Abstract: The invention is targeted mainly at a polymer powder suitable for 3D printing by sintering, comprising: (a) a polymer composition comprising at least one thermoplastic elastomer; (b) a pigment composition comprising at least one pigment exhibiting an absorbance of the light with a wavelength of 1000 nm, as measured according to the standard ASTM E1790, of less than 50%; and also, if appropriate, (c) one or more fillers or reinforcements; and (d) one or more additional additives. The invention is also targeted at a process for the preparation of said powder and also at the use of said powder for 3D printing by sintering. Finally, it is targeted at the use of a pigment exhibiting an absorbance of the light with a wavelength of 1000 nm, as measured according to the standard ASTM E1790, of less than 50% to improve the definition and/or the mechanical properties of the articles printed by a process of 3D printing by sintering of a thermoplastic elastomer powder.

Abstract: The present invention relates to a molding composition, comprising by weight: (A) 38 to 87% of at least one semi-crystalline aliphatic polyamide, (B) 3 to 25% of a hollow glass reinforcement, (C) 5% to 30% glass fibers, (D) 5 to 15% of at least one impact modifier chosen from a polyolefin, a polyether block amide (PEBA-1) and a mixture thereof, the polyolefin and the PEBA-1 having a flexural modulus less than 200 MPa, in particular less than 100 MPa, as measured according to standard ISO 178:2010, at 23° C., (E) 0 to 2% by weight of at least one additive, the sum of the proportions of each constituent of said composition being equal to 100%, the density of the composition being less than 1.12 g/cm3.

Abstract: A process for transfer imprinting using a novel family of anti-sticking layers, such as for nanoimprint lithography processes, is described.

Abstract: The invention relates to the use of a compatible thermoplastic material (film, sheet, or raft) as the base sheet or layer for 3-D printing an article. The use of the base film provides a means of printing a large article, and of reducing warpage by printing directly on the film. The printed article adheres to the film better than to traditional printer surfaces (glass, metal, glue, or reusable films), because the printed article and film weld together by forming chain entanglements, due to being compatible, miscible, or semi-miscible in the melt.

Abstract: The present invention relates to a multilayer composition comprising a surface layer comprising a thermoplastic polymer A and a substrate layer comprising a polymeric composite material based thermoplastic (meth)acrylic matrix and a fibrous material as reinforcement. The multilayer composition is suitable for mechanical or structured parts or articles with a decorative surface aspect The present invention concerns also a manufacturing process for multilayer mechanical or structured parts or articles and three-dimensional mechanical or structured parts.

Abstract: A process for preparing a semifinished product comprising a PAEK-based resin and reinforcing fibers, including: preparing a dispersion comprising a PAEK-based resin in pulverulent form dispersed in an aqueous phase including at least one volatile organic compound and optionally a surfactant; bringing the reinforcing fibers into contact with said aqueous dispersion; drying the fibers impregnated with dispersion; and heating the impregnated fibers to a temperature sufficient for the melting of the resin, so as to form a semifinished product, wherein the aqueous phase of the dispersion has a dynamic viscosity, measured at 25° C. under a shear stress of 6.8 s?1 on a Brookfield DV2T Extra viscometer, is between 0.1 and 25 Pa·s; and wherein when the surfactant is present, its content is less than 1% by weight relative to the mass of dispersed resin.

Abstract: A method of manufacturing an impregnated fibrous material including a fibrous material made of continuous fibers and at least one thermoplastic polymer matrix, the method including pre-impregnating the fibrous material while it is in the form of a roving or several parallel rovings with the thermoplastic material and heating the thermoplastic matrix for melting, or maintaining in the molten state, the thermoplastic polymer after pre-impregnation, the at least one heating step being carried out by means of at least one heat-conducting spreading part (E) and at least one heating system, with the exception of a heated calendar, the roving or the rovings being in contact with part or all of the surface of the at least one spreading part (E) and partially or wholly passing over the surface of the at least one spreading part (E) at the level of the heating system.

Abstract: A polyamide powder for use in a process of powder agglomeration by sintering, including at least one chain limiting agent. A process for preparing a powder including at least one chain limiting agent, wherein the chain limiter is mixed with the polyamide powder, and if need be at least one thioether antioxidant, by dry blending.

Abstract: A method for preparing composite parts, including a step of depositing at least one band of fibrous material impregnated with a thermoplastic polymer on a substrate, by means of a main heating system selected from the following two systems: a preheating system (1) and a heating system (2), in combination with at least one secondary heating system selected from: a heating system (3), a post-heating system (4), a heating system (5), and a preheating system (6), or by means of the two main heating systems (1) and (2), the substrate being previously devoid of any deposited band or comprising at least one band n?1 of said fibrous material, the thermoplastic polymer being amorphous, with a Tg such that Tg?80° C., or semicrystalline, with a Tm?150° C.

Abstract: The invention relates to a powder based on at least one polyether ketone ketone homopolymer or copolymer essentially consisting of, or consisting of, an isophthalic repeating unit and, in the case of the copolymer, a terephthalic repeating unit (T), the isophthalic repeating unit representing at least 85% by weight relative to the total weight of said at least one polyether ketone ketone.

