Patents Assigned to Cataler Corporation
  • Patent number: 11679379
    Abstract: The exhaust gas purification device includes a substrate, a first catalyst layer, and a second catalyst layer. The substrate includes an upstream end, a downstream end, and a porous partition wall defining a plurality of cells extending between the upstream end and the downstream end. The plurality of cells include an inlet cell opening at the upstream end and sealed at the downstream end, and an outlet cell adjacent to the inlet cell sealed at the upstream end and opening at the downstream end. The first catalyst layer is disposed on a surface of the partition wall in an upstream region. In a downstream region, the second catalyst layer is disposed inside the partition wall, and a second catalyst-containing wall including the partition wall and the second catalyst layer has a porosity of 35% or more.
    Type: Grant
    Filed: May 2, 2022
    Date of Patent: June 20, 2023
    Assignees: TOYOTA JIDOSHA KABUSHIKI KAISHA, CATALER CORPORATION
    Inventors: Koji Sugiura, Takeshi Hirabayashi, Akemi Satou, Keisuke Murawaki, Takaya Ota, Masatoshi Ikebe, Kohei Takasaki, Takeshi Morishima
  • Patent number: 11660589
    Abstract: An exhaust gas purification device that allows suppressing an increase in pressure loss is provided. The exhaust gas purification device of the present disclosure includes a honeycomb substrate and an inflow cell side catalyst layer. The substrate includes a porous partition wall which defines inflow cells and outflow cells extending from an inflow side end to an outflow side end. The inflow cell side catalyst layer is disposed on a surface on the inflow cell side in an inflow cell side catalyst region from an inflow side end to a position close to an outflow side end of the partition wall. The permeability of a portion including an outflow side region from the position to the outflow side end of the partition wall is higher than a gas permeability of a portion including the inflow cell side catalyst region of the partition wall and the inflow cell side catalyst layer.
    Type: Grant
    Filed: May 1, 2020
    Date of Patent: May 30, 2023
    Assignees: TOYOTA JIDOSHA KABUSHIKI KAISHA, CATALER CORPORATION
    Inventors: Koji Sugiura, Hiromasa Nishioka, Naoto Miyoshi, Akemi Sato, Masatoshi Ikebe, Ryota Nakashima, Yasutaka Nomura, Hirotaka Ori
  • Publication number: 20230149907
    Abstract: A gas purification catalyst device comprises: a substrate; and one or more catalyst layers on the substrate. Among the one or more catalyst layers, at least one catalyst layer contains both Cu-CHA-type zeolite particles and iron-supporting metal oxide particles in which iron is supported on metal oxide particles.
    Type: Application
    Filed: April 2, 2021
    Publication date: May 18, 2023
    Applicant: CATALER CORPORATION
    Inventors: Takuto ARAKAWA, Yuya KAWANO, Tsubasa NANJO, Yoshinori YAMASHITA
  • Patent number: 11633724
    Abstract: Methods for exhaust gas purification, including the steps of: attaching an exhaust gas purification catalyst to an exhaust system of an internal combustion engine, and supplying an exhaust gas to the exhaust gas purification catalyst, where the exhaust gas purification catalyst includes an upper layer containing first carrier particles which are particles of an inorganic oxide and rhodium, and a lower layer containing second carrier particles which are particles of an inorganic oxide, the upper layer includes a rhodium-rich portion near the surface of the upper layer on the upstream side of the exhaust gas flow, and the existence range of the rhodium-rich portion is in a range of greater than 50% to 80% of the length of the upper layer from a downstream side end of an exhaust gas flow and of less than 20 ?m in the depth direction from an outermost surface of the upper layer.
