Abstract: A composition that upon firing, forms a low-temperature clean enamel layer is disclosed. The composition can be applied to a metal substrate to provide a low-temperature cleaning, durable coating for cooking surfaces. Also disclosed are methods of forming enamel layers and corresponding coated substrates. Various ground coats and related methods are also described. Furthermore, various multilayer coatings and structures are disclosed that include an enamel layer and a ground coat layer.
Type:
Grant
Filed:
October 26, 2012
Date of Patent:
July 7, 2015
Assignee:
Ferro Corporation
Inventors:
Albert L. Benford, Jr., Andrew Gorecki, Louis J. Gazo, Charles A. Baldwin
Abstract: The present subject matter provides a transitional layer and related methods, used to increase the transmission or reflection of light between two mediums having different indices of refraction. The transitional layer is disposed between the two mediums and the transmission or reflection of light is increased by the interaction of light with the transitional layer. The transitional layer has light scattering particles dispersed therein, a single-layer gradient index-of-refraction, a multi-layer gradient index-of-refraction, alternating layers of high and low index-of-refraction, or a combination thereof, in order to increase the transmission or reflectance of light between the two mediums.
Type:
Application
Filed:
August 1, 2013
Publication date:
June 25, 2015
Applicant:
FERRO CORPORATION
Inventors:
George E. Sakoske, Enos A. Axtell, III, James D. Walker
Abstract: Various laser marking compositions and related methods are described. The laser marking compositions utilize one or more populations of particles having certain average particle sizes or a range of sizes. Marks or other indicia formed using the compositions and methods exhibit increased contrast, improved substrates bonding, and greater dispersability.
Type:
Application
Filed:
July 25, 2013
Publication date:
May 7, 2015
Applicant:
Ferro Corporation
Inventors:
George E. Sakoske, Joseph E. Sarver, Dennis R. Gilmore, Stephen Rozwood, Sean T. Weir
Abstract: This invention relates to lead free and cadmium free copper-containing glass frits that can be used as pigments to color other glass frits or to impart color to solid substrates such as glass, ceramic or metals, or to impart color to a thermoplastic mass. The compositions comprise silica, alkali metal oxides, alkaline earth metal oxides, tin oxide and copper oxide. The resulting compositions can be used to decorate and protect automotive, beverage, architectural, pharmaceutical and other glass substrates, generally imparting a red color.
Type:
Application
Filed:
November 7, 2014
Publication date:
March 12, 2015
Applicant:
FERRO CORPORATION
Inventors:
Enos A. Axtell, III, George E. Sakoske, Andreas Schulz, Juergen Hanich, Lothar Heck, Dietrich Speer, Martin Baumann
Abstract: A process of transesterifying biobased epoxidized vegetable oils with a dialkyl carbonate produces mixtures of epoxidized fatty acid cyclic glycerin carbonate esters and epoxidized fatty acid alkyl esters.
Type:
Application
Filed:
August 23, 2013
Publication date:
February 26, 2015
Applicant:
Ferro Corporation
Inventors:
John D. Bradshaw, George F. Schaefer, Larry J. Baldwin, Ronald J. Raleigh, JR., Brenda Hollo
Abstract: A composition that upon firing, forms a non-stick enamel layer is disclosed. The composition can be applied to a metal substrate to provide a non-stick, durable coating for cooking surfaces. Also disclosed are methods of forming enamel layers and corresponding coated substrates. Various ground coats and related methods are also described. Furthermore, various multilayer coatings and structures are disclosed that include an enamel layer and a ground coat layer.
Type:
Grant
Filed:
June 18, 2014
Date of Patent:
February 24, 2015
Assignee:
Ferro Corporation
Inventors:
Albert L. Benford, Jr., Andrew Gorecki, Louis J. Gazo, Charles A. Baldwin
Abstract: This invention relates to lead free and cadmium free copper-containing glass fits that can be used as pigments to color other glass fits or to impart color to solid substrates such as glass, ceramic or metals, or to impart color to a thermoplastic mass. The compositions comprise silica, alkali metal oxides, alkaline earth metal oxides, tin oxide and copper oxide. The resulting compositions can be used to decorate and protect automotive, beverage, architectural, pharmaceutical and other glass substrates, generally imparting a red color.
