Abstract: An aqueous synthetic acid composition is disclosed for use in oil industry activities, the composition comprising: lysine and hydrogen chloride in a molar ratio ranging from 1:3 to 1:12.5, preferably from more than 1:5 to 1:8.5. The composition can also further comprise a metal iodide or iodate an alcohol or derivative thereof. The composition demonstrates advantageous properties over known synthetic acids at temperatures above 90° C. The composition is useful in various oil and gas industry operations. Preferred embodiments of the composition provide substantial advantages in matrix acidizing by increasing the effectiveness of wormholing as compared to conventional mineral acids such as HCl.
Type:
Grant
Filed:
July 28, 2017
Date of Patent:
August 24, 2021
Assignee:
FLUID ENERGY GROUP LTD
Inventors:
Clay Purdy, Alexander David Jamieson, Markus Weissenberger
Abstract: An aqueous caustic composition comprising: a caustic component; an amino acid additive adapted to provide an extended buffering effect to the caustic composition when such is exposed to an acid; and water, wherein the caustic component and the amino acid additive are present in a molar ratio ranging from 15:1 to 5:1. Methods of using such compositions are also disclosed.
Abstract: An aqueous modified acid composition for use in oil industry activities, said composition comprising: an amino acid, an alkanolamine and strong acid wherein the mineral acid:alkanolamine/amino acid are present in a molar ratio of not more than 15:1, preferably not more than 10:1; it can also further comprise a metal iodide or iodate. Said composition demonstrates advantages over known conventional acids and modified acids.
Abstract: An aqueous caustic composition comprising: a caustic component; an additive adapted to provide an extended buffering effect to the caustic composition when such is exposed to an acid; and water. Methods of using such compositions are also disclosed.
Abstract: An aqueous caustic composition comprising: a caustic component; an additive adapted to provide an extended buffering effect to the caustic composition when such is exposed to acid; and water. Methods of using such compositions are also disclosed.
Abstract: An aqueous modified acid composition for industrial activities, said composition comprising: an alkanolamine and strong acid in a molar ratio of not less than 1:15, preferably not less than 1:10; it can also further comprise a metal iodide or iodate. Said composition demonstrates advantages over known conventional acids and modified acids.
Abstract: A synthetic caustic composition for use in oil & gas industry activities, said composition comprising: metal hydroxides; an amino acid; urea; a sodium silicate and water.
Type:
Grant
Filed:
December 7, 2016
Date of Patent:
August 25, 2020
Assignee:
Fluid Energy Group Ltd.
Inventors:
Clay Purdy, Darren Thatcher, Alexander David Jamieson
Abstract: Methods of using an organic acid composition in oil industry activities, said composition comprising: methane sulphonic acid, a metal iodide or iodate, and an alcohol or derivative thereof.
Type:
Grant
Filed:
July 2, 2018
Date of Patent:
March 17, 2020
Assignee:
Fluid Energy Group Ltd.
Inventors:
Clay Purdy, Darren Thatcher, Jon Garner, Bruce Ulmer, Alexander David Jamieson
Abstract: A corrosion inhibition package for use with an aqueous acid composition, said package comprising: a terpene; a cinnamaldehyde or a derivative thereof; at least one amphoteric surfactant; and a solvent. Also disclosed are compositions comprising said corrosion inhibitor package. Preferably, the corrosion inhibition package meets the environmental requirements for classification as yellow according to the Norwegian North Sea offshore drilling regulatory requirements.
Abstract: A synthetic acid composition for use in oil industry activities comprising urea and methanesulphonic acid in a molar ratio of not loss than 1.0:1, a metal iodide or iodate and an alcohol or derivative thereof.
Type:
Grant
Filed:
May 20, 2016
Date of Patent:
June 25, 2019
Assignee:
FLUID ENERGY GROUP LTD.
Inventors:
Clay Purdy, Darren Thatcher, Jon Garner, Bruce Ulmer, Alexander David Jamieson
Abstract: An organic acid composition for use in oil industry activities, said composition comprising: methane sulphonic acid; a metal iodide or iodate; and an alcohol or derivative thereof. The uses include: injection/disposal in wells; squeezes and soaks or bullheads; acid fracturing; acid washes or matrix stimulations; fracturing spearheads (breakdowns); pipeline scale treatments; cement breakdowns or perforation cleaning; pH control; and de-scaling applications.
Type:
Grant
Filed:
May 20, 2016
Date of Patent:
May 7, 2019
Assignee:
FLUID ENERGY GROUP LTD.
