Patents Assigned to Hach Company
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Patent number: 11169112Abstract: An embodiment provides a method for measuring pH in an aqueous sample with a frit-less electrode, including: introducing an aqueous sample into a measurement device comprising at least three electrodes, wherein at least one electrode of the at least three electrodes comprises a ground rod electrode, wherein at least one electrode of the at least three electrodes comprises a first measurement electrode, and wherein at least one electrode of the at least three electrodes comprises a second measurement electrode; measuring a first electrical potential between the first measurement electrode and the ground rod electrode in the aqueous sample; measuring a second electrical potential between the second measurement electrode and the ground rod electrode in the aqueous sample; and identifying a pH of the aqueous sample based upon a difference between the first electrical potential and the second electrical potential. Other aspects are described and claimed.Type: GrantFiled: May 31, 2019Date of Patent: November 9, 2021Assignee: HACH COMPANYInventors: Vishnu Rajasekharan, David L. Rick
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Patent number: 11093777Abstract: One embodiment provides a method for capturing information from a measuring instrument, including: capturing, using an image capture device, an image of information displayed on the measuring instrument; analyzing, using a processor, the information; detecting, based on the analyzing, a plurality of elements within the information; wherein the plurality of elements comprise: identification data associated with the measuring instrument and measurement data, the identification data being coded within a tag element; wherein the tag element is at least one of a quick response code, a two dimensional barcode, a barcode, and a service identification tag; the identification data comprising data relating to at least one of: unit type, notation type, device type, device identification, device location, device vendor, device manufacturer, and current user; extracting, using a processor, the plurality of elements from the image; and storing, in a storage device, the plurality of elements in a formatted file.Type: GrantFiled: October 26, 2015Date of Patent: August 17, 2021Assignee: HACH COMPANYInventors: Brian Alan Harmon, Theo Grover Tillson Barker
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Patent number: 11035798Abstract: An embodiment provides a method for measuring amines in a solution, including: preparing an indicator-metal complex, wherein the indicator-metal complex comprises an indicator and a metal; introducing the indicator-metal complex to a solution, wherein the solution contains an amount of amine, wherein the amine activates the indicator-metal complex causing a change in fluorescence intensity of the indicator-metal complex; and measuring the amount of amine in the solution by measuring the change in fluorescence intensity of the indicator-metal complex.Type: GrantFiled: July 15, 2019Date of Patent: June 15, 2021Assignee: HACH COMPANYInventors: Darren Kent MacFarland, Rachel Nicole Seals
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Patent number: 11029280Abstract: An embodiment provides a method for determining the alkalinity of an aqueous sample using an alkalinity sensor, including: monitoring the pH of an aqueous sample using a pH sensor in a sample cell, the pH sensor including a pH sensor electrode made of boron-doped diamond; generating hydronium ions, using a hydronium generator, in the aqueous sample in the sample cell, the hydronium generator including a hydronium-generating electrode; changing the pH of the aqueous sample by causing the hydronium generator to generate an amount of hydronium ions in the aqueous sample; quantifying and converting a current or charge to the number of hydronium ions produced to an end point of the electrochemical titration, the end point correlating to the alkalinity of a sample; and analyzing the alkalinity of the aqueous sample based on the generated amount of hydronium ions and the resulting change in pH monitored by the pH sensor.Type: GrantFiled: June 22, 2017Date of Patent: June 8, 2021Assignee: HACH COMPANYInventors: Dan Kroll, Corey Salzer
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Patent number: 10890574Abstract: An embodiment provides a method for measuring a concentration of lead(0) in an aqueous sample, including: introducing an aqueous sample to a reaction vessel; adding a copper(II) acetate material to the aqueous sample in the reaction vessel; chelating unreacted copper(II) material by introduction of an organosulfur compound to the aqueous sample in the reaction vessel; adding a colorimetric indicator to the aqueous sample in the reaction vessel; and measuring a concentration of lead(II) in the aqueous sample by measuring a colorimetric change of the aqueous sample caused by a reaction of lead(II) within the aqueous sample with the colorimetric indicator. Other aspects are described and claimed.Type: GrantFiled: November 5, 2018Date of Patent: January 12, 2021Assignee: HACH COMPANYInventor: Angella Nicholle Greenawalt
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Patent number: 10823672Abstract: Various turbidimeters are described that can detect light directly in a substantially circular, e.g., encompassing, manner such that an increased amount of scattered light from a sample vial may be detected by a light detector, e.g., a photodiode or photodiode array. In an embodiment, a substantially circular photodiode array is provided to directly detect scattered light in an arc about the sample vial. In other embodiments, light guides are provided in an arc element that guides light to a detector or detectors. Other aspects are described and claimed.Type: GrantFiled: November 21, 2019Date of Patent: November 3, 2020Assignee: HACH COMPANYInventors: Richard Edward Leggett, Wayne Boris Perdue, Andreas Mitreiter
