Abstract: New polymers are disclosed to be made in supported Ziegler-Natta systems. They include monomers exhibiting polar functionality such as through a hydroxyl group or other functional group protected during polymerization in the presence of highly active catalysts by the use of a protective alkyl silane group which is removed after polymerization to restore the functionality of the group. The typical polymer thus made is a polyolefin having functional groups on its backbone; the functional groups may be reacted with conventional dyes and/or may perform other functions and enter reactions with other reactive compounds.
Abstract: Isophorone is made by the aldol condensation of acetone followed by separate steps to remove acetone, mesityloxide, and beta isophorone. Variations include recycling of mesityloxide and/or beta isophorone.
Type:
Grant
Filed:
September 9, 1993
Date of Patent:
October 4, 1994
Assignee:
Aristech Chemical Corporation
Inventors:
Michael C. Grebinoski, Donald Glassman, Carole L. Elias, Alain A. Schutz
Abstract: Water blown, thermosetting unsaturated polyester-polyurethane hybrid foam compositions are formed by the reaction of an A side composition and a B side composition. The A side composition comprises a polyfunctional isocyanate compound and a free radical initiator. The B side composition comprises a mixture of: (i) an ethylenically unsaturated monomer solution having dissolved therein about 30-90 weight percent of a polyester polyol having at least one ethylenically unsaturated group per molecule which has predominantly hydroxyl end groups; (ii) an amine compound having two or more primary or secondary amine groups in an amount effective to react with the A side composition to form small urea domains finely dispersed within a continuous polyester-polyurethane hybrid phase; and (iii) about 25 to about 150 equivalents water based on 100 equivalents of active hydrogen in the B side.
Type:
Grant
Filed:
February 24, 1993
Date of Patent:
September 6, 1994
Assignee:
Aristech Chemical Corporation
Inventors:
Gary T. Brooks, Harold R. Edwards, Jr., Kathy J. Thrash, Donald E. Rubis, David P. Sinclair
Abstract: Phenol plant waste water containing small amounts of phenol and sodium sulfate is successfully distilled through the addition of recovered sodium sulfate to enhance the volatility of the phenol relative to water; at least a portion of the sodium sulfate is recycled, while a significant portion of the phenol can be returned to the phenol plant for recovery.
Type:
Grant
Filed:
August 4, 1993
Date of Patent:
September 6, 1994
Assignee:
Aristech Chemical Corporation
Inventors:
Thomas H. Bossler, Donald Glassman, Michael C. Grebinoski, Howard H. Morgan, Jr., Jennifer L. Voss
Abstract: A process for making 1,1-bis-(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane via the acid catalyzed reaction of phenol and 3,3,5-trimethylcyclohexanone containing an organic thiol co-catalyst is described wherein the organic thiol is rejuvenated by treatment with a halogen acid and recycled to a fresh mixture of phenol and 3,3,5-trimethylcyclohexanone to make additional 1,1-bis-(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane.
Type:
Grant
Filed:
November 12, 1993
Date of Patent:
August 9, 1994
Assignee:
Aristech Chemical Corporation
Inventors:
Jeffrey S. Salek, Joseph Pugach, Mark R. Rubino
Abstract: New polymers are disclosed to be made in supported Ziegler-Natta systems. They include monomers exhibiting polar functionality such as through a hydroxyl group or other functional group protected during polymerization in the presence of highly active catalysts by the use of a protective alkyl silane group which is removed after polymerization to restore the functionality of the group. The typical polymer thus made is a polyolefin having functional groups on its backbone; the functional groups may be reacted with conventional dyes and/or may perform other functions and enter reactions with other reactive compounds.
Abstract: Carbon electrode impregnating pitch is made from coal tar by centrifugation of the coal tar to remove particulates, followed by milling and distilling the remaining material.
Abstract: Settlement of barnacles on surfaces in a marine environment is inhibited by employing as a construction material for said surface of polymers including methyl methacrylate and an effective amount (preferably about 2% to about 10%) of a copolymerizable N-substituted maleimide.
