Patents Assigned to Atofina Research S.A.
  • Publication number: 20120053304
    Abstract: A method for the copolymerization of ethylene and a C3+ olefin copolymer in a loop reactor system and polymers formed therefrom are described herein.
    Type: Application
    Filed: August 24, 2010
    Publication date: March 1, 2012
    Applicant: ATOFINA Research S.A.
    Inventors: Louis Fouarge, Eric Damme, Olivier Miserque, Daniel Siraux, Philippe Bodart, André Lewalle, Marc Van der Auwera, Frans Van den Brande, Giacomo Conti, Hugo Vandaele, Mark Verleysen, Carl Van Camp, Etienne Laurent, Philippe Marechal, Marc Moers, Leopold D'Hooghe, Marjan Sillis, Kai Hortman, Pascal Folie, Renaud Oreins
  • Publication number: 20090143546
    Abstract: A method for controlling the injection of catalyst slurry in a polymerization reactor is described herein. The method includes the preparation of polyethylene with a solid catalyst and a hydrocarbon diluents. The method includes providing solid catalyst and a hydrocarbon diluent in one or more storage vessels such that a catalyst slurry is obtained in said vessel, transferring said catalyst slurry from said storage vessel to a mixing vessel wherein said catalyst slurry is diluted for obtaining a suitable concentration for use in a polymerization reaction, pumping said diluted catalyst slurry at a controlled flow rate from said mixing vessel to said polymerization reactor through one or more conduits, by means of a membrane pump provided in each of said conduits, and the membrane pump is controllable as a function of reactant concentration within the polymerization reactor.
    Type: Application
    Filed: October 1, 2008
    Publication date: June 4, 2009
    Applicant: ATOFINA RESEARCH S.A.
    Inventors: Louis Fouarge, Eric Damme, Olivier Miserque, Daniel Siraux, Philippe Bodart, Andre Lewalle, Marc Van der Auwera, Frans Van den Brande, Giacomo Conti, Hugo Vandaele, Mark Verleysen, Carl Van Camp, Etienne Laurent, Philippe Marechal, Marc Moers, Leopold D'Hooghe, Marjan Sillis, Kai Hortman, Pascal Folie, Renaud Oreins
  • Publication number: 20050272891
    Abstract: The present invention relates to an apparatus and process for polymerizing olefins. One embodiment comprises polymerizing at least one monomer in a first loop reactor in the presence of a catalyst to produce a first polyolefin fraction. A portion of the first polyolefin fraction is transferred to a second loop reactor, connected in series with the first loop reactor. The process further comprises polymerizing in the second loop reactor at least one monomer in the presence of a catalyst to produce a second polyolefin fraction in addition to the first polyolefin fraction. The combination of the first and second polyolefin fractions can produce a polymer resin fluff having bimodal molecular weight distribution.
    Type: Application
    Filed: February 14, 2005
    Publication date: December 8, 2005
    Applicant: ATOFINA Research S.A.
    Inventors: Louis Fouarge, Eric Damme, Olivier Miserque, Daniel Siraux, Philippe Bodart, Andre Lewalle, Marc Auwera, Frans Brande, Giacomo Conti, Hugo Vandaele, Mark Verleysen, Carl Camp, Etienne Laurent, Philippe Marechal, Marc Moers, Leopold D'Hooghe, Marjan Sillis, Kai Hortman, Pascal Folie, Renaud Oreins
  • Patent number: 6946521
    Abstract: A polyethylene resin comprising from 35 to 49 wt. % of a first polyethylene fraction of high molecular weight and from 51 to 65 wt. % of a second polyethylene fraction of low molecular weight, the first polyethylene having a density of up to 0.930 g/cm3, and an HLMI of less than 0.6 g/10 min and the second polyethylene fraction comprising a high density polyethylene having a density of at least 0.969 g/cm3 and an MI2 of greater than 10 g/10 min, and the polyethylene resin, having a density of great 0.946 g/cm3, an HLMI of from 1 to 100 g/10 min, a dynamical viscosity, measured at 0.01 radians/second, greater than 200,000 Pa.s and a ratio of the dynamical viscosities measured at, respectively 0.01 and 1 radians/second greater than 8.
    Type: Grant
    Filed: October 25, 2001
    Date of Patent: September 20, 2005
    Assignees: ATOFINA Research S.A., Solvay Polyolefins Europe-Belgium S.A.
    Inventors: Olivier Miserque, Jacques Michel, Marc Dupire, Fabian Siberdt, Jean-Louis Costa, Serge Bettonville, Virgil Rouyer, Eric Damme
  • Patent number: 6894132
    Abstract: Provided is a catalyst for the polymerization of olefins of general formula: R?(C4R?mC5C4R?n)XMeQ wherein X is an hetero-atom ligand with one or two lone pair electrons selected from the elements of Group VA or VIA which can be substituted or non-substituted: (C4Rm?C5C4Rn?) is a symmetrically substituted, 3,6-substituted fluorenyl; R? is hydrogen or hydrocarbyl radical having from 1-20 carbon atoms, a halogen, an alkoxy, an alkoxy alkyl or an alkylamino or alkylsilylo radical, each R? may be the same or different and m and n independently are 1, 2 3 or 4, with the proviso that the bilateral symmetry is maintained; R? is a structural bridge between X and the (C4R?mC5C4R?n) ring to impart stereorigidity; Q is a hydrocarbyl radical having 1-20 carbon atoms or is a halogen; Me is a Group IIIB, IVB, VB, or VIB metal as positioned in the Periodic Table of Elements; and Me can be in any of its theoretically possible oxidation states.
