Abstract: Polyboronic compounds and methods of making them are provided. The polyboronic compounds are useful as crosslinking agents. The polyboronic compounds are produced by contacting a polymeric amine with a trialkylborate in the presence of a solvent so that the resulting molecule has more than one B—N bond.

Abstract: Disclosed is a method of rapidly hydrating a hydratable polymer, which method involves irradiating with radio frequency electromagnetic radiation, a mixture of at least the polymer and an aqueous hydrotreating medium to form a viscosified mixture of at least aqueous hydrotreating medium and hydrated polymer. Related methods of treating a subterranean formation and continuously hydrotreating a subterranean formation are also revealed.

Abstract: A kit for converting an existing wireline retrievable surface controlled subsurface safety valve (170, 270, 370) into a bypass passageway apparatus (100) allowing the injection of production-enhancing fluid into a wellbore while maintaining the operation of the closure member (374). Bypass passageway (280) can extend between upper (260) and lower (275) adapters external to the existing wireline retrievable surface controlled subsurface safety valve (270) to allow fluid injection bypass thereof. Conversion kit can include a tubing string hanger to suspend a velocity tubing string (407, 507), a gas lift valve (475) for gas lift operations, a locking mandrel (220), and/or a spacer tube (240).

Abstract: The present disclosure is directed to a method comprising introducing into a well bore a fluid comprising a zwitterionic polymer. The polymer is prepared by inverse emulsion polymerization of at least one monomer Ab comprising a betaine group and optionally one or more nonionic monomers Ba. The well bore is chosen from a natural gas well bore and an oil well bore.

Abstract: The present disclosure is directed to a gas lift system adapted to provide a gas injection point to a deeper location in a wellbore. A turn-over suspension mandrel can be landed inside a side pocket mandrel and connected to a gas lift valve on one end and a coil on the other end. A length of production tubing can extend from the side pocket mandrel. The production tubing can include a production packer to seal the annulus between the tubing and the well casing. The turn-over suspension mandrel can be constructed such that gas entering the gas lift valve is directed down through the coil and into the wellbore beneath the production packer. A plug can be placed at the bottom of the coil in order to prevent blowouts during installation of the gas lift system. An alternative embodiment of the present disclosure provides a coil and plug hung from a gas lift valve of a pack-off assembly.

Abstract: A method of hydraulically fracturing a formation comprises controlling a pump rate during hydraulic fracturing of the first section of the horizontal well bore during a first period to break down the formation while reducing pick up of sand positioned in the well bore; during a subsequent second period to pick up the sand positioned in the well bore generally at a rate at which the formation will accept the sand; and, during a subsequent third period to fracture the formation.

Abstract: A flapper for use as a component of a safety valve designed for deployment in a well bore having well bore fluids. The flapper includes a flapper body forming a flapper valve bore therethrough. The flapper body further forms a groove proximate to the flapper bore. The flapper also includes a plunger member sized and configured to be received in the flapper valve bore. The plunger member includes a first end portion and a second end portion. Additionally, the flapper includes a leaf spring including a primary end portion and a secondary end portion, the primary end portion of the leaf spring detachably attached to the second end portion of the plunger member and unattached to the flapper body and the secondary end portion of the leaf spring being sized and configured to be received and retained in the groove and to bias the plunger member into the flapper valve bore.

Abstract: Compositions and methods of reducing a flow of aqueous liquids through a subterranean formation are provided. The compositions and methods are used for water control. The compositions include a water control additive that is prepared by reacting a soluble sodium silicate and a hydrolysable organosilane compound to produce silanol that reacts and forms a bond with the formation thereby producing a binding polysiloxane.

Abstract: A process for forming a strong, low-density proppant, which process includes heating pumice particulates, or shaped agglomerates thereof, so as to form heat-treated pumice particulates, or heat-treated, shaped pumice agglomerates, having an apparent density of 2.4 or less and a crush resistance of no more than 10% fines at 4000 psi. Proppants, and well treatment fluids comprising proppants, meeting these characteristics and processes for treating subterranean formations using fluids which include such proppants are also described.

Abstract: A wellhead assembly for an injection tubing string is provided which allows a master valve to be closed without damaging the injection tubing string while still allowing for the use of a back pressure valve to isolate the tree. Wellhead assemblies and related methods of the present invention include a flange adapted to be connected between a wellhead and a Christmas tree. The assembly also includes a mandrel adapted to being inserted into the longitudinal bore of the flange, the mandrel having a port for communicating with an injection port which extends radially through the flange. The assembly further includes a hanger adapted to connect to the upper end of the injection string, wherein the hanger is further adapted to land in the longitudinal bore of the mandrel. The hanger includes a communication passageway for facilitating fluid communication between the port of the mandrel and the injection tubing string.

Abstract: A thermophilic mannanohydrolase enzyme may be used as an enzyme breaker for fracturing fluids containing hydratable polymers of guar and underivatized guar. The enzyme is effective in downhole temperatures exceeding 160° F.

