Abstract: A method of bonding two substrates at least one of which is a rubbery polymeric material having carbon-carbon double bonds on the polymer backbone, the method comprising:
a) applying an aqueous polyurethane dispersion adhesive composition to at least one of the substrates, the adhesive compostion further comprising an epoxy resin;
b) allowing the composition to dry; and then
c) joining the substrates with heating to activate the adhesive. The substrates are suitably footwear materials such as a molded rubber outer sole which has been first primed with a chlorinating primer, and a foam midsole of a material such as a lightly crosslinked ethylene vinyl acetate. The process results in bonded assemblies having improved humidity resistance.
Type:
Grant
Filed:
December 8, 1998
Date of Patent:
September 11, 2001
Assignee:
H. B. Fuller Licensing & Financing, Inc.
Inventors:
Yuduo Zhu, Robert J. Duff, Peter Gottschalk, Brian L. Marty
Abstract: The present invention relates to water-based pressure sensitive adhesives comprising at least one water-based polymer and at least one aminoplast resins such as melamine-formaldehyde resins, urea-formaldehyde resins, alkylated melamine-formaldehyde resins and combinations thereof. More particularly, the invention relates to water-based pressure sensitive adhesives comprising the reaction product of aqueous polymer dispersions and water dispersible melamine-formaldehyde resins. The pressure sensitive adhesives are characterized as having enhanced bonding characteristics including loop tack, peel strength, and shear strength making them particularly useful for the manufacture of dry-bonded laminates, tapes, labels, medical patches and devices, flexible packages, furnace ducts, exterior insulating finish system and the like.
Abstract: The present invention relates to a water based laminating adhesive composition and a method of using thereof. More particularly, the invention relates to a water-based laminating adhesive comprising: a first component comprising at least one aqueous vinyl polymer dispersion (A) comprising the reaction product of i) at least one ethylenically unsaturated monomer; ii) at least one free radical initiator; and iii) optionally, at least one ethylenically unsaturated oligomer; and b) a second component comprising at least one water dispersible polyfunctional aziridine crosslinking agent (B). The adhesive optionally comprises at least one aqueous polyurethane polymer dispersion (C). Improved bonded properties of dry laminated flexible film substrates such as polyolefin, polyester and polyamide, as well as cellophane, metals or paper are obtained.
Type:
Grant
Filed:
June 4, 1998
Date of Patent:
June 19, 2001
Assignee:
H. B. Fuller Licensing & Financing, Inc.
Inventors:
George A. Papsin, Thomas E. Rolando, Peter A. Voss
Abstract: The present invention relates to a flame retardant hot melt composition comprising from about 10% to about 60% by weight of the adhesive of at least one copolymer of ethylene, from about 10% to about 70% by weight of the adhesive of a flame retarding hydrated inorganic compound and from about 5% to about 35% by weight of at least one wax component.
Type:
Grant
Filed:
November 30, 1998
Date of Patent:
May 29, 2001
Assignee:
H. B. Fuller Licensing & Financing, Inc.
Abstract: This invention relates to a hot melt adhesive composition in pellet form. The hot melt adhesive composition is pressure sensitive, having a storage modulus, G′, at 25° C., of less than about 5×106 dynes/cm2. The pellets are coated with a pelletizing aid on the surface at a concentration preferably ranging from about 1 wt-% to about 30 wt-%. The pelletizing aid is a hot melt adhesive component or a material which does not substantially adversely affect the adhesive properties.
Type:
Grant
Filed:
May 31, 2000
Date of Patent:
May 29, 2001
Assignee:
H. B. Fuller Licensing & Financing Inc.
Inventors:
Janelle C. Cameron, Carolyn A. Fischer, Nicholas C. Lehman, Jeffrey S. Lindquist, Christopher E. Olson, Steve A. Fox
Abstract: The present invention relates to an aqueous laminating adhesive composition and a method of using thereof. More particularly, the invention relates to an aqueous laminating adhesive composition comprising at least one aqueous polyurethane polymer dispersion (A), at least one aqueous non-polyurethane polymer dispersion (B) prepared by free radical polymerization, and at least one water dispersible polyfunctional crosslinking agent (C). Improved bonded properties of dry laminated flexible film substrates such as polyolefin, polyester and polyamide, as well as cellophane, metals or paper are obtained.