    Type: Grant
    Filed: July 11, 2022
    Date of Patent: April 25, 2023
    Assignees: CATALER CORPORATION, TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Shunsuke Oishi, Takaya Ota, Yoshinori Saito, Seiji Nakahigashi, Isao Chinzei, Hiromasa Suzuki
  • Publication number: 20230114106
    Abstract: An exhaust gas purification catalyst device comprising a base material and a catalyst coating layer provided on the base material, wherein the catalyst coating layer contains zeolite particles, inorganic oxide particles other than the zeolite particles, and a catalyst precious metal, and the ratio dZEO/dOX between the average particle diameter dZEO of the zeolite particles and the average particle diameter dOX of the inorganic oxide particles other than the zeolite particles is 3.4 or less.
    Type: Application
    Filed: March 17, 2021
    Publication date: April 13, 2023
    Applicant: CATALER CORPORATION
    Inventors: Kohei TAKASAKI, Tatsuya OHASHI, Shunsuke OISHI
  • Patent number: 11621428
    Abstract: An anode catalyst layer for a fuel cell includes: electrode catalyst particles; a carbon carrier carrying the electrode catalyst particles; water electrolysis catalyst particles; a proton-conductive binder; and a graphitized carbon, wherein the content of the graphitized carbon in the anode catalyst layer for a fuel cell is 3-70 mass % with respect to the total mass of the electrode catalyst particles, the carbon carrier, and the graphitized carbon.
    Type: Grant
    Filed: September 4, 2019
    Date of Patent: April 4, 2023
    Assignee: CATALER CORPORATION
    Inventors: Akihiro Hori, Yosuke Horiuchi
  • Patent number: 11607672
    Abstract: Methods for exhaust gas purification, including the steps of: attaching an exhaust gas purification catalyst to an exhaust system of an internal combustion engine, and supplying an exhaust gas to the exhaust gas purification catalyst, where the exhaust gas purification catalyst includes an upper layer containing first carrier particles which are particles of an inorganic oxide and rhodium, and a lower layer containing second carrier particles which are particles of an inorganic oxide, the upper layer includes a rhodium-rich portion near the surface of the upper layer on the upstream side of the exhaust gas flow, and the existence range of the rhodium-rich portion is in a range of greater than 50% to 80% of the length of the upper layer from a downstream side end of an exhaust gas flow and of less than 20 ?m in the depth direction from an outermost surface of the upper layer.
    Type: Grant
    Filed: July 11, 2022
    Date of Patent: March 21, 2023
    Assignees: CATALER CORPORATION, TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Shunsuke Oishi, Takaya Ota, Yoshinori Saito, Seiji Nakahigashi, Isao Chinzei, Hiromasa Suzuki
  • Patent number: 11602742
    Abstract: Provided is an exhaust gas purification device that ensures an improved purification performance and a suppressed pressure loss. An exhaust gas purification device of the present disclosure includes a honeycomb substrate and an inflow cell side catalyst layer. disposed on a surface on the inflow cell side in an inflow side region of the partition wall. When a gas permeability coefficient of an inflow side partition wall portion including the inflow side region of the partition wall and the inflow cell side catalyst layer is Ka and a gas permeability coefficient of an outflow side partition wall portion including an outflow side region at least from the predetermined position to an outflow side end of the partition wall is Kb, a ratio Ka/Kb of the gas permeability coefficients is within a range of 0.4 or more and 0.8 or less.
    Type: Grant
    Filed: February 18, 2021
    Date of Patent: March 14, 2023
    Assignees: TOYOTA JIDOSHA KABUSHIKI KAISHA, CATALER CORPORATION
    Inventors: Koji Sugiura, Hiromasa Nishioka, Naoto Miyoshi, Akemi Sato, Ryota Nakashima, Masatoshi Ikebe, Keisuke Murawaki, Hirotaka Ori
  • Publication number: 20230076536
    Abstract: An exhaust gas purification catalyst device including a substrate and an SCR catalyst layer on the substrate, the substrate containing catalyst precious metal particles directly supported on the substrate, the catalyst precious metal particles containing Pt, and the catalyst precious metal particles having an average particle diameter of 30 to 120 nm inclusive.
