Abstract: Polyamide mixtures (blends) or alloys having improved transparency, chemical resistance and slight natural color, as well as a process improving the melting capacity and homogeneity of blends of polyamide according to formula (I) and partly crystalline polymers according to formula (II). Transparent polyamide blends are obtained which exhibit improved properties with respect to transparency, color, and chemical resistance, in particular stress cracking resistance against isopropanol, without resulting losses in the mechanical properties. At the same time it was possible to distinctly raise the throughput during extrusion while maintaining optimum transparency.
Abstract: The invention concerns an adhesive for the treatment of reinforcement inserts for the production of reinforced polymer products in the form of an aqueous dispersion, containing an adhesive as a solid and additives. The aqueous dispersion has a solids fraction of 55-85 wt % provided that the average particle diameter of the solids is <2.0 &mgr;m.
Abstract: The present invention provides barrier composite resin compositions and moulded bodies, comprising (a) aromatic polyamide resins or polyamide resin compositions containing at least one aromatic polyamide resin, and (b) a layered silicate modified by a triazine compound derivative.
Abstract: Copolyamides, consisting of polycondensation products of the following components: caprolactam 10 to 45 mol-%, laurolactam 30 to 55 mol-%, at least 2 dicarboxylic acids 20 to 50 mol-% of the following compounds, aliphatic &agr;,&ohgr;-dicarboxylic acids with 6 up to 14 C atoms inclusively, terephthalic acid, isophthalic acid and 2,6-naphthalene dicarboxylic acid, wherein the content of aromatic dicarboxylic acids is lower than 10 mol-%, with reference to the allover amount of the above-mentioned components, which add up to 100 mol-%, a diamine mixture in an amount that is equimolar to that of the dicarboxylic acids, chosen from the group of the following substances, hexamethylene diamine, piperazine and/or 2-methyl- 1,5-diaminopentane, wherein the molar content of hexa-methylene diamine is between 75 and 95 mol-% with reference to the diamine mixture.
Type:
Application
Filed:
May 9, 2001
Publication date:
February 21, 2002
Applicant:
EMS-Chemie Ag
Inventors:
Gerhard Poessnecker, Jurgen Spindler, Eberhard Kinkelin
Abstract: Thermoplastic multilayer composite, particularly in the form of a multilayer hose, a multilayer pipe or a multilayer container, containing at least one intermediate layer made of a molding compound on the basis of ethylene/vinyl alcohol copolymers between layers made of molding compounds on the basis of polyamide, the intermediate layer being bonded via at least one adhesion-promoting layer made of a molding compound on the basis of polyamide selected from the group of copolyamide 6/12, block copolyamide 6/12, polyamide 612, polyamide 610, a mixture of polyamide 6 and polyamide 12 with compatibilizer, a mixture of polyamide 6 and polyamide 11 with compatibilizer, with at least one neighboring layer made of a molding compound on the basis of polyamide 12, polyamide 11, polyamide 1010, polyamide 1012, or polyamide 1212.
Abstract: The invention provides polyamide resin compositions with good mechanical properties and dimensional stability during water absorption. Polyamide resin composition, comprising 100 parts by weight of resin contents composed of (A) 60 to 98% by weight of polyamide resin, (B) 40 to 2% by weight of polyolefine resin having dicarboxylic acid anhydride groups, as well as (C) 0.3 to 30 parts by weight of triazine-containing layered silicate with intercalated triazine compound derivatives with at least one positive charge.
Abstract: The invention relates to a reversible thermotropic plastics molding compound. Thermotropic molding compounds of this kind are used, amongst other things, for glass and coverings for shading and light/heat regulation in houses, cars, etc. The molding compound according to the invention consists of two compounds which are not thermodynamically miscible with one another. The first component consists of a plastics material, while the second component is not liquid-crystalline and has a refractive index which is the same as the first component in the transparent range and the temperature dependency of which is different from the temperature dependency of the refractive index of the first component. On raising the temperature, the transmission of the molding compound is thus altered.
