Patents Assigned to Engelhard Corporation
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Patent number: 7101473Abstract: An additive to enhance the activity of an FCC catalyst containing zeolite and matrix components comprises zeolite microspheres having a novel morphology comprising a macroporous matrix and crystallized zeolite freely coating the walls of the pores of the matrix. The additives formed from microspheres containing a metakaolin and kaolin calcined through its exotherm, the latter calcined kaolin being derived from a kaolin having a high pore volume. Kaolin having a high pore volume can be a pulverized ultrafine kaolin or a kaolin which has been pulverized to have an incipient slurry point less than 57% solids.Type: GrantFiled: May 31, 2002Date of Patent: September 5, 2006Assignee: Engelhard CorporationInventor: Michael Thomas Hurley
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Patent number: 7083829Abstract: A method and apparatus for treating the atmosphere comprising moving a vehicle through the atmosphere, the vehicle having at least one atmosphere contacting surface and a pollutant treating composition located on said surface. A specific embodiment comprises coating a motor vehicle radiator with pollutant treating catalyst.Type: GrantFiled: October 12, 2004Date of Patent: August 1, 2006Assignee: Engelhard CorporationInventors: Jeffrey B. Hoke, Fred M. Allen, Patrick W. Blosser, Zhicheng Hu, Ronald M. Heck
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Patent number: 7080505Abstract: A vehicular atmosphere cleansing system utilizes a regenerative wheel having flow channels extending through the wheel coated with an adsorbant. An atmosphere stream passes through a first position dependent portion of the wheel where VOC's including HC's are adsorbed while a heated atmosphere stream passes through a second position dependent regenerative portion of the wheel whereat VOC's are desorbed. The adsorbant is activated carbon having particles of micropore size adhered to the substrate by a silicone binder producing high adsorption efficiencies while withstanding relatively high regenerative heat temperatures resulting from exhaust gas sensible heat. A hydrocarbon senses HC in the desorbed heated atmosphere stream to rotatively and sequentially index pie shaped, segmented portions of the wheel into the wheel's regenerative region while also functioning as the main component of an OBD device for the system.Type: GrantFiled: July 8, 2003Date of Patent: July 25, 2006Assignee: Engelhard CorporationInventors: Gerald S. Koermer, Jeffrey B. Hoke, Ronald M. Heck, Terence C. Poles, Edward T. Wolynic
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Patent number: 7078004Abstract: The present invention relates to a method and article for treating a diesel engine exhaust stream. The stream is contacted with an upstream catalytic composition having a cerium component and/or a zeolite component to reduce the quantity and amount of the particulate matter in the exhaust stream. The stream passes from the upstream catalytic composition to a particulate filter located downstream from the upstream catalytic composition.Type: GrantFiled: January 10, 2003Date of Patent: July 18, 2006Assignee: Engelhard CorporationInventors: Kenneth E. Voss, Joseph C. Dettling, Stanley Roth, Ramesh Kakwani, Yiu Kwan Lui, Alexander Gorel, Gary W. Rice
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Patent number: 7074375Abstract: A hydrocarbon gas such as methane and LPG is desulfurized in the presence of oxygen and an oxidation catalyst to convert sulfur compounds in the gas to sulfur oxides. The sulfur oxides are then trapped downstream of the oxidation by an adsorbent. The amount of oxygen added to the hydrocarbon gas to promote oxidation is such that the sulfur compounds are selectively oxidized and the oxidation of the hydrocarbon gas is minimized to reduce hydrogen formation.Type: GrantFiled: December 3, 2002Date of Patent: July 11, 2006Assignee: Engelhard CorporationInventors: Jordan K. Lampert, Lawrence Shore, Robert J. Farrauto, Shinn Hwang
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Patent number: 7055311Abstract: An NOx emission system for diesel powered vehicles has a “Y” exhaust system with an NOx adsorber catalyst in each leg and an oxidation catalyst in the combined leg. One bank of cylinders sends exhaust gases to one of the “Y” legs while a second bank of cylinders send exhaust gases to the other “Y” leg. Composition of the exhaust gases in each leg is independently controlled by the engine's ECU so that exhaust gases in one leg are rich for regenerating the NOx adsorber catalyst in that leg while exhaust gas composition in the other leg is lean so that the combined gas stream is always lean and reductant slip is oxidized in the oxidation catalyst.Type: GrantFiled: August 31, 2002Date of Patent: June 6, 2006Assignee: Engelhard CorporationInventors: Tilman Wolfram Beutel, John Lawrence Calabrese
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Patent number: 7045056Abstract: A composition for controlling CO and NOx emissions during FCC processes comprises (i) acidic oxide support, (ii) cerium oxide, (iii) lanthanide oxide other than ceria such as praseodymium oxide (iv), optionally, oxide of a metal from Groups Ib and IIb such as copper, silver and zinc and (v) precious metal such as Pt and Pd.Type: GrantFiled: October 10, 2002Date of Patent: May 16, 2006Assignee: Engelhard CorporationInventors: Chandrasbekhar Pandurang Kelkar, Yuejin Li, Rostam J. Madon, Marius Vaarkamp
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Patent number: 7045007Abstract: An effect pigment is constituted by coated laminar platelets in which the platelets are a mixture of different platelet materials, one of which is platy glass or platy aluminum oxide, and in which the pigment exhibits visual homogeneity.Type: GrantFiled: December 31, 2002Date of Patent: May 16, 2006Assignee: Engelhard CorporationInventor: Frank Bagala, Sr.
