Patents Assigned to ExxonMobil Oil Corporation
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Patent number: 8105680Abstract: A heat sealable, multi-layer film structure for multi-color printing or lamination processes and method for making the same are provided. The multi-layer film structure may include a core layer comprising a thermoplastic polymer and essentially no migratory slip agents; a functional layer on a first side of the core layer, wherein the functional layer is a printable layer or a laminatable layer; and a heat sealable skin layer on a second side of the core layer, the heat sealable skin layer comprising a thermoplastic polymer and a slip system. The multi-layer film structure is prepared without any migratory slip additives. Without migratory slip additives, the multi-layer film structure exhibits excellent machinability on typical packaging equipment.Type: GrantFiled: April 8, 2008Date of Patent: January 31, 2012Assignee: ExxonMobil Oil CorporationInventors: Eric W. Bender, George F. Cretekos
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Patent number: 8080294Abstract: Disclosed in one aspect is a film comprising at least one core layer comprising a blend of at least 20 wt %, by weight of the core layer, of a first linear LLDPE having a molecular weight distribution (Mw/Mn) within the range of from 1.0 to 4.0; and at least 20 wt %, by weight of the core layer, of a second LLDPE—in a certain embodiment a short-chain branched LLDP—having a molecular weight distribution (Mw/Mn) within the range of from 1.0 to 7.0; characterized in that the density of the second LLDPE is greater than the density of the first LLDPE by at least 0.002 g/cm3; and/or the I2 of the second LLDPE is greater than the I2 of the first LLDPE by at least 0.5 dg/min. In certain embodiments, the first and second LLDPEs are produced by a metallocene-catalyzed reaction. In yet another embodiment, the combined molecular weight distribution (Mw/Mn) of the first and second LLDPEs is greater than 4.0.Type: GrantFiled: May 16, 2008Date of Patent: December 20, 2011Assignee: ExxonMobil Oil CorporationInventor: Pang-Chia Lu
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Patent number: 8048532Abstract: Disclosed herein is an improved, metallized polymer film and method for preparing the same. Such films comprise a) at least one treated polymeric skin layer comprising butylene, and b) a metal layer deposited onto at least one surface of this polymeric skin layer. The polymeric skin layer can comprise a propylene-butylene copolymer or an ethylene-propylene-butylene terpolymer, with this copolymer or terpolymer containing from about 4 wt % to about 12 wt % of butylene. The polymeric skin layer is preferably preconditioned by subjecting an outermost surface thereof to plasma treatment which facilitates the deposition thereon of a strongly adhering metal layer which is preferably aluminum. The resulting multi-layer films exhibit metal adhesion bond strength of at least about 100 grams/25 mm. These films will preferably also exhibit a Water Vapor Transmission Rate of from about 0.05 to about 0.2 g/m2/24 hour, and an Oxygen Transmission Rate of from about 5.0 to about 20 cm3/m2/24 hour.Type: GrantFiled: September 15, 2006Date of Patent: November 1, 2011Assignee: ExxonMobil Oil CorporationInventors: Laurence Dominique Urbain, George Forman Cretekos, Christophe J. Maertens
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Patent number: 8043674Abstract: Heat-sealable, multi-layer composite packaging structures that are suitable for packaging and having improved sealing properties and simplified construction as compared to prior art composite film constructions are disclosed. The inventive film structure includes a first substrate, such as paper, bonded such as by extrusion lamination, to a sealable, high-barrier film. This inventive “paper-adhesive-polymer” lamination may replace prior art “paper-adhesive-foil-adhesive” foil-based tandem laminations. An improved or comparable polymer film substrate may replace the “foil-adhesive” layer components of the popular incumbent prior art structure.Type: GrantFiled: September 15, 2006Date of Patent: October 25, 2011Assignee: ExxonMobil Oil CorporationInventors: Richard Alan Rehkugler, Salvatorf J. Pellingra, George F. Cretekos, Benoit Ambroise
