Patents Assigned to Endura S.P.A.
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Patent number: 10149478Abstract: The present invention provides a formulation characterised by the simultaneous presence in cyclodextrin based supramolecular complexes, of two components, one of which is a neonicotinoid selected from the group consisting of Thiacloprid and Thiamethoxam and the other possesses an activity synergistic with the first, enhancing its effectiveness. The synergistic component that is able to synergistically enhance the activity of the active principle is piperonyl butoxide, and. Processes for preparing said formulation and its use for the activities herein indicated are further aspects of the present invention.Type: GrantFiled: August 24, 2017Date of Patent: December 11, 2018Assignee: Endura S.P.A.Inventors: Oreste Piccolo, Valerio Borzatta, Giovanna Delogu, Elisa Capparella, Cristina De Candia, Carlotta Gobbi, Giovanna Di Blasi
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Patent number: 10104890Abstract: Provided are compositions comprising (i) a neonicotinoid; and (ii) a compound of formula (I) or (II), preferably wherein the composition is a pesticide composition, for example an insecticide composition. Also provided is use of a compound of formula (I) or (II) as a neonicotinoid synergist and use of a compound of formula (I) or (II) in combination with a neonicotinoid. Further provided are methods for controlling pests.Type: GrantFiled: March 7, 2012Date of Patent: October 23, 2018Assignees: Rothamsted Research Limited, Endura S.P.A.Inventors: Graham David Moores, Despina Philippou, Valerio Borzatta, Elisa Capparella
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Publication number: 20170347658Abstract: The present invention provides a formulation characterised by the simultaneous presence in cyclodextrin based supramolecular complexes, of two components, one of which is a neonicotinoid selected from the group consisting of Thiacloprid and Thiamethoxam and the other possesses an activity synergistic with the first, enhancing its effectiveness. The synergistic component that is able to synergistically enhance the activity of the active principle is piperonyl butoxide, and. Processes for preparing said formulation and its use for the activities herein indicated are further aspects of the present invention.Type: ApplicationFiled: August 24, 2017Publication date: December 7, 2017Applicant: Endura S.P.A.Inventors: Oreste Piccolo, Valerio Borzatta, Giovanna Delogu, Elisa Capparella, Cristina De Candia, Carlotta Gobbi, Giovanna Di Blasi
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Patent number: 9775340Abstract: The present invention provides a formulation characterized by the simultaneous presence in cyclodextrin based supramolecular complexes, of two components, one of which possesses insecticidal, acaricidal, fungicidal, snailcidal or vermicidal activity and the other possesses an activity synergistic with the first, enhancing its effectiveness. The biologically active substance is chosen from the following classes of chemical products: carbamates, organophosphates, thioureas, pentatomic or hexatomic heterocycles in which 1, 2 or 3 nitrogen atoms are present. The synergistic substance can be chosen from components containing at least one aromatic or non aromatic carbocyclic ring, such as piperonyl butoxide, sesamol, verbutin or MGK 264. For the same dose, the activity of the present formulations is greater than that of the mixture of the two active components alone or separately complexed with cyclodextrin.Type: GrantFiled: April 21, 2006Date of Patent: October 3, 2017Assignee: ENDURA S.P.A.Inventors: Oreste Piccolo, Valerio Borzatta, Giovanna Delogu, Elisa Capparella, Cristina de Candia, Carlotta Gobbi, Giovanna di Blasi
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Patent number: 9363995Abstract: The invention relates to the use of a derivative compound of 1,3-benzodioxole of formula (I) wherein R is a linear or branched (C4-C10)alkyl substituent as a synergistic compound of insecticidal active ingredients insecticidal compositions comprising at least one compound of Formula (I) and at least one insecticidal active ingredient are also described.Type: GrantFiled: March 14, 2013Date of Patent: June 14, 2016Assignee: Endura S.P.A.Inventors: Carlotta Gobbi, Valerio Borzatta, Elisa Capparella