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Patent number: 7045485Abstract: A composition for controlling NOx emissions during FCC processes comprises (i) an acidic oxide support, (ii) cerium oxide, (iii) a lanthanide oxide other than ceria such as praseodymium oxide, and (iv), optionally, an oxide of a metal from Groups Ib and IIb such as copper, silver and zinc.Type: GrantFiled: January 13, 2004Date of Patent: May 16, 2006Assignee: Engelhard CorporationInventors: Chandrashekhar Pandurang Kelkar, David Stockwell, Samuel Tauster
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Publication number: 20060100452Abstract: The present invention relates to a catalyst nickel, silica, alumina and magnesium, wherein the nickel to magnesium atomic ratio is 5-75. In particular the present invention relates to a catalyst comprising nickel, silica, alumina and magnesium, wherein the nickel to silicium atomic ratio (Ni/Si) is 2 to 30 the nickel to aluminum atomic ratio (Ni/Al) is 9 to 40 and the nickel to magnesium atomic ratio (Ni/Mg) is 5-75. The invention further relates to a method for preparing such a catalyst. The invention further relates to a process for hydrogenating unsaturated organic compounds.Type: ApplicationFiled: October 17, 2003Publication date: May 11, 2006Applicant: Engelhard CorporationInventors: Pieter Berben, Tjalling Rekker
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Patent number: 7041421Abstract: Disclosed is a red pigment compound containing a pigment represented by Formula I: having a certain Hue Angle and Apparent Strength. Also disclosed is a method of making a red pigment composition. Further disclosures relate to coating compositions, ink compositions, plastic compositions, electrostatic toner compositions, powder coating compositions, paint compositions, and paper compositions containing the red pigment represented by Formula I.Type: GrantFiled: September 8, 2003Date of Patent: May 9, 2006Assignee: Engelhard CorporationInventor: Amrit P. Bindra
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Patent number: 7041263Abstract: The present invention relates to a composite of cerium, zirconium and samarium components, a catalyst composition containing such composite and the use of the catalyst composition for the treatment of a gas stream to reduce contaminants contained therein. The catalyst composition has the capability of substantially simultaneously catalyzing the oxidation of hydrocarbons and carbon monoxide and the reduction of nitrogen oxides.Type: GrantFiled: November 15, 2002Date of Patent: May 9, 2006Assignee: Engelhard CorporationInventor: Shiang Sung
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Patent number: 7037875Abstract: A support for a catalyst for controlling vehicular exhaust emissions comprising a high surface area refractory metal oxide, e.g., gamma-alumina, having a monomolecular layer of a second oxide selected from the group consisting of titanium dioxide, cerium dioxide and zirconium dioxide. Typically, the monomolecular layer will have a thickness of less than about 10 angstroms. The support may be converted into a vehicular exhaust emission control catalyst by depositing the support on a substrate such as cordierite depositing a precious metal component such as platinum on at least part of the monomolecular layer. Preferably, the catalyst will also contain at least one NOx storage component deposited on at least part of the monomolecular layer. Catalysts prepared using the catalyst supports of the invention exhibit outstanding thermal stability and resistance to sulfur poisoning.Type: GrantFiled: April 4, 2003Date of Patent: May 2, 2006Assignee: Engelhard CorporationInventors: Zhicheng Hu, Knut Wasserman, Patrick L. Burk, Youchang Xie, Wei Lin
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Patent number: 7022644Abstract: Hydrogen sulfide formation is suppressed by a three-way conversion catalyst having an underlayer and a topcoat overlying the under layer. The under layer is prepared by dispersing a Group IIa metal oxide such as an oxide of magnesium, calcium, barium or strontium on a carrier such as a refractory metal oxide monolith. A topcoat overlying the undercoat is comprised of a three-way conversion catalyst material such as a platinum-group metal catalytic component, e.g., platinum, palladium, rhodium or mixtures thereof.Type: GrantFiled: February 20, 2002Date of Patent: April 4, 2006Assignee: Engelhard CorporationInventors: John S. Foong, Harold N. Rabinowitz