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Patent number: 7794849Abstract: A film structure including at least a base layer containing a thermoplastic polymer and at least an outer layer containing a low melting point polymer. Methods of manufacturing the film structure, including the steps of coextruding melts corresponding to the individual layers of the film structure through a die and thereafter: simultaneously biaxially stretching the coextruded film sheet; or sequentially biaxially stretching the coextruded film sheet, wherein the machine-direction orientation (MDO) is performed with a radiant-heated MDO stretcher. An extrusion-coated film structure exhibiting strong bond adhesion, and a method of manufacturing the same are also provided.Type: GrantFiled: April 16, 2009Date of Patent: September 14, 2010Assignee: ExxonMobil Oil CorporationInventors: Pang-Chia Lu, Robert G. Peet, Benoit Ambroise, Linda Maria Van den Bossche, Nancy Nadine Vanderheyden, François Bosch, Jacques Moriau, Lindsay J. Mendes, Syd R. Wright
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Patent number: 7626066Abstract: An oligomerization process in which hydrocarbon feedstocks are contacted with a hydrotreating catalyst in the absence of hydrogen and in the liquid phase. The catalyst is a heterogeneous catalyst selected from supported reduced metals, metals oxides, metal sulfides and combinations thereof. Preferred catalysts include mixed nickel and molybdenum oxides or mixed cobalt and molybdenum oxides. The process also oligomerizes sulfur compounds so that sulfur containing feedstocks can be treated without deactivating the catalysts.Type: GrantFiled: March 9, 2007Date of Patent: December 1, 2009Assignee: ExxonMobil Oil CorporationInventors: Stephen H. Brown, Robert A. Crane, Jr., Robert J. Saxton, William A. Weber
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Patent number: 7537829Abstract: Multi-layer films that are suitable for packaging and having improved sealing properties are disclosed. Some embodiments may also provide a lower minimum sealing temperature. A soft polymer is blended in a core layer and a tie layer comprising the soft polymer and, optionally, another polymer. A sealable layer is provided on the side of the tie layer opposite the core layer. The multi-layer films may be transparent, contain a cavitating agent, or are pigmented to form an opaque film. Also, the multi-layer film may be metallized or coated with a barrier coating.Type: GrantFiled: April 1, 2005Date of Patent: May 26, 2009Assignee: ExxonMobil Oil CorporationInventors: Salvatore J. Pellingra, Jr., Michael J. Bader
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Patent number: 7473439Abstract: Polymeric film structures incorporating at least one coating comprising a cross-linked EVOH copolymer and coating solutions suitable for use on polymeric films comprising at least one EVOH copolymer and at least one cross-linker are provided. The coated films may be single or multi-layered film structures. The films may also be metallized. The coated films exhibit beneficial water vapor and oxygen transmission rates. The coated films may also exhibit the beneficial barrier characteristics under conditions of high humidity. The coated films are suitable for packaging applications. The coating solutions exhibit beneficial stability characteristics over extended time periods.Type: GrantFiled: August 15, 2005Date of Patent: January 6, 2009Assignee: ExxonMobil Oil CorporationInventors: Rhonda E. Rogers Agent, Bruno R. L. Gringoire
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Patent number: 7432405Abstract: A process for the disproportionation of cumene is disclosed which comprises the step of contacting a feed containing cumene, under disproportionation conditions, with a catalyst comprising a molecular sieve, preferably TEA-mordenite. The contacting step disproportionates at least part of the cumene in the feed to provide a disproportionation effluent containing benzene and a mixture of diisopropylbenzene isomers. The effluent is then recovered and contains, prior to any separation step, less 1% of ortho-diisopropylbenzene by weight of the total diisopropylbenzene content of said effluent, less than 1 wt % of n-propylbenzene, less than 5 wt % of triisopropylbenzenes and less than 5 wt % of disproportionation products other than benzene and diisopropylbenzenes.Type: GrantFiled: July 12, 2005Date of Patent: October 7, 2008Assignee: ExxonMobil Oil CorporationInventors: William A. Weber, Walter R. Cade, Francis S. Bryan, Jose Guadalupe Santiesteban