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Patent number: 9247750Abstract: Described are new insecticide compounds that are derived from 2,2-dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylic acid, also known as chrysanthemic acid, insecticidal compositions that contain the compounds, methods of synthesizing the compounds and methods of eliminating harmful insects from a substrate including bringing the substrate into contact with an effective amount of one or more such compounds.Type: GrantFiled: September 15, 2008Date of Patent: February 2, 2016Assignee: Endura S.P.A.Inventors: Valerio Borzatta, Greta Varchi, Elisa Capparella, Alberto Guerrini, Arturo Battaglia, Federico Trefiletti
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Patent number: 9044012Abstract: Use of formulations comprising polyurea microcapsules obtainable by interfacial polymerization of diphenylmethylen-4,4?-diisocyanate (MDI), optionally in admixture with polymethylenepolyphenylisocyanate (PAPI), said formulations having a prolonged knockdown and killing effect longer than at least 3 months, preferably at least of 6 months, still more preferably at least of 9 months from the application, wherein the microcapsules comprise: an active principle selected from the pyrethroid and/or neonicotinoid classes, synergizing agents selected between PEO and Verbutin, the concentration of the active principle in the microcapsule as % by weight on the total of the microcapsule is comprised between 1 to and 60% the average diameter of the microcapsules is comprised between 2 and 50 ?m.Type: GrantFiled: November 1, 2012Date of Patent: June 2, 2015Assignees: ENDURA S.P.A., SIPCAM S.P.A.Inventors: Valerio Borzatta, Marco Bernardini, Carlotta Gobbi, Giorgio Freschi, Edoardo Russo, Matteo Campanati, Francesca Borgo
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Publication number: 20150038465Abstract: The invention relates to the use of a derivative compound of 1,3-benzodioxole of formula (I) wherein R is a linear or branched (C4-C10) alkyl substituent as a synergistic compound of insecticidal active ingredients insecticidal compositions comprising at least one compound of Formula (I) and at least one insecticidal active ingredient are also described.Type: ApplicationFiled: March 14, 2013Publication date: February 5, 2015Applicant: ENDURA S.P.A.Inventors: Carlotta Gobbi, Valerio Borzatta, Elisa Capparella
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Patent number: 8809389Abstract: A composition comprising an alkynyl phenoxy compound of Formula (I) as a synergist and a pesticidal active ingredient is described, wherein R1 and R2, similar or different, are (C1-C4)alkyl or R1O— and R2O— together represent a group —O—CH2—O—, —O—CH(CH3)—O, —O—CH2—CH2—O—, —O—CH2—CH2—, R3 is (C1-C6)alkyl, (C3-C6)alkenyl or —B—(CH2—CH2—O)z-R6 where B is —CH2—O— or —O—, z is 0, 1 or 2 and R6 is (C1-C4)alkyl; R4 is hydrogen or methyl; R5 is hydrogen or methyl; x is an integer from 1 to 2; y is 0, 1 or 2; with the proviso that when R3 is —B—(CH2CH2—O)z-R6, y is 1 and 5-(propargyloxy)-benzo[1,3]dioxole is excluded.Type: GrantFiled: August 18, 2010Date of Patent: August 19, 2014Assignees: Endura S.p.A., Rothamsted Research Ltd.Inventors: Valerio Borzatta, Elisa Capparella, Leni Moroni, Graham Moores, Despina Philippou
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Publication number: 20140107162Abstract: Provided are compositions comprising (i) a neonicotinoid; and (ii) a compound of formula (I) or (II), preferably wherein the composition is a pesticide composition, for example an insecticide composition. Also provided is use of a compound of formula (I) or (II) as a neonicotinoid synergist and use of a compound of formula (I) or (II) in combination with a neonicotinoid. Further provided are methods for controlling pests.Type: ApplicationFiled: March 7, 2012Publication date: April 17, 2014Applicants: ENDURA S.P.A., ROTHAMSTED RESEARCH LIMITEDInventors: Graham David Moores, Despina Philippou, Valerio Borzatta, Elisa Capparella
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Publication number: 20130115261Abstract: Use of formulations comprising polyurea microcapsules obtainable by interfacial polymerization of diphenylmethylen-4,4?-diisocyanate (MDI), optionally in admixture with polymethylenepolyphenylisocyanate (PAPI), said formulations having a prolonged knockdown and killing effect longer than at least 3 months, preferably at least of 6 months, still more preferably at least of 9 months from the application, wherein the microcapsules comprise: an active principle selected from the pyrethroid and/or neonicotinoid classes, synergizing agents selected between PEO and Verbutin, the concentration of the active principle in the microcapsule as % by weight on the total of the microcapsule is comprised between to and 60% the average diameter of the microcapsules is comprised between 2 and 50 ?m.Type: ApplicationFiled: November 1, 2012Publication date: May 9, 2013Applicants: SIPCAM S. P. A., ENDURA S. P. A.Inventors: ENDURA S. P. A., SIPCAM S. P. A.
