Abstract: The invention provides a composite separator and an electrochemical device such as a battery with the composite separator. The composite separator includes at least one metal-organic framework (MOF) composite layer, and at least one porous layer serving a mechanical support for the at least one MOF composite layer. The at least one MOF composite layer includes at least one MOF material defining a plurality of pore channels and at least one polymer. The at least one MOF material is a class of crystalline porous scaffolds constructed from metal clusters with organic ligands and is activated at a temperature for a period of time such that the at least one MOF material includes unsaturated metal centers, open metal sites and/or structural defects that are able to complex with anions in electrolyte.
Type:
Grant
Filed:
March 18, 2020
Date of Patent:
August 1, 2023
Assignees:
FORD CHEER INTERNATIONAL LIMITED, XIONGDI FINE CHEMICAL CO. LTD
Abstract: The invention relates to a method for fabricating a regenerative polysulfide-scavenging layer (RSL). The method includes embedding nanowires or nanocrystals of metal oxides with a membrane of carbon nanotubes (CNTs); and forming the RSL with the embedded nanowires or nanocrystals of the metal oxides and the membrane, so as to enable lithium-sulfur batteries with high energy density and prolonged cycling life. The invention also relates to a lithium-sulfur battery that contains the RSL.
Type:
Grant
Filed:
February 6, 2018
Date of Patent:
April 20, 2021
Assignees:
THE REGENTS OF THE UNIVERSITY OF CALIFORNIA, FORD CHEER INTERNATIONAL LIMITED