Patents Assigned to Ciba Specialty Chemcials Corporation
-
Patent number: 7157586Abstract: Benzotriazole UV absorbers substituted with a ultra long ester or amide moiety wherein the ester or amide group is a hydrocarbyl group of 25 to 100 carbon atoms or is a group of alkyl of 25 to 100 carbon atoms interrupted by 5 to 39 oxygen atoms and terminated with an omega-OH or an omega-OR group exhibit excellent stabilization efficacy while they concomitantly do not bloom when incorporated into polyolefin films. These benzotriazole UV absorbers also provide excellent protection to white, dyed, dipped, unscented and/or scented candle wax from discoloration and degradation.Type: GrantFiled: February 11, 2002Date of Patent: January 2, 2007Assignee: Ciba Specialty Chemcials CorporationInventors: Mervin Wood, Ramanathan Ravichandran, Douglas Wayne Horsey, Anunay Gupta, Deborah DeHessa, Luther A. R. Hall, Andrea Smith, Stephen Mark Andrews
-
Patent number: 6218536Abstract: 1,2-Bis-adducts of stable hindered nitroxide compounds with substituted ethylenes are prepared by reacting two equivalents of nitroxyl compound with an ethylenically unsaturated compound such as styrene or an acrylate ester. These adducts are very effective inhibitors to prevent the premature polymerization of ethylenically unsaturated monomers when such monomers are distilled, processed or stored.Type: GrantFiled: October 7, 1998Date of Patent: April 17, 2001Assignee: Ciba Specialty Chemcials CorporationInventors: Glen Thomas Cunkle, Thomas F. Thompson, Volker H. von Ahn, Roland A. E. Winter
-
Patent number: 6191182Abstract: A novel process for the preparation of compounds of formula I by aminolysis of a p-halophenyl alkyl ketone of formula II with a cyclic amine of formula III in water at a temperature of at least 130° C., in which formulae X is a halogen atom and R1, R2 and R3 are as claimed in claim 1, as well as the novel compounds of formula I and their use for the preparation of photoinitiators for the photopolymerisation of ethylenically unsaturated compounds.Type: GrantFiled: June 10, 1999Date of Patent: February 20, 2001Assignee: Ciba Specialty Chemcials CorporationInventors: Rinaldo Hüsler, Rudolf Schwabe, Reto Luisoli
-
Patent number: 6180315Abstract: Novel compositions for making structured color images and application thereof Compositions for making structured color images comprising (a) a soluble pigment precursor which can be transformed to an insoluble pigment by means of chemical, thermal, photolytic or radiation-induced method, and (b) a binder polymer or prepolymer, or a positive or negative resist-type resin which can be structured by crosslinking, polymerization or depolymerization by applying heat or electromagnetic irradiation. The compositions can be applied to optical and thermal recording, printing, and the production of color filters for Liquid Crystal Displays, with high accuracy, high transparency and high stability.Type: GrantFiled: December 10, 1999Date of Patent: January 30, 2001Assignee: Ciba Specialty Chemcials CorporationInventors: Ulrich Sch{umlaut over (a)}deli, John S. Zambounis, Abul Iqbal, Zhimin Hao, Henri Dubas
-
Patent number: 6171995Abstract: A composition, comprising (a) a compound of formula I (R1R2R3P)xLyM2+Z1−Z2− (I), wherein R1, R2 and R3 are each independently of one another H, C1-C20alkyl, C1-C20-alkoxy; C4-C12cycloalkyl which is unsubstituted or substituted by C1-C6-alkyl, C1-C6haloalkyl or C1-C6alkoxy; C4-C12cycloalkoxy which is unsubstituted or substituted by C1-C6-alkyl, C1-C6haloalkyl or C1-C6alkoxy; C6-C16aryl which is unsubstituted or substituted by C1-C6alkyl, C1-C6haloalkyl or C1-C6alkoxy; C6-Cl6aryloxy which is unsubstituted or substituted by C1-C6alkyl, C1-C6haloalkyl or C1-C6alkoxy; C7-C16-aralkyloxy which is unsubstituted or substituted by C1-C6alkyl, C1-C6haloalkyl or C1-C6alkoxy; or C7-C16aralkyloxy which is unsubstituted or substituted by C1-C6alkyl, C1-C6-haloalkyl or C1-C6alkoxy; or R2 and R3 together are tetra- or pentamethylene which is unsubstituted or substituted by C1-C6alkyl, C1-C6haloalkyl or C1-C6alkoxy; tetra- or pentamethylenedioxyl which is unsubstituted or substituted by C1-C6alType: GrantFiled: November 14, 1997Date of Patent: January 9, 2001Assignee: Ciba Specialty Chemcials CorporationInventors: Andreas M{umlaut over (u)}hlebach, Paul Adriaan Van Der Schaaf, Andreas Hafner