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Patent number: 7393592Abstract: A coextruded, heat-sealable film structure includes a core layer of a thermoplastic polymer having a first side and a second side. A functional layer which is printable, sealable, or can be laminated or is treatable for printing, sealing, or laminating is on the first side of the core layer. A heat-sealable layer is on the second side of the core layer. The heat-sealable layer is composed of a thermoplastic polymer and an amount of a slip system, based upon the entire weight of the heat-sealable layer, sufficient to reduce the coefficient of friction and improve the slip performance of the film structure. The slip system is composed of a silicone gum and at least one antiblocking agent. The film structure exhibits the desirable combination of improved converting performance and excellent machinability performance.Type: GrantFiled: March 25, 2004Date of Patent: July 1, 2008Assignee: ExxonMobil Oil CorporationInventors: Karen A. Sheppard, Robert A. Migliorini
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Patent number: 7371465Abstract: An embossable, multilayer, polyolefin film comprising a core layer comprising a polyolefin and an appearance enhancing agent selected from the group consisting of coloring agents, phosphorescence producing agents, reflective agents, and mixtures thereof, wherein the core layer comprises the interior of the film; and an embossable layer exterior to and on one side of the core layer, the embossable layer comprising an olefin polymer, and being particularly suitable for embossing and subsequently receiving a metal layer thereon.Type: GrantFiled: April 29, 2002Date of Patent: May 13, 2008Assignee: ExxonMobil Oil CorporationInventors: Salvatore J. Pellingra, Robert A. Migliorini
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Patent number: 7294380Abstract: Clear and opaque polymeric film structures for providing clear and opaque labels that are removable, respectively. The film structure includes a core layer and first skin layer, wherein the first skin layer contains a polymeric matrix of a material that allows a label, which has been produced from the film structure and applied onto a container or product, to be removed from the container or product by the solution employed in a process for re-using the container. The first skin layer is co-extruded along with the remainder of the layers of the film structure, or the first skin layer is deposited on the film structure as an emulsion or extrusion coating. The first skin layer can be contacted with a water-based adhesive to affix the label onto a particular product or product container. Labels produced from the film structure exhibit a desirable combination of excellent initial adhesion strength, moisture resistance and delaminatability, as well as excellent removability.Type: GrantFiled: May 27, 2004Date of Patent: November 13, 2007Assignee: ExxonMobil Oil CorporationInventors: Jo Ann H. Squier, Robert E. Touhsaent
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Patent number: 7288304Abstract: A metallized thermoplastic label includes a first skin layer containing a thermoplastic and a first cavitating agent, wherein the first skin layer has a first side and a second side, the first skin layer is cavitated, and the first side of the first skin layer is adapted to be used in contact with a cold glue adhesive. The label further includes a cavitated core layer and a second skin layer that is metallized. The particle size of the cavitating agent in the core layer is selected to achieve a desired appearance, especially luster, of the metal layer.Type: GrantFiled: December 30, 2002Date of Patent: October 30, 2007Assignee: ExxonMobil Oil CorporationInventor: JoAnn H. Squier
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Patent number: 7280881Abstract: A system for integrating a packaging supply chain from a point that a digital contract proof is available through delivery of finished packaging materials to an end user, wherein said system comprises a computer system accessible for interactive communications with users, said computer system comprising a first memory area for storing functionality and data for end user members of the supply chain; a second memory area for storing functionality and data for converter members of the supply chain; and a third memory area for storing functionality and data for other members of the supply chain.Type: GrantFiled: December 22, 2006Date of Patent: October 9, 2007Assignee: ExxonMobil Oil CorporationInventors: Robert J. Eller, Joseph J. Cardillo
