Abstract: A resin cassette for an additive manufacturing apparatus includes (a) a light transmissive window; (b) a circumferential frame connected to and surrounding the window, the window and frame together forming a well configured to receive a light polymerizable resin; and (c) a fluorophore layer in or on the window.

Abstract: A removable window cassette (100) for a bottom-up stereolithography apparatus includes (a) a light-transmissive window (110) having a rigid bottom portion (112), a semipermeable top portion (114), and a fluid flow region therebetween; (b) a circumferential frame (120) surrounding said window and into which said window is recessed, said frame having a top portion, a bottom portion, and an internal wall portion (120C), said frame internal wall portion defining with said window semipermeable top portion a well into which a polymerizable liquid may be received; and (c) a plurality of clamp draw-in pins (140) connected to said frame bottom portion and extending downward therefrom; and (d) at least a first and second port (150A, 150B) connected to said frame bottom portion, with said first port in fluid communication with said second port through said window fluid flow region.

Abstract: A method for carbon nanotube purification, preferably including: providing carbon nanotubes; depositing a mask; and/or selectively removing a portion of the mask; and optionally including removing a subset of the carbon nanotubes and/or removing the remaining mask.

Abstract: Provided herein according to some embodiments is a dual cure stereolithography resin that includes thermoplastic particles, which thermoplastic particles are insoluble in the resin and insoluble during a first, light, cure in which an intermediate object is produced, but then dissolve or swell in the intermediate object during the second, heat, cure.

Abstract: An ocean alkalinity enhancement (OAE) system that reduces atmospheric CO2 and mitigates ocean acidification by electrochemically processing feedstock solution (e.g., seawater or brine) to generate an alkalinity product that is then supplied to the ocean. The OAE system includes a base-generating device and a control circuit disposed within a modular system housing deployed near a salt feedstock. The base-generating device (e.g., a bipolar electrodialysis (BPED) system) generates a base substance that is then used to generate the ocean alkalinity product. The control circuit controls the base-generating device such that the alkalinity product is supplied to the ocean only when (1) sufficient low/zero-carbon electricity is available, (2) it is safe to operate the base-generating device, and (3) supplying the alkalinity product will not endanger sea life.

Abstract: A method of making a three-dimensional object from an object geometry data file that includes (a) slicing said object geometry data file to produce a rasterized image sequence file; (b) generating a signed distance field from said object geometry data file; (c) selecting, from a library of procedural texture functions, a procedural texture function defining a continuous internal or external set of features; (d) modifying said rasterized image sequence to include said internal or external set of features based on said signed distance field to thereby produce a modified image sequence file; and then (e) producing said three-dimensional object by additive manufacturing from said modified image sequence file, said three-dimensional object having said selected internal feature included therein and/or external feature included thereon.

Abstract: A method of measuring the viscosity of a resin in a bottom-up additive manufacturing apparatus, includes the steps of: (a) providing an additive manufacturing apparatus including a build platform and a light transmissive window, said build platform and said window defining a build region there between, with said window carrying a resin; (b) advancing said build platform and said window towards one another until said build platform contacts said resin; (c) detecting the force exerted on said build platform by said resin; and (d) generating in a processor a viscosity measure of said resin from said detected force.

Abstract: Provided herein is a dual cure resin useful for the production of objects by stereolithography, said resin comprising a mixture of: (a) a light-polymerizable component; and (b) a heat-polymerizable component, said heat-polymerizable component comprising: (i) a dicyclopentadiene-containing polyepoxide resin; (ii) a cyanate ester resin; (iii) an epoxy-reactive toughening agent; and (iv) a core shell rubber toughener.

Abstract: A method of improving production performance of an additive manufacturing system includes obtaining a first production plan and a second production plan, different from the first production plan, for the manufacture of a plurality of objects using a fleet of additive manufacturing apparatus, automatically generating a first allocation of a first quantity of the plurality of objects to the fleet of additive manufacturing apparatus using the first production plan, automatically generating a second allocation of a second quantity of the plurality of objects to the fleet of additive manufacturing apparatus using the second production plan, comparing a production performance of the first and second quantity of the plurality of objects after being manufactured by the fleet of additive manufacturing apparatus, and based on the comparison of the production performance, automatically regenerating the first and second allocations to change the first and second quantities.

