Patents Assigned to Grace & Co. -Conn.
  • Publication number: 20240174776
    Abstract: A process of producing a spherical catalyst component for use in producing polyolefin polymers includes dissolving a magnesium halide compound in a solvent to form a homogeneous solution, the solvent comprising an alcohol; and treating the homogeneous solution with a titanium compound in the presence of a surfactant, a supportive electron donor, and an internal electron donor to form a solid catalyst component comprising a magnesium halide compound base incorporating a titanium unit, the supportive electron donor, and the internal electron donor; wherein the catalyst component comprises particles having a substantially spherical shape and a D50 from about 3 ?m to about 150 ?m.
    Type: Application
    Filed: March 8, 2022
    Publication date: May 30, 2024
    Applicant: W.R. Grace & Co.-Conn.
    Inventors: Vladimir P. MARIN, Ahmed HINTOLAY
  • Patent number: 11993672
    Abstract: Disclosed are catalyst compositions having an internal electron donor which includes a 3,6-di-substituted-1,2-phenylene aromatic diester. Ziegler-Natta catalyst compositions containing the present catalyst compositions exhibit very high hydrogen response, high activity, high selectivity and produce propylene-based olefins with high melt flow rate.
    Type: Grant
    Filed: December 16, 2021
    Date of Patent: May 28, 2024
    Assignee: W.R. Grace & Co.-Conn.
    Inventors: Linfeng Chen, Tak W. Leung, Tao Tao, Kuanqiang Gao
  • Publication number: 20240165600
    Abstract: A modified zeolite catalyst composition is disclosed formed from a zeolite, alumina binder, and matrix. The modified zeolite catalyst composition may contain fluorine. Also disclosed, are methods for the preparation of pyridine and/or its alkylpyridine derivatives in high yield utilizing the modified zeolite catalyst composition.
    Type: Application
    Filed: October 20, 2020
    Publication date: May 23, 2024
    Applicant: W.R. Grace & Co.-Conn.
    Inventor: Dorai Ramprasad
  • Publication number: 20240157335
    Abstract: A stationary phase for high-performance liquid chromatography including monofunctional primary silane functionalized silica provides improved separation performance for the preparative or process scale purification of cannabidiol (CBD) and tetrahydro-cannabinol (THC). Silica bonded with monofunctional primary silane(s) provides more efficient separation of these molecules through higher resolution values, reduced peak broadening and lower separation impedance, thus enabling higher purity product or more efficient purification process.
    Type: Application
    Filed: March 9, 2022
    Publication date: May 16, 2024
    Applicant: W.R. Grace & Co.-Conn.
    Inventors: Keling ZHANG, Reno NGUYEN, Simon THOMAS
  • Publication number: 20240150503
    Abstract: A propylene-ethylene copolymer includes propylene as a primary monomer, an ethylene content (ET) of 3.0% to 5% by weight, a melt flow rate of from 20 to 45 g/10 min, a xylene soluble fraction (XS) of from 2.0% to 7.0% by weight, and an XS/ET ratio of less than or equal to 1.51.
    Type: Application
    Filed: December 5, 2023
    Publication date: May 9, 2024
    Applicant: W.R. GRACE & CO.-CONN.
    Inventors: Matthew Fedec, Jan Van Egmond, Manu Rego, John Kaarto, Li-Min Tau
  • Patent number: 11945896
    Abstract: A Ziegler-Natta catalyst composition is disclosed. The catalyst composition includes an internal electron donor with improved polymerization kinetics, a long lifetime, improved stereoselectivity and/or improved hydrogen response.
    Type: Grant
    Filed: September 10, 2020
    Date of Patent: April 2, 2024
    Assignee: W.R. Grace & Co.-CONN.
    Inventors: Joseph Coalter, III, Rose Kent, Adam Marwitz, Ronald Epstein, Michael Elder
  • Patent number: 11905347
    Abstract: Propylene and alpha olefin random copolymers are disclosed that have excellent flow characteristics. For instance, the copolymers can be formulated so as to have a melt flow rate of greater than about 45 g/10 min. While still retaining the above flow characteristics, the copolymer can also be formulated to have greater stiffness, low xylene soluble content, and excellent transparency characteristics especially when combined with one or more clarifying agents.