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Patent number: 8357803Abstract: The present invention relates to the process of preparation of 2,3,4,9-tetrahydro-1/?/-?-carbolin-3-carboxylic acid esters substituted in position 1 of the general formula (I). in the preferred diastereoisomeric form through a single step starting from tryptophan in racemic form and/or its enantiomers and from 3,4-(methylenedioxy)benzaldehyde.Type: GrantFiled: February 20, 2009Date of Patent: January 22, 2013Assignee: Endura S.p.A.Inventors: Valerio Borzatta, Dina Scarpi, Antonio Guarna, Ernesto G. Occhiato
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Patent number: 8337871Abstract: The present invention provides a new insecticide formulation based on cyclodextrin characterized in that the active substance (insecticide and/or insect growth regulator), and a compound synergistic with the active substance, are complexed simultaneously with cyclodextrin. The formulation presents as a solid or as a solid/oil composition, and is soluble or completely emulsifiable in water or in aqueous mixtures of water miscible solvents. The activity of the present formulations was found to be greater than that of a mixture of the two active components each complexed separately with cyclodextrin, for the same dose. The preparation process of said formulation and its use as an insecticide in agriculture, for veterinary use or to eliminate household insects, are further aspects of the present invention.Type: GrantFiled: October 26, 2004Date of Patent: December 25, 2012Assignee: Endura S.p.A.Inventors: Oreste Piccolo, Giovanna Delogu, Valerio Borzatta
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Patent number: 8025894Abstract: The present invention relates to a new formulation characterised by the presence of two components, one of which (A) possesses insecticidal, acaricidal, fungicidal, snailcidal or vermicidal activity and the other (B) exhibits synergistic activity with the first by enhancing its effectiveness, and in which the average release time of component (A) is 1 to 12 hours later than the average release time of component (B). The formulation is obtained by: a) separate microencapsulation of both components (A) and (B) within a multilayer system of specific polymers in which component (A) is in a more interior portion of the capsule than component (B), being separated from component (B) by a polymer layer of suitable thickness (FIG. 1); b) microencapsulation of both components within a single layer system (FIG. 2), combined with an immediate-release emulsion/microemulsion containing an additional amount of component (B).Type: GrantFiled: April 20, 2006Date of Patent: September 27, 2011Assignee: Endura S.p.A.Inventors: Valerio Borzatta, Oreste Picolo, Elisa Capparella
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Patent number: 8017557Abstract: The present invention has as subject, the use of benzodioxole derivatives as modulators of the activity or of the content of protein hydrolases in plants. Such a new use allows the increase of the natural or induced defences of the plant.Type: GrantFiled: February 13, 2003Date of Patent: September 13, 2011Assignee: Endura S.p.A.Inventors: George Denys Glynne Jones, Valerio Borzatta
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Publication number: 20100285960Abstract: A method for regulating the release rate of microencapsulated actives comprising: 1a) addition or subtraction of piperonylbutoxide (PBO), component B) to 2a) formulations A) comprising at least one microencapsulated active having agrochemical activity, optionally PBO outside the microcapsule, 3a) dilution by water of component A) and/or component B) until the active application dose, the ratio by weight PBO/active ranges from 0.1 to 80, the PBO subtraction being feasible only when the PBO is present outside the microcapsule of the formulation A).Type: ApplicationFiled: December 23, 2008Publication date: November 11, 2010Applicant: ENDURA S.p.A.Inventors: Carlotta Gobbi, Lucio Bassetti, Valerio Borzatta
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Publication number: 20100210721Abstract: Described are new insecticide compounds that are derived from 2,2-dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylic acid, also known as chrysanthemic acid, insecticidal compositions that contain the compounds, methods of synthesizing the compounds and methods of eliminating harmful insects from a substrate including bringing the substrate into contact with an effective amount of one or more such compounds.Type: ApplicationFiled: September 15, 2008Publication date: August 19, 2010Applicant: ENDURA S.P.A.Inventors: Valerio Borzatta, Greta Varchi, Elisa Capparella, Alberto Guerrini, Arturo Battaglia, Federico Trefiletti
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Publication number: 20100173781Abstract: A method for modulating the release rate of microencapsulated active ingredients comprising the following steps: I) preparation of an aqueous suspension A) comprising microcapsules of at least one active ingredient, II) preparation of a liquid emulsifiable in water, component B), comprising a solvent of the active ingredient and at least a surfactant, III) water, component C), for diluting to the application dose the active ingredient, and mixing A), B) and C).Type: ApplicationFiled: June 27, 2008Publication date: July 8, 2010Applicant: ENDURA S.p.A.Inventors: Carlotta Gobbi, Lucio Bassetti, Valerio Borzatta, Marco Bernardini, Francesca Borgo, Luigi Capuzzi
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Patent number: 7723539Abstract: Catalysts are described based on metal complexes derived from optically active s compounds, chosen from the classes consisting of bisoxazolines and salicylaldimines supported on an organic or inorganic matrix and employed in particular for the synthesis of optically active chrysanthemic acid.Type: GrantFiled: June 14, 2005Date of Patent: May 25, 2010Assignee: ENDURA S.p.A.Inventors: Silvia Carloni, Valerio Borzatta, Leni Moroni, Giada Tanzi, Giovanni Sartori, Raimondo Maggi
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Patent number: 7544843Abstract: A new process for synthesizing 3,4-dioxo-substituted aromatic aldehydes by Oppenauer oxidation of the corresponding benzyl alcohols is described. The process, which specifically uses formaldehyde as hydrogen acceptor, proceeds with unexpectedly high yields and conversion percentages, allowing low cost access to finished and intermediate products of high industrial interest in the field of pharmaceutical products and fragrances.Type: GrantFiled: July 25, 2006Date of Patent: June 9, 2009Assignee: Endura S.p.A.Inventors: Elisa Capparella, Elisa Poluzzi, Valerio Borzatta