Abstract: Provided is a process for depolymerization of a poly(C2-C4 alkylene terephthalate), which comprises contacting a poly(C2-C4 alkylene terephthalate) with methanol and a catalyst chosen from potassium carbonate, sodium carbonate, magnesium methoxide, 1,8-diazabicyclo[5.4.0]undec-7-ene, and triazabicyclodecene, at a temperature sufficient to effect said depolymerization. The process of the invention can be carried out a substantially lower temperature and requires less methanol than necessary for zinc acetate-catalyzed reactions, and is sufficiently robust to tolerate lower-quality poly(C2-C4 alkylene terephthalate) scrap feeds.
Type:
Application
Filed:
December 10, 2020
Publication date:
February 2, 2023
Applicant:
Eastman Chemical Company
Inventors:
Robert Jacks Sharpe, Michael Charles Morrow
Abstract: An esterification process that uses an acetic acid composition from a wood acetylation process as a reactant. Even though the acetic acid composition contains impurities, such as ethyl acetate, methyl acetate, acetaldehyde, acetone, terpenes and/or terpenes derivatives, the impurities do not adversely affect the quality of the ether-ester products. This process can be economically advantageous by using cheaper acetic acid—one sourced directly from a wood acetylation process.
Type:
Application
Filed:
December 16, 2019
Publication date:
January 26, 2023
Applicant:
EASTMAN CHEMICAL COMPANY
Inventors:
MESFIN EJERSSA JANKA, KEVIN JOHN FONTENOT
Abstract: A method for manufacture of polyesters with recycle content is described in various aspects. The methods of the present disclosure effectively and cost-efficiently incorporates recycled DMT into existing TPA-based polyester manufacturing systems. Recycle feed compositions for manufacture of polyesters with recycle content and recycled content polyesters are also described.
Type:
Application
Filed:
December 16, 2020
Publication date:
January 26, 2023
Applicant:
Eastman Chemical Company
Inventors:
Earl Edmondson Howell, Jr., Michael Paul Ekart, Travis Wynn Keever, Bob N. Jack, Jonathan Michael Horton, Daniel Lee Martin
Abstract: Disclosed is a method for treating the product stream from a polyester methanolysis depolymerization process wherein the product stream includes dimethyl terephthalate and one or more side species selected from the group consisting of dimethyl phthalate, dimethyl isophthalate, bisphenol-A, an adipic acid diester and colorants. The method includes a) hydrogenating said dimethyl terephthalate to form one or more of dimethyl 1,4-cyclohexanedicarboxylate and 1,4-cyclohexanedimethanol; and (b) hydrogenating one or more of said one or more side species of said product stream. A method for depolymerization of polyester is also described.
Type:
Application
Filed:
December 16, 2020
Publication date:
January 26, 2023
Applicant:
Eastman Chemical Company
Inventors:
William Christopher Ketchie, Noah Glenn McMillan, Michael Paul Ekart, Travis Wynn Keever
Abstract: An electrochemical electrode for use in a biosensor. The electrode comprises a substrate, a palladium metal layer manufactured on the substrate, and a palladium oxide-containing layer manufactured on the palladium metal layer. The palladium metal layer has a thickness of no more than 90 nm, and the palladium oxide-containing layer has a thickness of no more than 40 nm.
Type:
Grant
Filed:
January 30, 2018
Date of Patent:
January 24, 2023
Assignee:
Eastman Chemical Company
Inventors:
Dennis Lee Ashford, II, Spencer Erich Hochstetler
Abstract: Disclosed is a method for depolymerization of polyester. The method includes (a) treating said polyester with methanol under conditions sufficient to depolymerize at least some of said polyester and form a reaction product that includes dimethyl terephthalate and at least one diol; and (b) converting the diol to a compound substantially non-reactive with said with dimethyl terephthalate and the polyester. A method for producing a cyclic carbonate is also described.
Abstract: A cellulose ester composition is provided comprising at least one cellulose ester and at least one polymeric aliphatic polyester (PAP), and optionally at least one impact modifier and/or at least one monomeric plasticizer. Processes for producing the cellulose ester compositions as well as articles made using these compositions are also provided.