    Type: Application
    Filed: February 10, 2021
    Publication date: March 9, 2023
    Applicant: CATALER CORPORATION
    Inventors: Tsubasa NANJO, Yuya KAWANO, Takuto ARAKAWA, Yoshinori YAMASHITA, Shunsuke OHISHI, Ryosuke TAKASU
  • Patent number: 11577226
    Abstract: The present disclosure provides an exhaust gas purification catalyst having an improved Rh activation, which comprises a substrate and a catalyst coat layer formed on the substrate, the catalyst coat layer having a two-layer structure, wherein the catalyst coat layer includes an upstream portion on an upstream side and a downstream portion on a downstream side in an exhaust gas flow direction, and a part or all of the upstream portion is formed on a part of the downstream portion, wherein the upstream portion contains Rh fine particles and Pt, wherein the Rh fine particles have an average particle size measured by a transmission electron microscope observation of 1.0 nm or more to 2.0 nm or less, and a standard deviation ? of the particle size of 0.8 nm or less, and wherein the downstream portion contains Rh.
    Type: Grant
    Filed: December 1, 2020
    Date of Patent: February 14, 2023
    Assignees: TOYOTA JIDOSHA KABUSHIKI KAISHA, CATALER CORPORATION
    Inventors: Seiji Nakahigashi, Isao Chinzei, Shogo Shirakawa, Hiromasa Suzuki, Masahide Miura, Takahiro Nishio, Norimichi Shimano, Hiroki Nihashi, Mitsuyoshi Okada, Takashi Onozuka, Souta Akiyama, Hiromi Togashi, Takahiro Noguchi, Isao Naito
  • Patent number: 11559768
    Abstract: The present disclosure provides the exhaust gas purification catalyst with the improved purification performance under the high Ga condition and the transient state in which an A/F repeats rich and lean phases. The present disclosure relates to an exhaust gas purification catalyst comprising a catalyst coating layer on a substrate, the catalyst coating layer containing a noble metal, a composite oxide containing cerium oxide and zirconium oxide, and a composite oxide containing aluminum oxide, wherein in the catalyst coating layer: an average thickness of the coating layer is in a range from 20 ?m to 100 ?m; a porosity measured by a weight-in-water method is in a range from 50% by volume to 80% by volume; and high-aspect-ratio pores having an aspect ratio of 5 or more account for 0.
    Type: Grant
    Filed: April 17, 2020
    Date of Patent: January 24, 2023
    Assignees: TOYOTA JIDOSHA KABUSHIKI KAISHA, CATALER CORPORATION
    Inventors: Isao Chinzei, Masahide Miura, Seiji Nakahigashi, Hiromasa Suzuki, Akira Morikawa, Toshio Yamamoto, Satoru Katoh, Takashi Onozuka, Hirotaka Ori, Mitsuyoshi Okada, Sho Hoshino
  • Publication number: 20220412244
    Abstract: An exhaust gas purification catalyst apparatus has a honeycomb base material and a catalyst noble metal supported by the honeycomb base material, wherein: the honeycomb base material contains ceria-zirconia composite oxide particles as one of the constituent materials, is of a wall flow type, and includes inlet-side cells and outlet-side cells demarcated by porous partition walls; the catalyst noble metal is supported in inlet-side support regions and outlet-side support regions; each of the inlet-side support regions is formed with a specific length from the exhaust gas flow upstream end; the catalyst noble metal 70% support depth is not greater than 50% of the thickness of the porous partition walls; each of the outlet-side support regions is formed with a specific length from the exhaust gas flow downstream end; and the catalyst noble metal 70% support depth is greater than 50% of the thickness of the porous partition walls.
