Abstract: This invention provides an improved method for recovering an organic acid as a salt from various process streams by addition of a crystallizing base to a concentrated solution of neutralized organic acid. The addition of such a base causes crystallization of the salt. This process provides more efficient recovery of organic acid salt from a fermentation process stream than traditional crystallization and it may be used essentially as a one step purification process. The improved method is particularly applicable to the recovery of trisodium or tripotassium citrate from process streams produced in the fermentation and recovery of citric acid, with the addition of a crystallizing base such as sodium hydroxide, sodium carbonate, potassium hydroxide, or ammonia. The resulting product may be combined with an anticaking agent and/or dried to provide a particularly free flowing product.
Type:
Grant
Filed:
May 27, 1994
Date of Patent:
September 12, 1995
Assignee:
Haarmann & Reimer Corp.
Inventors:
Steven W. Felman, Chetna Patel, Bhalchandra H. Patwardhan, David J. Solow
Abstract: The invention discloses an antimicrobial composition composed of a hypothiocyanate generating system adjusted to a pH between about 1.5 and about 5 with a di or tricarboxylic acid. This composition provides synergistically improved antimicrobial action. With the addition of the organic acid, the antimicrobial composition provides effective cidal activity against Gram negative microorganisms in 20 minutes or less. The composition is particularly effective against Salmonella and may be used to provide greater than 6 logs reduction in viable cell count.
Abstract: Disclosed are 1- and 2-mono esters of citric acid and methods for preparing them in the pure form. These novel compounds are useful as surfactants.
Abstract: Disclosed is an improved method for preparing a particulate citric acid material. The method involves spray granulating citric acid from its partially purified fermentation broth to form granules which are freer flowing and less inclined to fracture than is citric acid prepared by crystallization techniques which properties render this material suitable for handling in bulk.
Type:
Grant
Filed:
October 5, 1990
Date of Patent:
September 3, 1991
Assignee:
Haarmann & Reimer Corp.
Inventors:
Helmut A. Mothes, Bhalchandra H. Patwardhan, Theo G. Schroeder, David J. Solow
Abstract: The invention discloses an antimicrobial composition composed of an antimicrobial polypeptide and a hypothiocyanate component. Synergistic activity is seen when the composition is applied at between about 30 and 40 degrees Centigrade at a pH between about 3 and about 5. The composition is useful against gram negative bacteria such as Salmonella. A preferred composition is nisin, lactoperoxidase, thiocyanate and hydrogen peroxide. Such a composition is capable of reducing the viable cell count of Salmonella by greater than 6 logs in 10 to 20 minutes.
Type:
Grant
Filed:
June 13, 1990
Date of Patent:
August 27, 1991
Assignee:
Haarmann & Reimer Corp.
Inventors:
Nancy L. Bycroft, Graham S. Byng, Stephen R. Good
Abstract: Alkali metal citrates are prepared by the addition of an alkaline alkali metal base or salt to citric acid solutions and recovered in solid form by the addition of a C.sub.1 to C.sub.5 alcohol to the solution to cause precipitation.
Abstract: Disclosed is a composition comprising a mixture of acylated diesters of dl-malic acid corresponding to the formula: ##STR1## where P is palmityl and S is stearyl.
Type:
Grant
Filed:
December 14, 1989
Date of Patent:
May 14, 1991
Assignee:
Haarmann & Reimer Corp.
Inventors:
Donald F. Hershberger, Richard A. Plunkett
Abstract: Disclosed is a method for inhibiting the contamination of processed meat products by pathogenic or spoilage microorganisms which method involves treating the surface of the meat product with a lanthionine bacteriocin.
Type:
Grant
Filed:
April 23, 1990
Date of Patent:
May 14, 1991
Assignee:
Haarmann & Reimer Corp.
Inventors:
Mark W. Collison, Terry F. Farver, Christine A. McDonald, Paula J. Herald, Daniel J. Monticello