Abstract: An apparatus and method for directionally disposing an elongated flexible member in a pressurized conduit. The method includes inserting a bent end portion of an elongated hollow body through an opening in fluid communication with a well valve and defined by a pressurized conduit, the bent end portion being disposed in a pre-determined direction and location within the pressurized conduit; inserting a lead portion of an elongated flexible member into a fluid passageway defined by a primary valve, the fluid passageway of the primary valve being in sealed fluid relationship with the elongated hollow body which, in turn, is in sealed fluid relationship with the pressurized conduit, so that the lead portion of the elongated flexible member is inserted through the bend end portion and into the pressurized conduit by a pre-determined distance; and thereafter retaining in place the inserted elongated flexible member, whereby the elongated flexible member is directionally disposed in the pressurized conduit.

Abstract: A wellhead assembly for an injection tubing string is provided which allows a master valve to be closed without damaging the injection tubing string while still allowing for the use of a back pressure valve to isolate the tree. Wellhead assemblies and related methods of the present invention include a wellhead apparatus adapted to be connected to a wellhead. The assembly also includes a mandrel adapted to being inserted into the longitudinal bore of the wellhead apparatus, the mandrel having a port for communicating with an injection port which extends radially through the wellhead apparatus. The assembly further includes a hanger adapted to connect to the upper end of the injection string, wherein the hanger is further adapted to land in the longitudinal bore of the mandrel. The hanger includes a communication passageway for facilitating fluid communication between the port of the mandrel and the injection tubing string.

Abstract: The application discloses a safety valve including a flapper valve and a packer assembly to be installed in a bore to isolate a first zone from a second zone. Preferably, the safety valve includes a hydraulic conduit bypassing the flapper valve to allow communication therethrough when the valve is closed. Furthermore, the safety valve preferably allows unobstructed passage of tools and fluids therethrough when the flapper valve is open. The application discloses a method to install a safety valve in an existing string of tubing by deploying a packer assembly having an integral safety valve.

Abstract: The application discloses a safety valve to replace an existing safety valve in order to isolate a production zone from a string of tubing when closed. Preferably, the safety valve includes a flow interruption device displaced by an operating conduit extending from a surface location to the safety valve through the inside of the production tubing. The application also discloses a bypass-conduit which allows communication from a surface location to the production zone through the safety valve without affecting the operation of the safety valve.

Abstract: The production of hydrocarbons from a subterranean formation is enhanced by use of a well treatment fluid which contains a carboxylated guar which may be prepared by reacting a guar source and a derivatizing agent of the formula X(CH2)nCOOH or alkali salts thereof, wherein X is selected from the group consisting of —OSO2CH3; —OSO2C2H5; —OTs, —Br, and —I and n is between from 1 to 4. The intrinsic viscosity of the carboxylated guar in 2% KCl at 27° C. is at least 750 mL/g and the degree of substitution (DS) of the carboxylated guar is typically between from about 0.02 to about 0.15.

Abstract: Apparatuses and methods to inject chemical stimulants (284) to a production zone (102, 202) through a string of production tubing (110, 210) around a downhole obstruction are disclosed. The apparatuses and methods include deploying an anchor seal assembly (200) to a landing profile (120, 220) located within a string of production tubing (110, 210). The anchor seal assembly (200) is in communication with a surface station through an injection conduit (260, 264) and includes a bypass pathway (262) to inject various fluids to a zone below.

Abstract: A storm plug for temporarily isolating an offshore well in deep water includes a retrievable service packer connected to a valve housing containing a movable isolation sleeve and a standing valve. The standing valve precludes the fluid flow through a portion of the isolation sleeve. The isolation sleeve being hydraulically actuated from an open position to a closed position. In the open position, fluid may flow through flow ports in the standing valve to an annular bypass area between the valve housing and the isolation sleeve. In the closed position, the isolation sleeve prevents fluid flow through the valve housing. The valve may be hydraulically actuated as compared to conventional storm valve that are set by workstring rotation. The running tool used to run the storm plug into the well may be hydraulically disconnected from the valve housing.

Abstract: The present invention provides systems and methods for injecting or retrieving tubewire into or out of coiled tubing. The system comprises an injector, coiled tubing coupled to the injector and a pumping mechanism. The injector is adapted to apply a force to inject or retrieve the tubewire into or out of the coiled tubing while the pump pumps fluid in the direction of the force to provide fluid drag on the tubewire. The tubewire may be bent or straightened, and may include a protuberance on its free end to assist in the injection and retrieval process. During injection, the coiled tubing may remain on a reel or may be stretched out along a surface.

Abstract: A hydraulic sleeve valve that includes a valve position indication system that provides an indication that the valve has reached a predetermined position, such as, for example, the fully opened or fully closed condition. The hydraulic sleeve valve may include a bypass relief system and may also provide a valve control fluid circulation function to filter or otherwise manipulate the control fluid.