    Type: Application
    Filed: June 17, 2020
    Publication date: December 29, 2022
    Applicants: CATALER CORPORATION, TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Kana IWATA, Minoru ITOU, Takeru YOSHIDA, Masaru KAKINOHANA, Hiromasa SUZUKI, Atsushi TANAKA
  • Patent number: 11534737
    Abstract: An exhaust gas purification catalyst including particles of a catalyst metal supported on secondary particles of an inorganic oxide, wherein when scanning transmission electron microscope-energy dispersive X-ray line analysis is performed from a surface of the secondary particles toward a center thereof, a support density of the catalyst metal on a surface side of the secondary particles is greater than the support density of the catalyst metal in a center part of the secondary particles.
    Type: Grant
    Filed: January 16, 2019
    Date of Patent: December 27, 2022
    Assignee: CATALER CORPORATION
    Inventor: Hiroki Nihashi
  • Patent number: 11524285
    Abstract: The exhaust gas purification catalyst device includes an upper layer which includes first carrier particles and rhodium, and a lower layer which includes second carrier particles, and the upper layer includes a rhodium enriched area in the range a, from the upstream end in the exhaust gas flow to 50% of the upper layer length, and a range b from the upper layer top surface to 18 ?m in the depth direction. The rhodium enriched area contains at least 50% and less than 100% of all the rhodium in the upper layer.
    Type: Grant
    Filed: January 25, 2019
    Date of Patent: December 13, 2022
    Assignees: CATALER CORPORATION, TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Shunsuke Oishi, Takaya Ota, Isao Chinzei, Hiromasa Suzuki, Yoshinori Saito, Seiji Nakahigashi
  • Patent number: 11524284
    Abstract: An exhaust gas purification device has a metal substrate and a catalyst layer on the metal substrate, wherein the metal substrate is a wound body of one or a plurality of metal foils, at least one of the one or a plurality of metal foils is a perforated metal foil having holes, the catalyst layer contains noble metal catalyst particles and a carrier for carrying the noble metal catalyst particles, and more noble metal catalyst particles are present in the catalyst layer on side surfaces of holes, which face an upstream side of an exhaust gas flow, than in the catalyst layer on side surfaces of holes, which face a downstream side of the exhaust gas flow.
    Type: Grant
    Filed: September 14, 2018
    Date of Patent: December 13, 2022
    Assignee: CATALER CORPORATION
    Inventors: Kohei Takasaki, Yuji Matsuhisa, Nobuaki Bando, Hiroshi Ono, Tomohito Mizukami, Tsuyoshi Ito
  • Publication number: 20220387983
    Abstract: There is provided an exhaust gas purification device that shows a high HC removal performance under a condition in which a rich air-fuel mixture is introduced. The exhaust gas purification device includes a substrate, a first catalyst layer, and a second catalyst layer. The substrate includes an upstream end and a downstream end. The first catalyst layer is disposed on a surface of the partition wall in an upstream region including the upstream end of the substrate. The second catalyst layer is disposed inside the partition wall in a downstream region including the downstream end of the substrate. The first catalyst layer contains a first metal catalyst and alumina-zirconia composite oxide. The second catalyst layer contains a second metal catalyst.
    Type: Application
    Filed: May 24, 2022
    Publication date: December 8, 2022
    Applicants: TOYOTA JIDOSHA KABUSHIKI KAISHA, CATALER CORPORATION
    Inventors: Koji SUGIURA, Takeshi HIRABAYASHI, Akemi SATOU, Keisuke MURAWAKI, Takaya OTA, Masatoshi IKEBE, Kohei TAKASAKI, Takeshi MORISHIMA
  • Publication number: 20220370997
    Abstract: The exhaust gas purification device includes a substrate, a first catalyst layer, and a second catalyst layer. The substrate includes an upstream end, a downstream end, and a porous partition wall defining a plurality of cells extending between the upstream end and the downstream end. The plurality of cells include an inlet cell opening at the upstream end and sealed at the downstream end, and an outlet cell adjacent to the inlet cell sealed at the upstream end and opening at the downstream end. The first catalyst layer is disposed on a surface of the partition wall in an upstream region. In a downstream region, the second catalyst layer is disposed inside the partition wall, and a second catalyst-containing wall including the partition wall and the second catalyst layer has a porosity of 35% or more.