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Patent number: 10801990Abstract: An embodiment provides a method for compensating for inteferants in measurement of alkalinity in a reagent-less system, including: introducing an aqueous sample into a measurement device comprising one or more series of electrodes; applying an electrical signal to the aqueous sample using the one or more series of electrodes, wherein the electrical signal is selected from the group consisting of: current and voltage; identifying, during application of the electrical signal, that the electrical signal reaches an oxidation threshold and measuring, prior to reaching the oxidation threshold, a first electrical response to the electrical signal, the first electrical response attributable to interferants in the aqueous sample; identifying, during application of the electrical signal, that the electrical signal reaches an endpoint and measuring, from the oxidation threshold to the endpoint, a second electrical response to the electrical signal; and measuring an alkalinity of the aqueous sample based upon a differencType: GrantFiled: April 17, 2018Date of Patent: October 13, 2020Assignee: HACH COMPANYInventors: Vishnu Vardhanan Rajasekharan, Corey Alan Salzer
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Patent number: 10794882Abstract: An embodiment provides a method for measuring fluoride concentration in an aqueous solution, including: preparing a polyethylene glycol (PEG) monomethyl ether to produce an ester; reacting the ester in the presence of ammoniated tetrahydrofuran to produce an amino polyethylene glycol; placing, in a solution comprising a benzaldehyde species with a phenol functional group and a carboxylic acid functional group, a 2,3,3-trimethylindolenine derivative to produce a hemicyanine with a phenol functional group and a carboxylic acid functional group; combining, in a polar aprotic solvent, the hemicyanine with the phenol functional group and carboxylic acid functional group with a 1,1-carbonyldiimidazole (CDI) and adding the amino-PEG to produce a hemicyanine-PEG; and creating a fluoride sensitive hemicyanine species by reacting the hemicyanine-PEG that contains a phenol functional group with a SiR3 species. Other embodiments are described and claimed.Type: GrantFiled: April 12, 2018Date of Patent: October 6, 2020Assignee: HACH COMPANYInventors: Darren Kent MacFarland, Angella Nicholle Greenawalt
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Patent number: 10794883Abstract: An embodiment provides a method for measuring aluminum concentration in an aqueous sample, including: preparing a chromeazurol S indicator solution; placing the chromeazurol S indicator solution in a sample containing aluminum, wherein the placing causes the chromeazurol S to chelate aluminum within the sample creating a colored complex; and measuring, using colorimetric techniques, a concentration of aluminum within the sample, wherein the measuring comprises measuring an absorbance at a wavelength for the colored complex. Other embodiments are described and claimed.Type: GrantFiled: February 15, 2019Date of Patent: October 6, 2020Assignee: Hach CompanyInventors: Melanie Ann Roth, Angella NIcholle Greenawalt
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Patent number: 10724984Abstract: An embodiment provides a method for oxidizing organic carbon, including: introducing, in a reaction chamber of a total organic carbon analyzer, a fluid sample comprising organic carbon, wherein the reaction chamber includes an electrochemical cell and wherein the electrochemical cell comprises an SP3 substituted solid carbon electrode doped with a conductivity elevating composition; applying, using a generator, a positive potential to the SP3 substituted carbon electrode, the positive potential being sufficient to oxidize organics in the fluid sample to produce carbonate and partially oxidized organics; introducing, in the reaction chamber, at least one acid reagent comprising a metallic catalyst, prior to or substantially simultaneously during the application of the positive potential to the SP3 substituted carbon electrode, that converts the carbonate and the partially oxidized species to carbon dioxide; and detecting, using at least one detector, the carbon dioxide produced by the oxidation.Type: GrantFiled: July 29, 2017Date of Patent: July 28, 2020Assignee: HACH COMPANYInventors: Seamus O'Mahony, Vishnu Vardhanan Rajasekharan
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Patent number: 10718861Abstract: A method for constructing a frequency profile of an emitted signal suitable for use in a non-contact ranging system with multi-scale spectral analysis includes determining N stepped frequency chirps, wherein each frequency chirp of the N stepped frequency chirps has a linear FM modulation of predetermined bandwidth and slope, and wherein a starting frequency for each of the plurality of stepped frequency chirps is chosen so that a non-linear step profile is created which extends over a predetermined total bandwidth, sorting the plurality of N stepped frequency chirps into P sub-sequences, where P is equal to the product of decimation factors to be used in the multi-scale spectral analysis, and ordering the P sub-sequences end to end in time.Type: GrantFiled: September 21, 2017Date of Patent: July 21, 2020Assignee: HACH COMPANYInventor: David L. Rick