    Type: Grant
    Filed: June 26, 2003
    Date of Patent: May 17, 2005
    Assignee: Atofina Research S.A.
    Inventor: Abbas Razavi
  • Patent number: 6881493
    Abstract: Uses of syndiotactic/atactic block polypropylene are provided in which the molecular weight thereof is preferably at least 120kD. The syndiotactic/atactic block polypropylene may be used as a polypropylene modifier, a component in an adhesive composition, a shock absorber component, a waterproof membrane component, a packaging film or component thereof, a shapable composition component, and an acoustic absorbent material component, a composition for moulding into a footwear component, a bitumen modifier, a compatibiliser, an emulgator or an emulsifier, as a viscosity improver, and as a spilled oil absorber.
    Type: Grant
    Filed: October 9, 2001
    Date of Patent: April 19, 2005
    Assignee: ATOFINA Research S.A.
    Inventors: Bernard Haveaux, Thierry Coupin
  • Patent number: 6872763
    Abstract: Provided is a vulcanizing agent for vulcanizing bitumen, which vulcanizing agent comprises a sulphur agent and a binder, wherein the vulcanizing agent is in the form of pellets. Further provided is a process for producing a surfacing composition, which process comprises contacting bitumen with an elastomer and the vulcanizing agent of the present invention.
    Type: Grant
    Filed: October 24, 2001
    Date of Patent: March 29, 2005
    Assignee: ATOFINA Research, S.A.
    Inventor: Patrizio Andriolo
  • Patent number: 6863941
    Abstract: An automobile fuel tank comprising at least two components which have been joined together to form a tank having a wall defining a fuel chamber, at least one of the components being injection moulded and defining a part of the wall and composed of a polyethylene having a density of from 0.930 to 0.955 g/cm3, a dispersion index D of from 2 to 3 and a melt index MI2 of from 0.2 to 2 g/10 min.
    Type: Grant
    Filed: January 24, 2003
    Date of Patent: March 8, 2005
    Assignee: ATOFINA Research S.A.
    Inventor: Patrick Detounay
  • Patent number: 6858133
    Abstract: A process for desulfurising an olefin-containing hydrocarbon feedstock including sulfur-containing hydrocarbon compounds as impurities, the process comprising passing a hydrocarbon feedstock containing one or more olefins through a reactor containing a crystalline silicate selected from the group consisting of an MFI-type crystalline silicate having a silicon/aluminum atomic ratio of at least 180 and an MEL-type crystalline silicate having a silicon/aluminum atomic ratio of from 150 to 800 which has been subjected to a steaming step to produce an effluent with an olefin content of lower molecular weight than that of the feedstock and removing hydrogen sulphide from the effluent.
    Type: Grant
    Filed: April 23, 2002
    Date of Patent: February 22, 2005
    Assignee: Atofina Research S.A.
    Inventors: Jean-Pierre Dath, Walter Vermeiren, Koen Herrebout
  • Patent number: 6852764
    Abstract: Provided is a blend comprising: a) from 20 to 60 wt % of a thermoplastic elastomer; b) from 8 to 30 wt % of a vinylaromatic polymer; c) from 10 to 30 wt % of one or more processing aid; d) from 0 to 20 wt % of one or more additives.
    Type: Grant
    Filed: December 7, 2000
    Date of Patent: February 8, 2005
    Assignee: Atofina Research S.A.
    Inventor: Jean-Marie Mlinaric
  • Publication number: 20040249094
    Abstract: Use of isotactic polypropylene homopolymers or copolymers in processes in which the polypropylene solidifies from a melt, wherein for enhanced speed of solidification of the polypropylene the polypropylene has a melt temperature and a crystallisation temperature not more than 50° less than the melt temperature resulting from the polypropylene having been produced using a metallocene catalyst component having the general formula as described herein:
    Type: Application
    Filed: March 3, 2004
    Publication date: December 9, 2004
    Applicant: ATOFINA Research, S.A.
    Inventor: Axel Demain
  • Patent number: 6824886
    Abstract: Use of a homogeneous blend of a metallocene-catalysed medium density polyethylene (mMDPE) with low density polyethylene (LDPE), to produce blown films, this composition essentially consisting of from 0.5 to 99.5 % by weight of mMDPE and from 99.5 to 0.5 % by weight of LDPE, based on the total weight of the blend. The blend is optionally coextruded between layers of LDPE. The compositions of this invention have good processability and are used to make blown films which have the good optical properties of LDPE and the good mechancial and processing properties of MDPE.