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Patent number: 7022646Abstract: A layered catalyst composite for controlling vehicular exhaust emissions is disclosed. The composite comprises a substrate such as cordierite, at least one bottom layer deposited on the substrate containing a precious metal component such as platinum and at least one NOx storage component present in the amount of about 0.3 to about 1.5 g/in3, and at least one top layer deposited on the bottom layer containing a precious metal component such as platinum and at least one NOx storage component present in the amount of about 0.0 to less than about 0.3 g/in3.Type: GrantFiled: January 31, 2003Date of Patent: April 4, 2006Assignee: Engelhard CorporationInventor: Yuejin Li
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Patent number: 7018643Abstract: In one embodiment, the present invention relates to a pesticide delivery system, containing a continuous film having a thickness from about 1 ?m to about 1,000 ?m and noncontinuous areas having sizes less than about 100 ?m, the continuous film containing a particulate material wherein at least 90% by weight of the particulate material has a particle size of about 10 microns or less, and a pest control agent at least partially coating the particulate material.Type: GrantFiled: November 22, 2002Date of Patent: March 28, 2006Assignees: Engelhard Corporation, The United States of America as represented by the Secretary of AgricultureInventors: Gary J. Puterka, David Michael Glenn, Dennis G. Sekutowski
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Patent number: 7014700Abstract: Highly reflective interference effect pigments with dark absorption color are obtained by reducing platy titanium dioxide. The present effect pigments may be used in cosmetics, plastics, inks, and coatings including solvent and water borne automotive paint systems.Type: GrantFiled: January 13, 2004Date of Patent: March 21, 2006Assignee: Engelhard CorporationInventors: Carmine V. DeLuca, Jr., William Howard
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Patent number: 7012038Abstract: One aspect of the invention relates to a dehydrogenation catalyst composite containing alumina, chromium oxide, lithium oxide, and sodium oxide. The invention also relates to methods of making the dehydrogenation catalyst composite. Another aspect of the invention relates to method of dehydrogenating a dehydrogenatable hydrocarbon involving contacting the dehydrogenatable hydrocarbon with a dehydrogenation catalyst composite containing alumina, chromium oxide, lithium oxide, and sodium oxide to provide a dehydrogenated hydrocarbon, such as an olefin.Type: GrantFiled: June 12, 2002Date of Patent: March 14, 2006Assignee: Engelhard CorporationInventors: Saeed Alerasool, Harold E. Manning
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Patent number: 6999167Abstract: An apparatus and a method for objectively ascertaining a color match between a selected standard color and the color exhibited by an interference effect pigment during processing thereof and terminating the process upon achieving a match. The invention provides a spectrophotometer attached to a flow cell to monitor the color of a platy effect pigment to monitor pigment color and ascertain completion of the coating reaction process involved in interference pigment production.Type: GrantFiled: February 12, 2001Date of Patent: February 14, 2006Assignee: Engelhard CorporationInventors: James B. Carroll, Jr., Charles Willard
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Patent number: 6992037Abstract: One aspect of the invention relates to catalyst composite containing a metal catalyst and a specifically defined carbon support containing a carbonaceous material. For example, the carbon support may have a total pore surface area of about 800 m2/g or more and about 2,000 m2/g or less where about 20% or less of the total pore surface area is micro pore surface area. Alternatively the carbon support may have a total pore volume of at least about 0.75 cc/g where about 15% or less of the total pore volume is micro pore volume. In yet another aspect of the invention, the carbon support may have a phosphorus content of about 0.75% by weight or less. In still yet another aspect of the invention, a methods of making and using the catalyst composite are disclosed.Type: GrantFiled: September 17, 2001Date of Patent: January 31, 2006Assignee: Engelhard CorporationInventors: Jian Ping Chen, Charles R. Penquite, Deepak S. Thakur