-
Patent number: 6162883Abstract: A mixture of at least one thermal carbene-free ruthenium catalyst A and at least one thermal ruthenium carbene catalyst B, both of which initiate the ring-opening metathesis polymerization on their own, said catalysts being present in a weight ratio of A to B from 10:1 to 1:10. By adding this mixture even in small amounts, the ring-opening metathesis polymerization of strained cycloolefins can be effectively catalyzed.Type: GrantFiled: September 30, 1998Date of Patent: December 19, 2000Assignee: Ciba Specialty Chemcials CorporationInventors: Andreas Muhlebach, Paul Adriaan Van Der Schaaf, Andreas Hafner
-
Patent number: 6147026Abstract: A composition, comprising(a) a compound of formula I(R.sub.1 R.sub.2 R.sub.3 P).sub.x L.sub.y M.sup.2+ Z.sub.1.sup.- Z.sub.2.sup.- (I),whereinR.sub.1, R.sub.2 and R.sub.3 are each independently of one another H, C.sub.1 -C.sub.20 alkyl, C.sub.1 -C.sub.20 -alkoxy; C.sub.4 -C.sub.12 cycloalkyl which is unsubstituted or substituted by C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl or C.sub.1 -C.sub.6 alkoxy; C.sub.4 -C.sub.12 cycloalkoxy which is unsubstituted or substituted by C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 haloalkyl or C.sub.1 -C.sub.6 alkoxy; C.sub.6 -C.sub.16 aryl which is unsubstituted or substituted by C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl or C.sub.1 -C.sub.6 alkoxy; C.sub.6 -C.sub.16 aryloxy which is unsubstituted or substituted by C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl or C.sub.1 -C.sub.6 alkoxy; C.sub.7 -C.sub.16 aralkyl which is unsubstituted or substituted by C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl or C.sub.1 -C.sub.6 alkoxy; or C.sub.7 -C.sub.Type: GrantFiled: November 14, 1997Date of Patent: November 14, 2000Assignee: Ciba Specialty Chemcials CorporationInventors: Frans Setiabudi, Dean Tallak Behm
-
Patent number: 5998518Abstract: A description is given of compounds of the formula I ##STR1## where R.sup.1 is H, C.sub.1 -C.sub.12 alkyl, C.sub.2 -C.sub.12 alkenyl, C.sub.2 -C.sub.12 alkynyl, O--C.sub.1 -C.sub.12 alkyl, CO--C.sub.1 -C.sub.12 alkyl, in which radicals alkyl chains may also be interrupted by O, S, S.dbd.O, SO.sub.2 or N--C.sub.1 -C.sub.12 alkyl, or is C.sub.5 -C.sub.12 cycloalkyl which is unsubstituted or substituted by1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals, O--C.sub.5 -C.sub.12 cycloalkyl, which is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals, CO--C.sub.6 -C.sub.14 aryl, which is unsubstituted or substituted by 1 to 9 C.sub.1 -C.sub.4 alkyl and/orC.sub.1 -C.sub.4 alkoxy radicals, O-benzyl, which on the aromatic ring is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals, CO-benzyl, which on the aromatic ring is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.Type: GrantFiled: October 15, 1997Date of Patent: December 7, 1999Assignee: Ciba Specialty Chemcials CorporationInventor: Alfred Steinmann
-
Patent number: 5726226Abstract: Compounds of formula (I) ##STR1## in which m+n is a number from 1 to 100 and n varies from zero to 90% of the sum of m+n; R.sub.1 and R.sub.3, which may be identical or different, are for example C.sub.1 -C.sub.18 alkyl or phenyl; R.sub.2 is C.sub.2 -C.sub.12 alkylene; G is for example a group of formula (IId) ##STR2## in which R.sub.5 and R.sub.6 are for example hydrogen; R.sub.4 is for example C.sub.1 -C.sub.18 alkyl; L.sub.1 has for example any one of the meanings given to R.sub.1 or is a group (R.sub.28).sub.3 SiO-- where R.sub.28 is C.sub.1 -C.sub.18 alkyl; and L.sub.2 is for example hydrogen, Na, K, C.sub.1 -C.sub.8 alkyl or a group (R.sub.28).sub.3 Si-- with R.sub.28 as defined above.The compounds of formula (I) are useful as light, heat and oxidation stabilizers for organic materials.Type: GrantFiled: May 22, 1997Date of Patent: March 10, 1998Assignee: Ciba Specialty Chemcials CorporationInventors: Valerio Borzatta, Primo Carrozza