Type:
Grant
Filed:
April 5, 1993
Date of Patent:
June 7, 1994
Assignee:
Aristech Chemical Corporation
Inventors:
Sharon J. Elliott, Virginia Piermattie, Stanley A. Rice, Theodore R. Wessendorf
Abstract: Crude coal tar is distilled in the form produced in a coke plant. The distillation tower contains a rectification section to retain naphthalene with the other components heavier than benzene. The benzene is removed overhead.
Abstract: A protective film is placed on acrylic sheet. The film has a polyethylene side and an adherent EVA side; it will survive stressful lamination procedures as well as thermoforming, and can be easily removed from a finished article after thermoforming.
Abstract: In the production of bisphenol-A from the reaction of phenol and acetone, values are recovered from a "heavy ends" fraction by passing the fraction through a thin-film evaporator, making a light fraction which is fractionally distilled into three portions, two of which have recoverable proportions of bisphenol-A, and recovering bisphenol-A from at least one of them.
Abstract: New polymers are disclosed to be made in supported Ziegler-Natta systems. They include monomers exhibiting polar functionality such as through a hydroxyl group or other functional group protected during polymerization in the presence of highly active catalysts by the use of a protective alkyl silane group which is removed after polymerization to restore the functionality of the group. The typical polymer thus made is a polyolefin having functional groups on its backbone; the functional groups may be reacted with conventional dyes and/or may perform other functions and enter reactions with other reactive compounds.
Abstract: New polymers are disclosed to be made in supported Ziegler-Natta systems. They include monomers exhibiting polar functionality such as through a hydroxyl group or other functional group protected during polymerization in the presence of highly active catalysts by the use of a protective alkyl silane group which is removed after polymerization to restore the functionality of the group. The typical polymer thus made is a polyolefin having functional groups on its backbone; the functional groups may be reacted with conventional dyes and/or may perform other functions and enter reactions with other reactive compounds.
Abstract: New polymers are disclosed to be made in supported Ziegler-Natta systems. They include monomers exhibiting polar functionality such as through a hydroxyl group or other functional group protected during polymerization in the presence of highly active catalysts by the use of a protective alkyl silane group which is removed after polymerization to restore the functionality of the group. The typical polymer thus made is a polyolefin having functional groups on its backbone; the functional groups may be reacted with conventional dyes and/or may perform other functions and enter reactions with other reactive compounds.
Abstract: A laminating resin comprising (A) an acrylated or methacrylated cycloaliphatic epoxide, (B) an acrylated or methacrylated alkoxylated bisphenol-A, in a weight ratio of (A) to (B) of about 3 to 1 to about 1 to 5, and (C) about 5% to about 50%, based on the total composition, cyclohexyl methacrylate. Vinyl toluene and ethylene glycol dimethacrylate are also used to modify certain properties of the resin.
Abstract: Growth of zebra mussels on a surface is inhibited by making the surface from an unsaturated polyester having copolymerized therein about 1-40% N-phenyl maleimide.
Abstract: Bis(diallylamino) silanes of the formula ##STR1## where R.sup.1 and R.sup.2 are lower alkyl or phenyl groups are copolymerized with lower olefins and desilylated to exhibit amine functionality; they are receptive to dyes.
Abstract: Silyl derivatives of eugenol include compositions of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are independently selected from linear, branched, and cyclic hydrocarbon groups having a total of from one to about eight carbon atoms, except that where one of R.sup.1, R.sup.2 or R.sup.3 is a phenyl group, the total of carbon atoms must be at least nine. They may be made by silylating the corresponding hydroxyl compound. They are useful as comonomers for olefins to introduce functional sites and may be copolymerized in Ziegler-Natta catalyst systems.
Abstract: Bis(diallylamino) silanes of the formula ##STR1## where R.sup.1 and R.sup.2 are lower alkyl or phenyl groups. The silanes may be homopolymerized or copolymerized with lower olefins and desilylated to exhibit amine functionality.
Abstract: Mono and diallyl amines are silylated to protect them from reacting with high activity Ziegler-Natta catalysts so they may be copolymerized with propylene; also disclosed are copolymers of such amines with propylene and their hydrolyzed or alcoholyzed counterparts.
Type:
Grant
Filed:
August 5, 1992
Date of Patent:
September 28, 1993
Assignee:
Aristech Chemical Corporation
Inventors:
Andrew J. Sivak, Leonard A. Cullo, William L. Krayer