Abstract: A composition including: (A) a copolymer having rigid blocks and flexible blocks (TPE), (B) a non-crosslinked polysiloxane silicone, preferably a non-crosslinked polyorganosiloxane, (C) a compatibilizer, improving the compatibility between the TPE and the silicone, the compatibilizer (C) being chosen from a polyolefin or a mixture of polyolefins, and optionally (D) an additive.

Abstract: Process for producing aminocarboxylic acid of formula (I): NH3—CH2—(CH2)n—COOH (I) including: (i) reacting the unsaturated carboxylic acid of formula (II): CH?CH—(CH2)n-1—COOH (II) with hydrogen bromide to form the ?-bromoalkanoic acid of formula (iii): Br—CH2—(CH2)n—COOH (III); (ii) reacting the w-bromoalkanoic acid obtained with ammonia in aqueous solution to form a reaction mixture; (iii) separating the reaction mixture of the aminocarboxylic acid of formula (I) and an aqueous solution rich in ammonium bromide; (iv) bringing the aqueous solution rich in ammonium bromide into contact with sodium hydroxide to form ammonia and an aqueous solution rich in sodium bromide; (v) purifying the aqueous solution rich in sodium bromide; (vi) bringing the purified aqueous solution rich in sodium bromide into contact with chlorine to form bromine and an aqueous solution rich in sodium chloride; (vii) reacting the bromine with hydrogen to form hydrogen bromide; and (viii) recycling the hydrogen bromide to step (i).

Abstract: The invention relates to the production of (meth)acrylic esters according to a process by direct esterification, and in particular to the purification of a crude reaction mixture comprising a C4-C12 (meth)acrylic ester using a dividing wall column employed in a particular configuration. The dividing wall column is equipped with a separating wall creating separation zones in the column, the wall not being joined to the upper dome of the column in the top part and being joined to the bottom of the column in the bottom part. The process according to the invention guarantees a product of very high purity, independently of the back-cracking reactions of the heavy by-products liable to arise during the purification of the product sought.

Abstract: The invention concerns a composite article, such as a mold part or an extrusion die, made of a composition comprising at least one polyarylether ketone and at least one thermally conductive filler, wherein the composite article has a thermal conductivity of at least 0.5 W/mK. The invention also concerns a composition and uses thereof.

Abstract: The present disclosure relates to liquid compositions including a (meth)acrylic polymer, a (meth)acrylic monomer, and a maturation agent selected from a metal oxide or a metal hydroxide. The (meth)acrylic polymer can contain a monomer carrying a carboxylic acid function and/or the (meth)acrylic monomer can carrying a carboxylic acid function. The liquid compositions can also contain a dynamic viscosity between 10 mPa·s and 10 000 mPa·s at 25° C.

Abstract: The present invention relates to a process for purifying a composition comprising a hydrohalocarbon B comprising the steps of: i) providing a composition A1 comprising a hydrohalocarbon B and at least one impurity C different from said hydrohalocarbon B, ii) compressing said composition A1, and optionally cooling it, so as to obtain said hydrohalocarbon B in liquid form in order to form a liquid stream A2 comprising said hydrohalocarbon B, iii) distilling said stream A2 obtained in step ii) in order to form and recover a stream A3 comprising said hydrohalocarbon B, characterized in that step iii) is carried out in a pressurized distillation device comprising one or more rotating packed beds.

Abstract: The invention relates to a container housing a composition comprising tetrafluoropropene. The container is made from metal and includes an inner surface, said inner surface being in contact with the composition and being at least partially covered with a coating containing zinc. Advantageously, the aforementioned composition comprises at least 15 wt.-% tetrafluoropropene relative to the total weight of the composition.

Abstract: An alkyd polymer composition for fast-drying, low VOC applications is provided. The alkyd polymer incorporates a minimum required level of a cyclic ether- and hydroxyl-containing composition formed from a sugar alcohol during the alcoholysis step while synthesizing the alkyd polymer. The disclosure also relates to the cyclic ether- and hydroxyl-containing composition which must have a minimum required level of cyclic ether structure incorporated therein in order to produce a sufficiently fast-drying alkyd polymer. Methods of making the cyclic ether- and hydroxyl-containing composition and the alkyd polymer comprising, as polymerized units, the cyclic ether- and hydroxyl-containing composition and a poly acid and/or an anhydride compound, as well as an optional polyol, other than the sugar alcohol, are also provided.

Abstract: The present invention relates to a polymer composition comprising a polymer comprising methyl methacrylate, (meth)acrylic acid and styrene monomers. In particular, the present invention relates to a polymer composition comprising a polymer comprising methyl methacrylate, (meth)acrylic acid and styrene monomers, said composition having particularly advantageous compromises of heat-resistant, fluidity, scratch-resistant and chemical-resistant properties. The present invention also relates to a molded or extruded object comprising a polymer comprising methyl methacrylate, (meth)acrylic acid and of styrene monomers, and the use of these objects.

Abstract: The present invention relates to a process for neutralizing a composition A comprising 1-chloro-3,3,3-trifluoropropene, 1,1-dichloro-1,3,3-trifluoropropane and one or more acid compound(s) of formula HX with X?F or Cl; said process comprising the step a) of bringing said composition A into contact with a solution B under conditions capable of limiting the formation of 1-chloro-1,3,3-trifluoropropene.