Type:
Grant
Filed:
June 4, 1998
Date of Patent:
May 22, 2001
Assignee:
H. B. Fuller Licensing & Financing, Inc.
Abstract: Printing rollers and sleeves for printing rollers can be provided with a high quality top coat composition which can improve various properties such as solvent resistance, cut resistance, and thermal stability (with respect to dimensional stability and hardness stability), and reduce manufacturing time and costs. A polyurethane top coat composition is used with filler present in an amount of from about 15-70% by weight of the coating. The coatings may also include a low density, high hardness foam underlayer which can be applied without a molding operation.
Abstract: The present invention is a cold seal composition having certain rheological properties. The composition comprises from about 10 wt-% to 100 wt-% of at least one homogeneous ethylene/&agr;-olefin interpolymers. The novel adhesive compositions of the present invention may be coated onto a variety of substrates, resist blocking upon being supplied as a roll-good, and exhibit a wide range of bond strengths, amenable to a variety of cold seal bonding applications.
Type:
Grant
Filed:
November 25, 1998
Date of Patent:
April 24, 2001
Assignees:
H. B. Fuller Licensing & Financing, Inc., The Dow Chemical Company
Inventors:
John P. Baetzold, Robert G. Polance, Michelle M. Chanak
Abstract: Reactive hot melt polyurethane adhesives are useful in the graphic arts area, and in particular, for bookbinding applications such as casemaking, casing-in, gluing-off or thread-securing, facing, slip cases, lining-up, tightbacking, and bonding sides and joints; and for puzzle and gameboard lamination.
Type:
Grant
Filed:
December 18, 1997
Date of Patent:
March 27, 2001
Assignee:
H. B. Fuller Licensing & Financing, Inc.
Inventors:
Kang Yang, David B. Malcolm, Michelle B. Acquaye, Kevin J. Reid, John M. Zimmel
Abstract: The present invention relates to a hot melt adhesive composition useful for articles such as plasters, bandages and tapes which are adhesively adhered to skin. The adhesive may be coated continuously and preferably, discontinuously onto a substrate. More preferably, the hot melt adhesive composition is pattern-coated. The adhesive is permanently adhered to at least one substrate of the article and removably or releasably attachable to skin. The adhesive advantageously does not cause skin irritation nor transfers adhesive to the skin upon removal.
Abstract: Described is a filter and a method for preparing the filter that includes a porous filter media that is bonded to an end cap using a two-part, isocyanate-based adhesive. The adhesive is free of inorganic pigments and fillers and is the reaction product of at least one polymeric polyol component and at least one polyisocyanate component. The polyol component includes a high MW triol having sufficiently different intrinsic reaction rates to generate phase separation during curing. The components react and cure to form a product having an L* white value greater than about 60.
Type:
Grant
Filed:
August 11, 1999
Date of Patent:
February 27, 2001
Assignee:
H. B. Fuller Licensing & Financing, Inc.
Abstract: The present invention relates to a high temperature resistant coating composition and a method of using thereof. More particularly, the invention relates to a coating composition comprising a resin containing functional hydroxyl groups (A), a polyfunctional epoxy resin (B), and an anhydride compound.(C).
Abstract: The invention is a disposable article comprising a discontinuous coating of a hot melt PSA permanently adhered to at least one substrate wherein the adhesive has a shear adhesion failure temperature of greater than about 79° C. (175° F.). Preferably, the adhesive is pattern coated directly onto a polyolefin film for use in a variety of articles including adhesive bandages, tape and feminine napkins.
Type:
Grant
Filed:
June 17, 1998
Date of Patent:
January 30, 2001
Assignee:
H. B. Fuller Licensing & Financing, Inc.
Abstract: A hot melt pressure sensitive adhesive comprising a) from about 15% to about 40% by weight of a block copolymer having a coupling efficiency of less than about 75%; b) from about 20% to about 50% by weight of a tackifying resin selected from the group consisting of those tackifying resins having a softening point of less than about 100° C.; c) from about 30% to about 50% by weight of a plasticizing oil; and d) up to about 15% of a compatible polymer wherein the total polymer content does not exceed 40% by weight of the adhesive wherein the hot melt pressure sensitive adhesive fails cohesively during use.
Type:
Grant
Filed:
June 12, 1997
Date of Patent:
January 9, 2001
Assignee:
H. B. Fuller Licensing & Financing, Inc.
Abstract: The present invention is a hot melt pressure sensitive adhesive comprising a block copolymer structure having an A--B--A backbone block copolymer having B or C blocks attached to the backbone, wherein the A--B--A block backbone is saturated and the B or C block is of the same composition or of a different composition than the midblock of the backbone.
