Abstract: A process for the di-tertiary-peroxide synthesis, wherein the condensation reaction between a tertiary hydroperoxide and a tertiary alcohol is carried out in the presence of an acid catalyst, constituted by a compound having a mono-sulphonated aromatic ring selected from the following formulae:
wherein: R is an alkyl group having from 2 to 9 carbon atoms, preferably from 2 to 6; R′ and R″ are alkyl groups having a number of from 1 to 9 carbon atoms, preferably from 1 to 6.
Abstract: Aqueous emulsions based on acrylic polymers and their use for preparing films to be used in processes of preparation of cathode ray tubes, having filming temperature between about 20 and 40.degree. C. which after drying produce films which, submitted to heating in nitrogen atmosphere, have a weight loss, for films having a thickness of 1-2 mm, and for the following cycle of heating:11.degree. C./minute from 25 to 375.degree. C.,5.degree. C./minute from 375 to 440.degree. C.,isotherm at 440.degree. C. for 45 minutes,respectively of:from 25 to 245.degree. C. lower than 15% by weightfrom 245 to 375.degree. C. from 30 to 70% by weightfrom 375 to 440.degree. C. of 97-99% by weightafter the isotherm at 440.degree. C. the remaining residue is lower than about 0.3% by weight, the curve gradient in the on set point ranging from 0.03 to 0.08 mg/.degree. K, and at 360.degree. C. from 0.12 to 0.30 mg/.degree. K; the on set temperature being at most of 300.degree. C.
Type:
Grant
Filed:
January 7, 1999
Date of Patent:
May 9, 2000
Assignee:
Elf Atochem S.r.l.
Inventors:
Ivan Fuso Nerini, Massimo Cesana, Daniele Becchi