Inventors:
Clay Purdy, Darren Thatcher, Jon Garner, Bruce Ulmer, Alexander David Jamieson
Abstract: A synthetic acid composition for use in oil industry activities is disclosed. The composition in a preferred embodiment comprises urea and hydrogen chloride in a molar ratio of not less than 0.1:1; and a metal iodide or iodate. Optionally, a phosphonic acid derivative may be added to the composition.
Type:
Grant
Filed:
September 29, 2015
Date of Patent:
January 29, 2019
Assignee:
FLUID ENERGY GROUP LTD.
Inventors:
Clay Purdy, Darren Thatcher, Jon Garner, Bruce Ulmer
Abstract: Methods of using an organic acid composition in oil industry activities, said composition comprising: methane sulphonic acid, a metal iodide or iodate, and an alcohol or derivative thereof.
Type:
Application
Filed:
July 2, 2018
Publication date:
November 1, 2018
Applicant:
FLUID ENERGY GROUP LTD.
Inventors:
Clay PURDY, Darren THATCHER, Jon GARNER, Bruce ULMER, Alexander David JAMIESON
Abstract: A synthetic acid composition for use in oil industry activities is disclosed. The composition comprises urea and hydrogen chloride in a molar ratio of not less than 0.1:1; a metal iodide or iodate; an alcohol or derivative thereof. Optionally, the composition may include formic acid or a derivative thereof propylene glycol or a derivative thereof, ethylene glycol glycerol or a mixture thereof; cinnamaldehyde or a derivative thereof; and a phosphonic acid derivative.
Type:
Grant
Filed:
May 28, 2015
Date of Patent:
July 31, 2018
Assignee:
FLUID ENERGY GROUP LTD
Inventors:
Clay Purdy, Darren Thatcher, Jon Garner, Bruce Ulmer
Abstract: A synthetic acid composition for use in oil industry activities, said composition comprising: urea and hydrogen chloride in a molar ratio of not less than 0.1:1; and an amino acid, and optionally, a phosphonic acid derivative.
Type:
Application
Filed:
September 29, 2015
Publication date:
November 2, 2017
Applicant:
FLUID ENERGY GROUP LTD.
Inventors:
Clay PURDY, Darren THATCHER, Jon GARNER, Bruce ULMER
Abstract: A synthetic acid composition for use in oil industry activities, said composition comprising: urea and hydrogen chloride in a molar ratio of not less than 0.1:1; and an alcohol or derivative thereof optionally, it may further comprise a phosphonic acid derivative.
Type:
Application
Filed:
September 29, 2015
Publication date:
October 12, 2017
Applicant:
Fluid Energy Group Ltd.
Inventors:
Clay Purdy, Darren Thatcher, John Garner, Bruce Ulmer
Abstract: A synthetic acid composition for use in oil industry activities, said composition comprising: urea and hydrogen chloride in a molar ratio of not less than 0.1:1; and a metal iodide or iodate. Optionally, a phosphonic acid derivative may be added.
Type:
Application
Filed:
September 29, 2015
Publication date:
September 28, 2017
Applicant:
Fluid Energy Group Ltd.
Inventors:
Clay Purdy, Darren Thatcher, Jon Garner, Bruce Ulmer
Abstract: A synthetic acid composition for use in oil industry activities, said composition comprising: urea and hydrogen chloride in a molar ratio of not less than 0.1:1 and formic acid or a derivative thereof.
Type:
Application
Filed:
September 29, 2015
Publication date:
July 27, 2017
Applicant:
Fluid Energy Group Ltd.
Inventors:
Clay PURDY, Darren THATCHER, John GARNER, Bruce ULMER
Abstract: A synthetic acid composition for replacement of hydrochloric acid in industrial activities requiring large amounts of hydrochloric acid, said composition comprising: urea and hydrogen chloride in a molar ratio of not less than 0.1:1; a metal iodide or iodate; an alcohol or derivative thereof. Optionally, formic acid or a derivative thereof; propylene glycol or a derivative thereof, ethylene glycol glycerol or a mixture thereof; cinnamaldehyde or a derivative thereof; and a phosphonic acid derivative can be added to the composition.
Type:
Application
Filed:
May 28, 2015
Publication date:
April 13, 2017
Applicant:
Fluid Energy Group Ltd.
Inventors:
Clay PURDY, Darren THATCHER, Jon GARNER, Bruce ULMER
Abstract: A synthetic acid composition for use in oil industry activities, said composition comprising: urea and methanesulphonic acid in a molar ratio of not less than 0.1:1; a metal iodide or iodate; an alcohol or derivative thereof.
Type:
Application
Filed:
May 20, 2016
Publication date:
December 1, 2016
Applicant:
FLUID ENERGY GROUP LTD.
Inventors:
Clay PURDY, Darren THATCHER, Jon GARNER, Bruce ULMER, Alexander David JAMIESON