Abstract: A method of making an object by additive manufacturing includes: (a) providing an additive manufacturing apparatus including a light source; (b) providing a carrier platform having a substantially planar object adhesion surface, the adhesion surface having a plurality of elongate wash channels formed therein; (c) producing the object on the carrier platform adhesion surface with the additive manufacturing apparatus from a light polymerizable resin, the object having at least one internal cavity formed therein; then (d) washing the object on the carrier platform with a wash liquid under conditions in which the wash liquid reaches the at least one internal cavity through the wash channels; then (e) optionally, at least partially drying the object on the carrier platform by separating the same from the wash liquid, and then agitating the object on the carrier platform to drain excess wash liquid from the object; (f) optionally, further curing the object.

Abstract: The present invention concerns methods of forming a three-dimensional object, and polymerizable liquids such as dual cure resins useful for making a three-dimensional object by sterolithography, such as by continuous liquid interface production (CLIP).

Abstract: Provided is a polymerizable liquid (or “resin”) for producing three-dimensional objects by additive manufacturing, which may include one or more of: (a) a polyvinyl siloxane; (b) a polythiol crosslinker; (c) a photoinitiator (e.g., a free radical photoinitiator); (d) optionally, a urethane (meth)acrylate oligomer; (e) optionally, a reactive diluent; (f) optionally, but in some embodiments preferably, a pigment or dye; (g) optionally, but in some embodiments preferably, a reactive or non-reactive filler; and (h) optionally, an odor scavenger.

Abstract: An assembly useful for thermoforming a dental aligner from polymer sheet material includes (a) a custom dental model having a planar bottom surface and a receptacle formed in said planar bottom surface; and (b) a reusable die removably received in said receptacle.

Abstract: The present disclosure describes a resin cassette for an additive manufacturing apparatus. The resin cassette includes a light-transmissive window, a frame connected to and surrounding the window, and at least one dame connected to the frame. The frame and window form a well for receiving a light polymerizable resin. The dam extends over and continuously contacts the window and partitions the well into a plurality of independent build regions, each independent build region configured for receiving different light polymerizable resins. Additive manufacturing apparatuses and methods of concurrently making three-dimensional objects are also described.

Abstract: A build plate for a three-dimensional printer includes: a rigid, optically transparent, gas-impermeable planar base having an upper surface and a lower surface; and a flexible, optically transparent, gas-permeable sheet having an upper and lower surface, the sheet upper surface comprising a build surface for forming a three-dimensional object, the sheet lower surface positioned on the base upper surface. The build plate includes a gas flow enhancing feature configured to increase gas flow to the build surface.

Abstract: Provided herein according to some embodiments is a dual cure additive manufacturing resin, comprising: (i) a light polymerizable component, (ii) a photoinitiator, (iii) a heat polymerizable component, and (iv) a non-reactive diluent, which resin is useful for the production of three-dimensional objects by additive manufacturing. Methods of using the same are also provided.

Abstract: A method of making a three-dimensional object (11) from a light polymerizable dual cure resin (16), includes the steps of: (a) producing a green intermediate object by light polymerization of the resin in a stereolithography process (e.g., continuous liquid interface production); (i) the object comprising a body portion and a circumferential boundary portion (12) included in at least part of the body portion i (ii) the stereolithography process including overexposing the boundary portion (as compared to the exposure of the body portion) with light; (b) cleaning the intermediate object; and then (c) baking the object to produce the three-dimensional object.

Abstract: Provided herein according to embodiments is a prepolymer compound of formula I: and a prepolymer compound of formula II: A polymerizable liquid composition comprising the prepolymer compound, methods of use in forming a three-dimensional object, and objects produced are also provided.

Abstract: Methods, systems, and/or apparatuses for making an object on a bottom-up stereolithography apparatus that includes a light source (11), a drive assembly (14), optionally a heater (34) and/or cooler (34), and a controller (15). The light source, optional heater and/or cooler, and/or the drive assembly have at least one adjustable parameter that is adjustable by said controller.

Abstract: A method of cleaning residual resin from an additively manufactured object, includes: (a) enclosing an additively manufactured object in an inner chamber of a centrifugal separator, the additively manufactured object including a light polymerized resin with a surface coating of viscous, unpolymerized, residual resin; (b) flooding the chamber with a volatile organic solvent vapor without contacting liquid organic solvent to the object, the vapor present in an amount sufficient to reduce the viscosity of the residual resin; and (c) spinning the additively manufactured object in the chamber to centrifugally separate at least a first portion of the residual resin from the object.