    Type: Grant
    Filed: June 7, 2019
    Date of Patent: February 20, 2024
    Assignee: W.R. GRACE & CO .- CONN.
    Inventors: Matthew John Fedec, Jan Willem Van Egmond, John Kalevi Kaarto, Amaia Montoya-Goni
  • Publication number: 20240043633
    Abstract: Olefin polymers are produced having a controlled amount of xylene soluble content. For example, polypropylene polymers can be produced having a relatively high xylene soluble content. The polymers are produced using particular external electron donors. The polymers can be produced without using a silicon-containing external electron donor.
    Type: Application
    Filed: November 30, 2021
    Publication date: February 8, 2024
    Applicant: W.R. Grace & Co.-CONN.
    Inventor: Jan W. Van Egmond
  • Patent number: 11891460
    Abstract: An activated solid catalyst component is disclosed formed from a magnesium compound, a titanium compound, an organosilicon compound, a supportive electron donor, and at least one internal electron donor. The solid catalyst component is activated to include titanium and carbon bonds by reaction with an activation agent, such as an aluminum compound. In one embodiment, small amounts of polymer are polymerized with the catalyst component during activation. The activated catalyst component is stable and, when formed, can later be used to produce various polyolefin polymers. The activated catalyst component has controlled reaction kinetics so that the catalyst does not overheat and degrade during initial polymerization.
    Type: Grant
    Filed: May 7, 2020
    Date of Patent: February 6, 2024
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Vladimir Marin
  • Publication number: 20240018346
    Abstract: A polymer composition includes a low ethylene random copolymer that can be used to form a meltspun or spunbond article at high spinning velocities. The polymer composition has a low xylene soluble content, a high crystallinity, or both, while having reduced spin-break at high spinning velocities. The polymer composition also exhibits good fiber tenacity and fabric softness.
    Type: Application
    Filed: December 6, 2021
    Publication date: January 18, 2024
    Applicant: W.R. Grace & Co.-CONN.
    Inventor: John Kaarto
  • Patent number: 11873355
    Abstract: Propylene-ethylene copolymer compositions and production methods are provided. The copolymer compositions can be particularly advantageous for use in hot fill packaging of foodstuffs. The propylene-ethylene copolymers can be produced using a Ziegler-Natta catalyst and an alkoxysilane electron donor. The compositions can have propylene as a primary monomer with an ethylene content ranging from 2.0 to 6.0 percent by weight with a xylene soluble content of less than 7.0 percent by weight.
    Type: Grant
    Filed: June 7, 2019
    Date of Patent: January 16, 2024
    Assignee: W.R. Grace & Co.-Conn.
    Inventors: Matthew John Fedec, Jan Willem Van Egmond, Manu Rego, John Kalevi Kaarto, Li-Min Tau
  • Publication number: 20230357552
    Abstract: Polymer compositions are disclosed that can be used to produce different types of molded articles, such as extruded piping structures. The polymer composition contains an oxidative stabilizing package. The oxidative stabilizing package contains at least one antioxidant, a nucleating agent, and an acid scavenger. The nucleating agent is a phosphate ester or a dicarboxylate metal salt. The stabilizing package of the present disclosure dramatically improves oxidation induction time.
    Type: Application
    Filed: August 31, 2021
    Publication date: November 9, 2023
    Applicant: W. R. Grace & Co.-Conn.
    Inventor: Zhiru MA
  • Publication number: 20230331882
    Abstract: Olefin polymers are produced having an ultra-high melt flow rate. The olefin polymers can be used to produce meltblown fibers and meltblown webs, which can then be incorporated into protective apparel. The polyolefin polymer is produced using a Ziegler-Natta catalyst and without having to use peroxides in order to obtain the high melt flow rate.
    Type: Application
    Filed: September 9, 2021
    Publication date: October 19, 2023
    Applicant: W. R. Grace & Co.-Conn.