    Type: Application
    Filed: May 2, 2022
    Publication date: November 24, 2022
    Applicants: TOYOTA JIDOSHA KABUSHIKI KAISHA, CATALER CORPORATION
    Inventors: Koji SUGIURA, Takeshi HIRABAYASHI, Akemi SATOU, Keisuke MURAWAKI, Takaya OTA, Masatoshi IKEBE, Kohei TAKASAKI, Takeshi MORISHIMA
  • Patent number: 11504704
    Abstract: An exhaust gas purification device includes a substrate including an upstream end and a downstream end and having a length Ls; a first containing Pd particles, extending between the upstream end and a first position, and being in contact with the substrate; a second containing Rh particles, extending between the downstream end and a second position, and being in contact with the substrate; and a third catalyst layer containing Rh particles, extending between the upstream end and a third position, and being in contact with at least the first catalyst layer, wherein an average of a Rh particle size distribution is from 1.0 to 2.0 nm, and a standard deviation of the Rh particle size distribution is 0.8 nm or less in each of the second catalyst layer and the third catalyst layer.
    Type: Grant
    Filed: August 24, 2021
    Date of Patent: November 22, 2022
    Assignees: TOYOTA JIDOSHA KABUSHIKI KAISHA, CATALER CORPORATION
    Inventors: Isao Chinzei, Takumi Tojo, Shogo Shirakawa, Sho Hoshino, Minoru Ito, Naoto Fujita
  • Patent number: 11504700
    Abstract: The present invention provides an exhaust gas purification catalyst including an alkaline earth metal supported in a highly dispersed state on a porous carrier. A catalyst layer of the exhaust gas purification catalyst provided by the invention has an alkaline earth metal-supporting region including a porous carrier, a catalyst metal belonging to the platinum group, and a sulfate of at least one type of alkali earth metal supported on the porous carrier. In a cross-section of this region, a Pearson correlation coefficient RAe/M is at least 0.5 as calculated using ? and ? for each pixel obtained by carrying out area analysis by FE-EPMA under conditions of pixel size of 0.34 ?m×0.34 ?m, and measured pixel number 256×256, and by measuring the characteristic X-ray intensity (?:cps) of the alkaline earth metal element (Ae) and the characteristic X-ray intensity (?:cps) of the main constituent element of the inorganic compound constituting the porous carrier for each pixel.
    Type: Grant
    Filed: April 9, 2018
    Date of Patent: November 22, 2022
    Assignee: Cataler Corporation
    Inventors: Shunsuke Oishi, Shogo Kawamura, Takahiro Nagata, Hirotaka Ori, Minoru Itou
  • Publication number: 20220347626
    Abstract: An exhaust gas purification device suppresses a pressure loss increase and includes a honeycomb substrate and inflow cell side catalyst layer. The substrate includes a porous partition wall defining several cells extending from an inflow side end surface to an outflow side end surface. The cells include an inflow and outflow cell adjacent across the wall. The inflow cell has an open inflow side end and sealed outflow side end. The outflow cell has a sealed inflow side end and open outflow side end. The catalyst layer is on an inflow cell side surface in an region extending from the inflow side end positioned 10% or more of the partition wall length. At this position, a filled portion of the inflow cell side catalyst layer pores are 40% or less. The pores are present to a depth of 50% of a thickness of the partition wall.
    Type: Application
    Filed: April 11, 2022
    Publication date: November 3, 2022
    Applicants: TOYOTA JIDOSHA KABUSHIKI KAISHA, CATALER CORPORATION
    Inventors: Akemi SATO, Takeshi HIRABAYASHI, Koji SUGIURA, Keisuke MURAWAKI, Takaya OTA, Masatoshi IKEBE, Kohei TAKASAKI, Takeshi MORISHIMA