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Patent number: 7279061Abstract: Improved metallized films are produced by transferring a protective layer onto a metal layer from the side of the film remote from the metal layer. The transfer preferably takes place in the metallizer shortly after metallization and before the metal layer is exposed to the atmosphere which reduces the tendency of the metal to oxidize leading to a purer metal layer with enhanced barrier properties.Type: GrantFiled: April 6, 2004Date of Patent: October 9, 2007Assignee: ExxonMobil Oil CorporationInventor: Jean-Marc Francois
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Patent number: 7195818Abstract: A sealable multi-layer opaque film. In particular, a sealable multi-layer opaque film that is moisture permeable and water resistant. The sealable multi-layer opaque film is an oriented multilayer film with a core layer comprising an orientation-enhancing polymer, a polypropylene homopolymer and a beta crystal nucleator of polypropylene and at least one sealable skin layer.Type: GrantFiled: May 1, 2002Date of Patent: March 27, 2007Assignee: ExxonMobil Oil CorporationInventors: Dan-Cheng Kong, Michael D. Cleckner
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Patent number: 7108060Abstract: Method and apparatus for fracturing different levels of a completion interval in a well. A workstring lowers a fracturing string which, in turn, is comprised of a base pipe which is blank except for perforated sections spaced along its length. Screen may be provided over said sections to block the flow of sand into the base pipe. An alternate flow path (e.g. shunt tubes) extends along the base pipe and has one or more outlets spaced along its length. A slurry is flowed into the annulus surrounding the fracturing string. As liquid is lost from the slurry, sand from the slurry will form bridges at said perforated sections thereby isolating portions of the annulus. Slurry then flows through the shunts tube(s) and out into the isolated portions to fracture the different levels in the completion interval.Type: GrantFiled: September 11, 2003Date of Patent: September 19, 2006Assignee: ExxonMobil Oil CorporationInventor: Lloyd G. Jones
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Patent number: 7067049Abstract: The present invention relates to formulated lubricant oils derived from a highly paraffinic basestock. The lubricating oils of the present invention achieve the extremely stringent viscosity requirements of SAE “0W” crossgraded engine oils and demonstrate an excellent combination of low-temperature performance and biodegradability not achievable by other formulations derived from other classes of basestocks.Type: GrantFiled: February 4, 2000Date of Patent: June 27, 2006Assignee: Exxonmobil Oil CorporationInventors: David J. Baillargeon, Thomas R. Forbus, Jr., Kenneth R. Graziani, Gretchen R. Hall, Nancy M. Page, Richard F. Socha
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Patent number: 6994291Abstract: An end-board for supporting and handling a core-wound roll of material, such as a roll of polymer film. The end-board includes a support plate having a product face, an outer face, a core support aperture, and a core channel, the core support aperture adapted to support a core plug or a core therein. The product face includes a roll recess for receiving an end of the core-wound roll within the roll recess when the core plug or core is positioned in the core support aperture. A locking collar may be used to selectively engage the support plate in the support plate core channel to prevent the supported core or core plug from passing through the core channel. A pair of handles within the support plate may be used to facilitate end-board manipulation.Type: GrantFiled: December 22, 2003Date of Patent: February 7, 2006Assignee: ExxonMobil Oil CorporationInventors: Sharon J. Kemp, Cheryl L. Wetmore
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Patent number: 6984764Abstract: The present invention provides a process for producing a monoalkylated aromatic compound, particularly ethylbenzene or cumene, in which a polyalkylated aromatic compound is contacted with an alkylatable aromatic compound in the liquid phase and in the presence of a transalkylation catalyst comprising TEA-mordenite having an average crystal size of less than 0.5 micron.Type: GrantFiled: May 4, 1999Date of Patent: January 10, 2006Assignee: ExxonMobil Oil CorporationInventors: Wieslaw J. Roth, Brian J. Ratigan, Dominick N. Mazzone