Type:
Grant
Filed:
June 16, 2010
Date of Patent:
February 3, 2015
Assignee:
Ferro Corporation
Inventors:
Enos A. Axtell, III, George E. Sakoske, Andreas Schulz, Juergen Hanich, Lothar Heck, Dietrich Speer, Martin Baumann
Abstract: Various laser marking compositions and related methods are described. The laser marking compositions include a molybdenum metal complex, a tungsten metal complex, or combinations thereof. Marks or other indicia formed on a substrate using the compositions and methods exhibit increased contrast and improved substrate bonding.
Type:
Application
Filed:
March 1, 2013
Publication date:
December 18, 2014
Applicant:
Ferro Corporation
Inventors:
Terry J. Detrie, George E. Sakoske, Stephen Rozwood, Joseph E. Sarver
Abstract: A low VOC medium is described. The medium comprises a low VOC solvent such as propylene carbonate, dimethyl carbonate, or combinations thereof. The low VOC medium also comprises one or more glycol ethers. In addition, the low VOC medium also includes one or more surfactants and/or dispersants. The low VOC medium may also optionally comprise one or more binders. The low VOC medium can be used in preparing coating compositions and pastes that are intended for use in applications that include a firing step.
Abstract: A glass composition comprising B2O3, Na2O, Al2O3, Li2O, TiO2, ZnO, Ta2O5, Nb2O3, BaO, ZrO2 and SiO2, and devoid of lead, bismuth, and vanadium. Pastes comprising the glass composition and devices including seals comprising such pastes are contemplated.
Abstract: A method of sealing at least two inorganic substrates together using an induction energy source comprising applying to at least one of the substrates a paste composition including a glass frit, and an induction coupling additive, bringing at least a second substrate into contact with the paste composition, and subjecting the substrates and paste to induction heating, thereby forming a hermetic seal between the two inorganic substrates.
Type:
Application
Filed:
September 12, 2012
Publication date:
October 9, 2014
Applicant:
FERRO CORPORATION
Inventors:
Srinivasan Sridharan, George E. Sakoske, Chandrashekhar S. Khadilkar, Gregory R. Prinzbach, John J. Maloney
Abstract: An acrylate-based curable printing medium is disclosed. Acrylates, in the form of monomers, dimers, trimers and oligomers, as well as resins, form an interpenetrating polymer network by crosslinking, which is effected by heat, and optionally peroxide curing agents. Formulations can be tailored to achieve desired properties of the cured polymer including film hardness, burnout properties, and adhesion to glass. Such properties are adjusted by manipulating the relative proportions of the acrylic monomers, oligomers and resins that are used as a ceramic medium or vehicle.
Type:
Grant
Filed:
August 18, 2010
Date of Patent:
August 26, 2014
Assignee:
Ferro Corporation
Inventors:
Terry J. Brown, Kimberly Stewart, Thirumalai Duraisamy
Abstract: Hot-melt sealing glass compositions that include one or more glass frits dispersed in a polymeric binder system. The polymeric binder system is a solid at room temperature, but melts at a temperature of from about 35° C. to about 90° C., thereby forming a flowable liquid dispersion that can be applied to a substrate (e.g., a cap wafer and/or a device wafer of a MEMS device) by screen printing. Hot-melt sealing glass compositions according to the invention rapidly re-solidify and adhere to the substrate after being deposited by screen printing. Thus, they do not tend to spread out as much as conventional solvent-based glass frit bonding pastes after screen printing. And, because hot-melt sealing glass compositions according to the invention are not solvent-based systems, they do not need to be force dried after deposition.