    Type: Grant
    Filed: September 23, 2002
    Date of Patent: November 30, 2004
    Assignee: ATOFINA Research S.A.
    Inventor: Marc Tavernier
  • Patent number: 6817114
    Abstract: Use of compositions prepared with organic coupling agents carrying epoxy groups for preparing applications requiring simultaneously improved mechanical properties and low viscosity.
    Type: Grant
    Filed: September 30, 2002
    Date of Patent: November 16, 2004
    Assignee: Atofina Research S.A.
    Inventor: Pierre Bredael
  • Patent number: 6774156
    Abstract: A process for producing a propylene copolymer having increased melt strength, the process comprising irradiating a copolymer of propylene and ethylene which has been polymerised using a Ziegler-Natta catalyst with an electron beam having an energy of at least 5 MeV and a radiation dose of at least 10 kGray and melting and mechanically processing the melt of the irradiated ethylene propylene copolymer to form long chain branches on the ethylene propylene copolymer molecules.
    Type: Grant
    Filed: September 2, 2003
    Date of Patent: August 10, 2004
    Assignee: ATOFINA Research S.A.
    Inventors: Guy Debras, Marc Dupire, Jacques Michel
  • Patent number: 6730742
    Abstract: A polypropylene fiber including greater than 50% by weight of a first isotactic polypropylene produced by a Ziegler-Natta catalyst, from 5 to less than 50% by weight of a second isotactic polypropylene produced by a metallocene catalyst and up to 15% by weight of a syndiotactic polypropylene (sPP).
    Type: Grant
    Filed: October 30, 2002
    Date of Patent: May 4, 2004
    Assignee: Atofina Research S.A.
    Inventor: Axel Demain
  • Patent number: 6727332
    Abstract: Use of isotactic polypropylene homopolymers or copolymers in processes in which the polypropylene solidifies from a melt, wherein for enhanced speed of solidification of the polypropylene the polypropylene has a melt temperature and a crystallisation temperature not more than 50° C. less than the melt temperature resulting from the polypropylene having been produced using a metallocene catalyst component having the general formula: R″(CpR1R2R3)(Cp′Rn′)MQ2. Cp and Cp′ are a substituted cyclopentadienyl ring, and a sybstituted or unsubstituted fluorenyl ring, respectively. R″ is a structural bridge; R1 is a substituent on the cyclopentadienyl ring distal to the bridge. The distal substituent comprises a bulky group of the formula XR*a; X is chosen from Group IVA. M is a Group IVB transition metal or vanadium and each Q is hydrocarbyl having 1 to 20 carbon atoms or is a halogen.
    Type: Grant
    Filed: August 24, 2001
    Date of Patent: April 27, 2004
    Assignee: Atofina Research S.A.
    Inventor: Axel Demain
  • Patent number: 6723795
    Abstract: Use of a multimodal polypropylene blend in melt processing wherein for enhancing a compromise between melt strength and drawability the blend has a dispersion index of at least 8 and a ratio Mz/Mn of at least 10.
    Type: Grant
    Filed: March 29, 2002
    Date of Patent: April 20, 2004
    Assignee: ATOFINA Research S.A.
    Inventors: Marc Dupire, Jacques Michel
  • Patent number: 6720388
    Abstract: A polypropylene blend including from 0.5 to 50% by weight of a syndiotactic polypropylene having a multimodal molecular weight distribution and at least 50% by weight of an isotactic polypropylene.
    Type: Grant
    Filed: January 24, 2002
    Date of Patent: April 13, 2004
    Assignee: Atofina Research S.A.
    Inventor: Axel Demain
  • Patent number: 6632854
    Abstract: A process for producing polypropylene having increased melt strength, the process comprising irradiating polypropylene with an electron beam having an energy of at least 5 MeV and with a radiation dose of from 5 to 100 kGray in the presence of a grafting agent for forming long chain branches on the polypropylene molecules.
    Type: Grant
    Filed: February 4, 2002
    Date of Patent: October 14, 2003
    Assignee: Atofina Research, S.A.
    Inventor: Yves Charlier
  • Patent number: 6609413
    Abstract: A method of continually measuring the cetane number of a diesel fuel, the method comprising the steps of: (a) providing a diesel engine having means for selectively supplying at least three diesel fuels to the engine, a first actuator for varying the injection timing of the engine, a second actuator for varying the fuel flow of the engine, and a third actuator for varying the compression ratio of the engine; (b) providing a first supply of a diesel fuel of known cetane number, a second supply of a diesel fuel of different known cetane number and a third supply of a diesel fuel of unknown cetane number to be measured, the third supply being connected to a diesel fuel blending system; (c) in a first cycle selectively and alternately supplying the first, second and third supplies to the diesel engine, and for each supply, controlling the first actuator to achieve an injection timing of a predetermined angle before top dead centre, controlling the second actuator to achieve a predetermined fuel flow and contro
    Type: Grant
    Filed: August 2, 2000
    Date of Patent: August 26, 2003
    Assignee: ATOFINA Research, S.A.
    Inventor: Roger De Craecker