Abstract: This invention relates to a non-contact coating method for producing a continuous coating and articles constructed therefrom. This invention further relates to a method for producing a textile material with a moisture-impermeable barrier layer and to a method for producing a moisture-absorbing article of hygiene which has such a barrier layer. This invention particularly relates to a textile material and hygienic disposable articles comprising a body fluid impermeable barrier layer which can be produced from a non-contact coating method. Preferably, the thermoplastic composition used for producing the barrier layer exhibits certain rheological characteristics and comprises at least one homogeneous linear or substantially linear interpolymer of ethylene with at least one C.sub.3 -C.sub.20 alpha-olefin, further characterized by each said interpolymer having a polydispersity less than about 2.5.
Type:
Grant
Filed:
August 29, 1996
Date of Patent:
September 19, 2000
Assignee:
H. B. Fuller Licensing & Financing, Inc.
Inventors:
Harald Werenicz, Thomas Wittkopf, Gerhard Voss, Peter Remmers, Mark G. Katsaros, Robert G. Polance, II, Mark S. Kroll, Wendy Hoenig, Selim Yalvac, Kalyan Sehanobish, Teresa Karjala, Deepak Parikh, David C. Kelley
Abstract: This invention relates to a hot melt adhesive composition in pellet form. The hot melt adhesive composition is pressure sensitive, having a storage modulus, G', at 25.degree. C., of less than about 5.times.10.sup.6 dynes/cm.sup.2. The pellets are coated with a pelletizing aid on the surface at a concentration preferably ranging from about 1 wt-% to about 30 wt-%. The pelletizing aid is a hot melt adhesive component or a material which does not substantially adversely affect the adhesive properties. The pellets are free-flowing and have a substantially tack-free surface.
Type:
Grant
Filed:
October 8, 1998
Date of Patent:
September 19, 2000
Assignee:
H. B. Fuller Licensing & Financing Inc.
Inventors:
Janelle C. Cameron, Carolyn A. Fischer, Nicholas C. Lehman, Jeffrey S. Lindquist, Christopher E. Olson, Steve A. Fox
Abstract: The present invention discloses aqueous paint compositions having enhanced adhesion characteristics. The compositions contain at least one water-soluble and/or water-dispersible polyether amide comprising the reaction product of polyoxyalkylene diamines and polycarboxylic acids. The dried compositions have improved adhesion characteristics making them particularly useful protective and/or decorative coatings on substrates including wood, metal, concrete, and plastic.
Type:
Grant
Filed:
August 25, 1999
Date of Patent:
September 5, 2000
Assignee:
H.B. Fuller Licensing & Financing, Inc.
Inventors:
Virginia A. Paulson, Keith W. Wiitala, Michael J. Dochniak
Abstract: A pumpable, thermoplastic desiccated mastic capable of desiccating a sealed insulating glass unit. The disclosed compositions comprise a defined resin component and a desiccant/adsorbent component comprising at least 20% by weight of the composition of a desiccant or moisture and volatile organic chemical adsorbing material. The said desiccant/adsorbent component being present in an amount less than the level which will cause the composition when tested as set forth in ASTM D-1238, Procedure B using a 1100 gram load and an 8 gram sample at 190.degree. C. to provide a melt flow time for a piston travel of 2.54 cm(1 inch) of more than 60 seconds.
Abstract: Disclosed are hot melt adhesives comprising at least one first homogeneous linear etylene polymer having a particular density and melt viscosity at 350.degree.F. (177.degree.C.), and an optional wax and tackifier. In particular, disclosed is a hot melt adhesive characterized by: a) at least one homogeneous linear or substantially linear interpolymer of ethylene with at least ibe C.sub.2 --C.sub.20 .alpha.-olefin interpolymer having a density from 0.850 g/cm.sup.3 to 0.895 g/cm.sup.3 ; and b) optionally at least one tackifying resin; and c) optionally at least one wax wherein the hot melt adhesive has a viscosity of less than about 5000 cPs (50 grams/cm.second) at 150.degree.C. Preferred hot melt adhesives for use in adhering cardboard or paperboard are disclosed, as well as the resultant adhered products. Also disclosed is a dual reactor process for the preparation of the inventive hot melt adhesives.
Type:
Grant
Filed:
January 8, 1998
Date of Patent:
August 22, 2000
Assignees:
The Dow Chemical Company, H.B. Fuller Licensing & Financing Inc.
Inventors:
Robert A. Dubois, Cynthia L. Rickey, Steven W. Albrecht, Beth M. Eichler, Thomas F. Kauffman, Maynard Lawrence, Thomas H. Quinn