Type:
Grant
Filed:
September 10, 2012
Date of Patent:
July 22, 2014
Assignee:
Ferro Corporation
Inventors:
Robert D. Gardner, Keith M. Mason, Srinivasan Sridharan, Aziz S. Shaikh
Abstract: A composition that upon firing, forms a non-stick enamel layer is disclosed. The composition can be applied to a metal substrate to provide a non-stick, durable coating for cooking surfaces. Also disclosed are methods of forming enamel layers and corresponding coated substrates. Various ground coats and related methods are also described. Furthermore, various multilayer coatings and structures are disclosed that include an enamel layer and a ground coat layer.
Type:
Grant
Filed:
April 27, 2010
Date of Patent:
July 15, 2014
Assignee:
Ferro Corporation
Inventors:
Albert L. Benford, Jr., Andrew Gorecki, Louis J. Gazo, Charles A. Baldwin
Abstract: This invention relates to glass and enamel compositions. The glass compositions comprise SiO2, Cs2O, Na2O, ZnO, B2O3, and TiO2, and optionally Bi2O3 and F. The resulting compositions can be used to form an enamel on a substrate, for example, to decorate and/or protect the substrate.
Type:
Grant
Filed:
May 4, 2011
Date of Patent:
July 8, 2014
Assignee:
Ferro Corporation
Inventors:
Sandeep K. Singh, George E. Sakoske, David A. Klimas
Abstract: A low VOC medium is described. The medium comprises a low VOC solvent such as propylene carbonate, dimethyl carbonate, or combinations thereof. The low VOC medium also comprises one or more glycol ethers. In addition, the low VOC medium also includes one or more surfactants and/or dispersants. The low VOC medium may also optionally comprise one or more binders. The low VOC medium can be used in preparing coating compositions and pastes that are intended for use in applications that include a firing step.
Abstract: A silver conductive coating possessing infrared absorbing properties is disclosed. The coating is made from a blend of one or more micron size silver powders and/or flakes together with carbon black, inorganic pigment, glass frit, and powdered selenium or bismuth metal. The foregoing dry ingredients are pasted with an organic vehicle, applied to a substrate, and fired at a temperature of up to 1400° F. The coating absorbs infrared radiation beyond the decomposition of carbon black, thus allowing higher firing temperatures and hence shorter firing times.
Type:
Grant
Filed:
October 21, 2010
Date of Patent:
April 8, 2014
Assignee:
Ferro Corporation
Inventors:
Terry J. Brown, David M. Stotka, William G. Picard, George E. Sakoske
Abstract: Pigment compositions are described that advantageously increase total solar reflectance. Also described are methods of making pigment compositions. The pigment compositions can contain copper oxide; copper antimony oxides, copper bismuth oxides, or combinations thereof; and alkaline earth metal oxides, early-transition metal oxides, post-transition metal oxides, metalloid (semi-metal) oxides, rare-earth metal oxides, or combinations thereof.
Abstract: A method of producing solid composite lipid/drug nanoparticles that includes the steps of: (1) dissolving a lipid and a drug in a suitable organic solvent to form a solution; (2) emulsifying the solution in a liquid to form an emulsion having a discontinuous phase of micelles comprising the organic solvent, the drug and the lipid, and a continuous phase comprising the liquid; and (3) contacting the emulsion with a supercritical fluid under conditions suitable to keep the supercritical fluid in a supercritical state, whereby the supercritical fluid extracts the organic solvent from the micelles, causing them to precipitate as organic-solvent free solid composite lipid/drug nanoparticles suspended or dispersed in the liquid.
Type:
Grant
Filed:
May 21, 2008
Date of Patent:
February 4, 2014
Assignee:
Ferro Corporation
Inventors:
Boris Y. Shekunov, Pratibhash Chattopadhyay, Robert W. Huff
Abstract: Broadband infrared radiation is used to heat and fuse an enamel paste to form an enamel seal between at least two solid substrates such as glass, ceramic or metal.
Type:
Application
Filed:
July 22, 2013
Publication date:
January 30, 2014
Applicant:
FERRO CORPORATION
Inventors:
John J. Maloney, Andrew M. Rohn, JR., Chandrashekhar S. Khadilkar, Srinivasan Sridharan, Robert P. Blonski, George E. Sakoske