    Inventor: Jan Van Egmond
  • Publication number: 20230312782
    Abstract: Phthalate-free polypropylene homopolymers and compositions incorporating the homopolymers are described. The phthalate-free polypropylene homopolymers exhibit high molecular weight as well as low XS content. Composition incorporating the phthalate-free polypropylene homopolymer can have relatively high stiffness properties. In addition, the polypropylene compositions can have good melt flow characteristics. Phthalate-free compositions including the homopolymers can be advantageously utilized in forming containers and other articles in food contacting, medical, and personal care applications.
    Type: Application
    Filed: June 29, 2021
    Publication date: October 5, 2023
    Applicant: W.R. Grace & Co.-Conn.
    Inventor: Zhiru MA
  • Publication number: 20230271163
    Abstract: A process for catalytic cracking of an iron-contaminated fluid catalytic cracking (FCC) feedstock. The process may include combining a FCC catalyst, a slurry containing a magnesium compound, and an iron-contaminated FCC feedstock during a FCC process under fluid catalytic cracking conditions, thereby generating an equilibrium FCC catalyst with reduced iron poisoning. The slurry containing the magnesium compound may not contain a calcium compound.
    Type: Application
    Filed: July 7, 2021
    Publication date: August 31, 2023
    Applicant: W. R. Grace & Co.-Conn.
    Inventors: Shankhamala Kundu, Ruizhong Hu, Wu-Cheng Cheng, Michael Ziebarth
  • Publication number: 20230257497
    Abstract: Propylene and butene random copolymers are disclosed that have excellent stiffness properties, low xylene soluble content, and excellent transparency characteristics especially when combined with one or more nucleating agents. The propylene-butene copolymers can be made with different melt flow characteristics making them well suited for use in injection molding, blow molding and thermoforming applications.
    Type: Application
    Filed: July 8, 2021
    Publication date: August 17, 2023
    Applicant: W. R. Grace & Co.-Conn.
    Inventors: Zhiru MA, John K. Kaarto
  • Publication number: 20230257569
    Abstract: Propylene and butene random copolymers are disclosed that have excellent stiffness properties and excellent transparency characteristics especially when combined with one or more nucleating agents. The propylene-butene copolymers can be made with different melt flow characteristics making them well suited for use in injection molding, blow molding and thermoforming applications.
    Type: Application
    Filed: July 7, 2021
    Publication date: August 17, 2023
    Applicant: W.R. Grace & Co.-Conn.
    Inventors: Jing Zhong, John K. Kaarto, Zhiru Ma
  • Patent number: 11691124
    Abstract: A process for preparing a catalyst comprises coating substantial internal surfaces of porous inorganic powders with titanium oxide to form titanium oxide-coated inorganic powders. After the coating, an extrudate comprising the titanium oxide-coated inorganic powders is formed and calcined to form a catalyst support. Then, the catalyst support is impregnated with a solution containing one or more salts of metal selected from the group consisting of molybdenum, cobalt, and nickel.
    Type: Grant
    Filed: June 29, 2021
    Date of Patent: July 4, 2023
    Assignee: W.R. GRACE & CO.-CONN
    Inventors: Stephen R Schmidt, Cristian Libanati
  • Publication number: 20230147998
    Abstract: The present invention relates to a process for making 1,4-butanediol. The process may include reacting a solution comprising 1,4-butynediol with hydrogen in a presence of an effective amount of a catalyst. The catalyst may include copper.
    Type: Application
    Filed: March 24, 2021
    Publication date: May 11, 2023
    Applicant: W. R. Grace & Co.-Conn.
    Inventor: Stephen Schmidt
  • Patent number: 11643481
    Abstract: The present invention provides polymer compositions having improved corrosivity, color stability and clarity. Also disclosed is a process of preparing the polymers. The process may comprise incorporating into the polymer an acid neutralizing amount of an amorphous aluminum silicate. The amorphous aluminum silicate may be present in the polymer in an amount such that the polymer composition having a Corrosivity Index of less than 6. A refractive index of the amorphous aluminum silicate may be the same or substantially the same as a refractive index of the polymer.
    Type: Grant
    Filed: February 1, 2019
    Date of Patent: May 9, 2023
    Assignee: W.R. Grace & Co.-Conn.
    Inventors: Amaia Montoya-Goni, John Kaarto, Michelle Ni Paine, Jose Manuel Rego, Feng Gu, Demetrius Michos, James Neil Pryor