Type:
Grant
Filed:
February 13, 2019
Date of Patent:
January 17, 2023
Assignee:
Eastman Chemical Company
Inventors:
Haining An, Wenlai Feng, Michael Eugene Donelson, Thomas Joseph Pecorini
Abstract: A poly(vinyl acetal) composition, such as a poly(vinyl butyral) composition or resin, can be made containing recycle content by the use of a recycle content aldehyde composition as a feedstock to make the PVA or by application of a recycle allotment, such as an allocation or credit, applied to either the aldehyde composition or to the PVA composition. The recycle content is obtained by cracking a recycle content pyrolysis oil to make a variety of olefins, such as propylene or ethylene.
Type:
Application
Filed:
November 6, 2020
Publication date:
January 5, 2023
Applicant:
Eastman Chemical Company
Inventors:
David Eugene Slivensky, Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, William Lewis Trapp, Xianchun Wu
Abstract: This invention relates to at least one copolyester comprising repeat units of the following structure: wherein R and R? represent residues of at least one diol; and wherein R and R? are not the same; wherein R? comprises residues of at least one diacid or diester and wherein n represents number of repeat units; and/or copolyester precursors thereof, and methods of manufacture.
Type:
Application
Filed:
June 26, 2020
Publication date:
January 5, 2023
Applicant:
Eastman Chemical Company
Inventors:
Robert Jacks Sharpe, Emmett Dudley Crawford
Abstract: A process for preparing a recycle cellulose ester and a recycle cellulose ester composition and articles made with such recycle cellulose esters comprising at least one cellulose ester having at least one substituent on an anhydroglucose unit (AU) derived from recycled plastic content syngas are provided. The recycled plastic content syngas can be obtained by gasifying feedstocks containing a solid fossil fuel such as coal, a plastic, and water. The plastic can be post-consumer or postindustrial plastic.
Type:
Application
Filed:
August 16, 2022
Publication date:
December 29, 2022
Applicant:
Eastman Chemical Company
Inventors:
Ronald Buford Sheppard, William Lewis Trapp
Abstract: An alkanolamine composition having a recycle content value is obtained by reacting a recycle content feedstock to make a recycle content alkanolamine or by deducting from a recycle inventory a recycle content value applied to an alkanolamine composition. At least a portion of the recycle content value in the feedstock or m an allotment obtained by an alkanolamine manufacturer has its origin in recycled waste and/or pyrolysis of recycled waste and/or in thermal steam cracking of recycle content pyoil.
Type:
Application
Filed:
November 6, 2020
Publication date:
December 22, 2022
Applicant:
Eastman Chemical Company
Inventors:
David Eugene Slivensky, Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, William Lewis Trapp, Xianchun Wu
Abstract: Processes and systems for making recycle content hydrocarbons, including olefins, from recycled waste material. Recycle waste material may be pyrolyzed to form recycle content pyrolysis oil composition (r-pyoil), at least a portion of which may then be cracked to form a recycle content olefin composition (r-olefin). The r-olefin may then be further separated into product streams in a separation zone downstream of the cracker furnace. In some cases, presence of recycle content hydrocarbons may facilitate more efficient operation of one or more distillation columns in the separation zone, including the deethanizer and ethylene fractionator.
Type:
Application
Filed:
October 29, 2020
Publication date:
December 22, 2022
Applicant:
Eastman Chemical Company
Inventors:
Daryl Bitting, Xianchun Wu, David Eugene Slivensky, Michael Gary Polasek
Abstract: Processes and systems for making recycle content hydrocarbons, including olefins, from recycled waste material. Recycle waste material may be pyrolyzed to form recycle content pyrolysis oil composition (r-pyoil), at least a portion of which may then be cracked to form a recycle content olefin composition (r-olefin). The r-olefin may then be further separated into product streams in a separation zone downstream of the cracker furnace. The presence of recycle content hydrocarbons may facilitate more efficient operation of one or more distillation columns in the separation zone, including the propylene fractionator.
Type:
Application
Filed:
October 29, 2020
Publication date:
December 22, 2022
Applicant:
Eastman Chemical Company
Inventors:
Daryl Bitting, Xianchun Wu, David Eugene Slivensky, Michael Gary Polasek
Abstract: A recycle content cellulose ester and method of making a recycle content cellulose ester wherein the recycle content is derived directly or indirectly from the cracking of recycle content pyrolysis oil and/or gas. The cracking of the pyrolysis oil can be conducted in a gas furnace or a split furnace.