Abstract: Novel, quick-crystallizing hot-melt adhesive masses having a melting point between 60° and 100° C. comprise a statistically-proportioned copolyester or copolyetherester based on terephthalic acid, adipic acid and a mixture of aliphatic diols; the molar proportion of terephthalic acid is between 55 and 85 mole %, relative to the total acid quantity; and the molar proportion of adipic acid is between 15 and 40 mole %. A combination of butane diol and hexane diol is used as the diol component; the molar component of butane diol is between 40 and 55 mole %; and the molar proportion of hexane diol is between 40 and 60 mole %. Up to 15 mole % of a dimer acid having a molar mass between 400 and 800 g/mole, or up to 10 mole % of a higher-molecular polyethylene glycol having a molecular mass of 600 to 4000 g/mole, can be used to increase the flexibility. The copolyester or copolyetherester hot-melt adhesive masses of the invention can be used in the hot-melt method, and in powder-form coating methods.
Type:
Grant
Filed:
July 13, 1999
Date of Patent:
July 3, 2001
Assignee:
EMS Chemie AG
Inventors:
Eberhard Kinkelin, Jürgen Spindler, Gerhard Pössenecker
Abstract: The invention relates to a process for preparing a &bgr;-hydroxyalkylamide, in which alkyl esters are reacted with &bgr;-aminoalcohols in the absence of solvents and in the presence of basic catalysts, where, to improve the selectivity, the ratio of equivalents of ester to equivalents of amine is 1:1.001 to 8.
Type:
Grant
Filed:
May 28, 1999
Date of Patent:
May 22, 2001
Assignee:
EMS-Chemie AG
Inventors:
Andreas Kaplan, Rene Gisler, Albert Reich
Abstract: In a core-shroud bicomponent fiber, which exhibits a core and a shroud at least partially enveloping the core, an elevated abrasion behavior, a low compaction under exposure to temperature and pressure and a high strength of the fibers is achieved by having the shroud consist of 45-98% w/w of a first polyamide having a melting point exceeding 280° C., and 2-20% w/w of a layer silicate.
Type:
Grant
Filed:
November 24, 1999
Date of Patent:
March 27, 2001
Assignee:
Ems-Chemie AG
Inventors:
Jürgen Spindler, Thomas Weller, Simon Sutter, Gunther Schäch
Abstract: A method for the transformation of cis- and trans-cyclododecene oxide into cyclododecanone, comprising carrying out the reaction with catalytically activated hydrogen in the presence of a copper catalyst at a temperature of 150-260° C. and at a pressure in a range from atmospheric pressure to elevated pressure. The reaction proceeds via the intermediate products cyclododecen-3-ol and cyclododecen-3-one, and with cyclododecene being obtained as a by-product.
Abstract: The invention concerns a softener-free polyamide prepared by polycondensation and/or polymerization of polyamide-forming monomers, wherein it was obtained by adding 5-50 wt. % of a dimer diol with a molecular weight within the range of 400-1000 and/or corresponding OH-terminated polyesters.
Abstract: The invention relates to special amyloses for producing biodegradable, clear, transparent and flexible plastic, in particular sheets and films, whicha) are swellable, but not soluble, in cold water;b) yield homogenous, flowable quasi-solutions without formation of gels if they are heated, with stirring, to temperatures above 80.degree. C., at atmospheric pressure; during cooling to a temperature of 50.degree. C., this state is maintained for at least five minutes, without gel formation or retrogradation, and the solution in a concentration between 5 and 25% is applicable to knife coating onto a plane surface with a gap width between 100 and 700 .mu.m.
Type:
Grant
Filed:
November 4, 1993
Date of Patent:
December 20, 1994
Assignees:
Battelle-Institut e.V., EMS-Chemie AG
Inventors:
Rainer Frische, Klaus Wollmann, Renate Gross-Lannert, Judith Schneider, Bernd Best