single resonance signal resulting from this excitation is detected to determine the total number of ions. In the off-resonance technique the magnetron mode is excited at a frequency that is near the magnetron frequency while simultaneously detecting the resulting ion motion. The off-resonance technique leaves the ion population in a state that is amenable to subsequent analysis.

Abstract: An electrical feed through for use in a high temperature oven such as the oven in a gas chromatograph. The feed through includes printed circuit boards which are maintained in compression to prevent the boards from physically separating at the elevated temperatures used in the oven. The structure that provides the compression also does not allow any flexure, torsional or longitudinal stress on the boards. The boards include an enhanced connector pad which is made from a continuous annular copper ring which is connected to all of the conductive layers of the board.

Abstract: In a fractional distillation tower which is divided into a plurality of sections by total drawoff trays, and wherein at least one fraction is withdrawn from each section. The cut point temperature between fractions is determined based on the partial pressure and temperature of the vapor in the upper portion of a section. The thus determined cut point temperature may be compared to a set point with the results of the comparison being utilized to maintain the actual cut point temperature between fractions substantially equal to the desired cut point temperature.

Abstract: A power supply system for a dynamic memory includes a main power supply, a backup power supply and a power down detection circuit which are all connected in parallel across the input of a DC/DC converter. In turn the DC/DC converter supplies regulated power to the dynamic memory. On interruption of the main power supply, the backup supply provides input power to the DC/DC converter only as long as the power sensed by the power down detection circuit is adequate for the DC/DC converter to maintain a bit pattern stored in the dynamic memory. On sensing inadequate input power to the DC/DC converter the backup supply is automatically disconnected.

Abstract: An apparatus and method for the ion chromatographic analysis of ionic species of a common first polarity opposite to a second polarity employ an eluant ion suppressor cell having two electrodes. The ionic species to be analyzed and an eluant solution are introduced in solution to an ion exchange resin bed. The eluant solution essentially consists of an eluting reagent in solution such that the eluting reagent is ionized to form first eluant ions of the first polarity and second eluant ions of the second polarity. An effluent essentially consisting of separated ionic species, first eluant ions and second eluant ions in solution is discharged from the resin bed. The effluent is introduced through an inlet in the suppressor cell such that the effluent flows along a surface of the first and second electrodes. An electrical voltage is applied to the electrodes so as to maintain the first electrode at the first polarity and the second electrode at the second polarity.

Abstract: In an absorption process utilizing a feed gas compressor, the absorption pressure is maximized within the constraints of the system by a computer controller that automatically increases the pressure until a constraint for compressor speed or absorption pressure is encountered. The control action coordinately manipulates compressor speed and the absorption pressure in response to the actual compressor suction pressure to achieve the desired result.

Abstract: A linear equation which infers elution time in a gas chromatograph as a function of temperature is assigned to a chemical compound. The linear equation is useful in constructing a computer data base which contains a long list of chemical compounds, a list of chromatographs each having a separation column containing a different adsorbent material, and a long list of linear equations associating each chemical compound with each chromatograph. The data base, which is arranged for computer searching, aids researchers in gas chromatography by automating a systematic search for optimum combination of separation columns and operating parameters.

Abstract: The efficiency of a furnace is determined by determining the percentage of the heat supplied to the furnace in the form of fuel which is lost due to a plurality of phenomena in the furnace operation. The thus determined efficiency may be displayed for use by an operator or may be utilized for automatic control of the furnace so as to substantially maximize the efficiency of the furnace.

Abstract: A computer system for a zone fired furnace generates a plurality of temperature set point signals for a plurality of furnace zones. The set point signals are derived from a master controller acting on the measured temperature of fluid that is heated in the plurality of furnace zones and then combined to form a heated stream. The master signal, which is a velocity type signal, is provided to a plurality of zone control stations corresponding to the plurality of furnace zones. Each zone control station integrates the master signal, and then biases the master signal for use as a zone temperature set point. The zone control station can be used to bias the individual coils so as to balance the temperature of the coils with respect to each other, or to intentionally unbalance one or more coils, as desired, so as to improve furnace operations.

Abstract: A tuning adjustment for a PI controller is disclosed which produces a desired response for a controlled variable in a selective control loop having an external reset feedback signal for anti-reset-windup protection. The desired control effect is evident in the time response of the controlled variables return to set point when a select switches signals and suddenly selects an output limited PI controller to control a process variable, and the selected controller assumes control of the process variable starting with its output at the limiting value. The tuning adjustment is implemented by combining the signal selected for controlling the process variable and a tuning factor for use as the reset feedback signal for the PI controller.

Abstract: A recirculating type analog to digital converter is disclosed which has an auto-zero mode that is introduced prior to each conversion cycle. The loop is based on an arrangement of operational amplifiers and FET switches, and further includes a comparator circuit, a reference voltage source and a microprocessor which are coupled to the loop. Also coupled to appropriate points in the loop are three time gated integrator circuits which generate analog signals which respectively compensate for offset voltages of operational amplifiers in the loop, the offset voltage of the comparator circuit which is coupled to this loop, and the gain of the loop. The compensating signals which are generated in the auto-zero mode are applied to the loop during the conversion cycle.

Abstract: A piston biasing means including, a coil-type spring, adapted to exert pressure on one side of a piston to be biased in a predetermined direction, a spring retaining means which is slidable toward and away from the piston when the spring is compressed and released and centering means, preferably including pivot balls on each end of the spring, so as to make point contact and rolling contact with the piston. A spring adjusting means to adjust the tension on the spring is also included. A piston assembly and valve assembly incorporating the piston biasing means are also described.

Abstract: A supervisory computer automatically equalizes the temperature of effluent streams of a multipass heating system to maximize heat transfer, without substantially disturbing a desired total flow through the heating system. Temperature control is achieved by manipulating the division of a feed stream among the multiple passes. In addition, if the flow in one or more passes cannot be manipulated, the control scheme automatically equalizes the temperatures of the remaining passes. This is accomplished by calculating a flow rate for adjusting the flow through the number of passes under supervisory control to a value, which in addition with any uncontrolled flow, will provide the desired total flow through the heating system. This adjusted flow rate is used as an approximate set point for the flow rate in each controlled pass. The adjusted flow rate signal is modified for control of each individual pass by applyng a bias through a conventional controller acting on a weighted average temperature signal.