Type:
Application
Filed:
November 6, 2020
Publication date:
December 22, 2022
Applicant:
Eastman Chemical Company
Inventors:
David Eugene Slivensky, Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, William Lewis Trapp, Xianchun Wu
Abstract: Processes and systems for making recycle content hydrocarbons, including olefins, from recycled waste material. Recycle waste material may be pyrolyzed to form recycle content pyrolysis oil composition (r-pyoil), at least a portion of which may then be cracked to form a recycle content olefin composition (r-olefin). The r-olefin may then be further separated into product streams in a separation zone downstream of the cracker furnace. In some cases, presence of recycle content hydrocarbons may facilitate more efficient operation of one or more distillation columns in the separation zone, including the debutanizer.
Type:
Application
Filed:
October 29, 2020
Publication date:
December 22, 2022
Applicant:
Eastman Chemical Company
Inventors:
Michael Gary Polasek, Daryl Bitting, David Eugene Slivensky, Xianchun Wu, Carey Dan Ashcroft, Jerome Leonard Stavinoha, Jr.
Abstract: Processes and systems for making recycle content hydrocarbons, including olefins, using a cracker furnace having enhanced coil design. In some cases, the design of the furnace may prevent coking, so that the run length of the furnace is longer than conventional cracking furnaces. Cracker feed streams to the furnace can include recycle content pyrolysis oil and may be used to form olefin-containing effluent stream having recycle content.
Type:
Application
Filed:
October 29, 2020
Publication date:
December 22, 2022
Applicant:
Eastman Chemical Company
Inventors:
Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, David Eugene Slivensky, Xianchun Wu
Abstract: A composition having a recycle content value is obtained by reacting a recycle content feedstock to make a recycle content oxo alcohol or oxo plasticizer or by deducting from a recycle inventory a recycle content value applied to an oxo alcohol or oxo plasticizer composition. At least a portion of the recycle content value in the feedstock or in an allotment obtained by an oxo alcohol or oxo plasticizer manufacturer has its origin in recycled waste and/or pyrolysis of recycled waste and/or in thermal steam cracking of recycle content pyoil.
Type:
Application
Filed:
November 6, 2020
Publication date:
December 22, 2022
Applicant:
Eastman Chemical Company
Inventors:
David Eugene Slivensky, Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, William Lewis Trapp, Xianchun Wu
Abstract: A pyrolysis method and system are provided that may utilize a recycled plastic feedstock that comprises various types of waste plastics or a feedstock that comprises various types of waste plastics and at least one crude post-industrial liquid waste. The disclosed pyrolysis method and system may be configured to convert various types of waste plastics, including post-customer and post-industrial wastes, and/or crude post-industrial liquid wastes into useful pyrolysis oils.
Type:
Application
Filed:
October 29, 2020
Publication date:
December 22, 2022
Applicant:
Eastman Chemical Company
Inventors:
Xianchun Wu, Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, David Eugene Slivensky, Damon Ray Billodeaux
Abstract: This invention relates to a curable composition comprising: I. a first component comprising a resin having at least one functional group selected from the group consisting of ?-ketoester and malonate functional groups, II. a second component comprising at least one curing agent having at least one aldehyde functional group, and III. a third component comprising at least one primary amine or at least one secondary amine, salts thereof, or combinations thereof.
Type:
Grant
Filed:
December 6, 2019
Date of Patent:
December 20, 2022
Assignee:
Eastman Chemical Company
Inventors:
Shawn Marie Dougherty, Terri Roxanne Carvagno, Monika Karin Wiedmann Boggs, Nick Allen Collins, Robert Jacks Sharpe, Ke Feng, Thauming Kuo, Liu Deng, Christopher Harlan Burk, Vasudev R. Bhonde
Abstract: A composition is contained a blend zone prior to refining containing non-fibrillated virgin cellulose fibers, waste/recycle cellulose fibers or both; cellulose ester fibers, water, and one or more additives comprising fillers, internal sizing agents, biocides, process anti-foaming agents, colorants, optical modifiers, or a combination thereof. An in-line mixer can be used for adding the additives, and the consistency of the composition is lowered relative to a feed of material from a hydropulper.
Type:
Grant
Filed:
July 26, 2019
Date of Patent:
December 20, 2022
Assignee:
Eastman Chemical Company
Inventors:
Charles Stuart Everett, Melvin Glenn Mitchell, Kenny Randolph Parker, Koushik Ghosh, Mounir Izallalen