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Patent number: 10670573Abstract: An embodiment provides a method for measuring ions in a solution, including: preparing a measurement device comprising an active indicator, wherein the active indicator comprises a silver complex; introducing the measurement device to a solution, wherein the silver complex reacts with the solution and generates a precipitation comprising one of the elements selected from the group consisting of: silver chloride, silver sulfide, and mixtures thereof; and measuring an amount of one of the elements selected from the group consisting of: chloride and sulfide, in the solution, wherein the measuring comprises identifying a peak of the precipitation on a portion of the measurement device and comparing the peak to a measurement chart.Type: GrantFiled: September 25, 2017Date of Patent: June 2, 2020Assignee: HACH COMPANYInventor: Arnold Bertron Kidd, IV
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Patent number: 10634656Abstract: A standard for testing measurement systems for aqueous chlorine species analysis includes an openable storage vessel and an aqueous composition including a compound having the formula R1R2NCl where R1 and R2 are independently methyl, ethyl or propyl, wherein the aqueous composition is storage stable within the openable storage vessel.Type: GrantFiled: October 28, 2016Date of Patent: April 28, 2020Assignee: HACH COMPANYInventor: Darren MacFarland
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Patent number: 10591455Abstract: An embodiment provides a method, including: operating a motor to position sample fluid within a fluid channel of a cuvette; transmitting light through an optical chamber of the cuvette; measuring a value of received light that has been transmitted through the optical chamber; comparing the measured value of light to one or more thresholds; determining a position of the sample fluid within the fluid channel based on a comparison from the comparing step; and generating a response based upon the position of the sample fluid with the fluid channel. Other aspects are described and claimed.Type: GrantFiled: June 23, 2017Date of Patent: March 17, 2020Assignee: HACH COMPANYInventors: Jim Duncan, Aria Farjam, Jim Harbridge, Brian Harmon, Ulrich Lundgreen, Darren MacFarland, Leon Moore, Perry Palumbo, William Louis Pherigo, Jr., Robert Stoughton, Luke Waaler
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Patent number: 10571315Abstract: An embodiment provides a method for measuring velocity and depth of fluid flow in a channel, including: transmitting, using a transmitter, directed energy comprising a single energy beam slant-wise toward a surface of a fluid in a fluid channel producing a plurality of reflections, wherein the transmitting comprises modulating a frequency associated with the single energy beam; detecting, at a receiver, received signals from the plurality of reflections; and determining, based upon differences between parameters of the transmitted single energy beam and parameters of the received signals, the velocity of the fluid and the depth of the fluid. Other embodiments are described and claimed.Type: GrantFiled: September 21, 2017Date of Patent: February 25, 2020Assignee: HACH COMPANYInventor: David L. Rick
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Patent number: 10539529Abstract: A method for determination of an unknown analyte using quantitative electrochemical generation of a detectable species, which provides specified quantities of the species, is described. As an example, free chlorine concentration measurements may be performed using N,N-Diethyl-p-phenylenediamine (DPD), or N,N-bis(2,4-di-sulfobenzyl)toluidinetetrasodium salt (SBT), for obtaining an in-situ calibration curve, whereby matrix effects are eliminated.Type: GrantFiled: August 30, 2017Date of Patent: January 21, 2020Assignee: HACH COMPANYInventor: Vishnu V Rajasekharan
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Patent number: 10527599Abstract: A kit for determining if a shock treatment is required for a water source may comprise a test strip having at least two chemically treated test areas. One of the areas is responsive in color to a concentration of free chlorine in the water and another test area is responsive in color to a concentration of total chlorine in the water. A chlorine indicator scale may be provided on a substrate, such as a label, and comprises a plurality of pairs of colored indicia and each pair of colored indicia representing a color pattern indicating a concentration, or range of concentrations, of total chlorine and free chlorine in the water. An alphanumeric designation may be provided adjacent to each pair of indicia indicating whether a shock treatment is required for the water source based on a color pattern the associated indicia pattern.Type: GrantFiled: January 14, 2014Date of Patent: January 7, 2020Assignee: HACH COMPANYInventors: Teresa Lynn Swanson, Ronald P. Merwin
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Patent number: 10520433Abstract: Various turbidimeters are described that can detect light directly in a substantially circular, e.g., encompassing, manner such that an increased amount of scattered light from a sample vial may be detected by a light detector, e.g., a photodiode or photodiode array. In an embodiment, a substantially circular photodiode array is provided to directly detect scattered light in an arc about the sample vial. In other embodiments, light guides are provided in an arc element that guides light to a detector or detectors. Other aspects are described and claimed.Type: GrantFiled: March 28, 2019Date of Patent: December 31, 2019Assignee: HACH COMPANYInventors: Richard Edward Leggett, Wayne Boris Perdue, Andreas Mitreiter
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Patent number: D936083Type: GrantFiled: January 24, 2020Date of Patent: November 16, 2021Assignee: HACH COMPANYInventors: Michael Jonathan Tschampl, Reece W. Hopkins, Jennifer Kotch, Heather Nicole Goodrich, Victor Ray Williams
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Patent number: D936086Type: GrantFiled: January 24, 2020Date of Patent: November 16, 2021Assignee: HACH COMPANYInventors: Michael Jonathan Tschampl, Reece W. Hopkins, Jennifer Kotch, Heather Nicole Goodrich, Victor Ray Williams