Patents Assigned to HELIOTROPE
  • Patent number: 11467461
    Abstract: An electrochromic (EC) device includes a first substrate, a second substrate, a transparent first conductor disposed between the first and second substrates, a transparent second conductor disposed between the first and second substrates, a working electrode disposed between the first and second conductors, a counter electrode disposed between the working electrode and the second conductor, and an electrolyte disposed between the working and counter electrodes. At least one of the first or second conductors is a multipart conductor which includes a transparent first conductive film, a first contact strip extending lengthwise in a first direction which is perpendicular to a second direction, along a first side of the EC device, and first conductive lines extending from the first contact strip toward an opposing second side of the EC device. The multipart conductor has a lower effective sheet resistance in the second direction than in the first direction.
    Type: Grant
    Filed: May 29, 2020
    Date of Patent: October 11, 2022
    Assignee: HELIOTROPE EUROPE S.L.
    Inventors: Willem den Boer, Amir Bayati, Guillermo Garcia, John Santos, George Rubin
  • Patent number: 11409176
    Abstract: A gel electrolyte precursor composition, an electrochromic device including a gel electrolyte formed from the precursor composition, and methods of forming the electrochromic device, the precursor composition including polymer network precursors including polyurethane acrylate oligomers, an ionically conducting phase, and an initiator.
    Type: Grant
    Filed: December 18, 2018
    Date of Patent: August 9, 2022
    Assignee: HELIOTROPE EUROPE S.L.
    Inventors: Xiaoliang Wang, Evelyn Davies, Janina Motter, Guillermo Garcia, Amir Bayati
  • Patent number: 11299429
    Abstract: An electrochromic device includes a light transmissive first substrate, a working electrode disposed on the first substrate, a light transmissive second substrate facing the first substrate, a counter electrode disposed on the second substrate, and a lithium-rich anti-perovskite (LiRAP) material disposed between the first and second substrates. The LiRAP material includes an ionically conductive and electrically insulating LiRAP material.
    Type: Grant
    Filed: May 26, 2020
    Date of Patent: April 12, 2022
    Assignee: HELIOTROPE TECHNOLOGIES, INC.
    Inventors: Adrian Winoto, Douglas Weir, Guillermo Garcia, Jason K. Holt, Amir Bayati, Bonil Koo, Hai Wang
  • Patent number: 11243447
    Abstract: An electrochromic (EC) device and method, the EC device including: an optically transparent first substrate; a working electrode disposed on the first substrate and including electrochromic nanoparticles and a flux material having a melting point ranging from about 25° C. to about 500° C.; and an electrolyte disposed on the working electrode. The flux material is configured to prevent or reduce sintering of the nanoparticles at a temperature of up to about 700° C.
    Type: Grant
    Filed: April 17, 2019
    Date of Patent: February 8, 2022
    Assignee: HELIOTROPE TECHNOLOGIES INC.
    Inventors: Scott Thomsen, Guillermo Garcia
  • Patent number: 11237448
    Abstract: An electrochromic (EC) device and method of operating the same, the EC device including a transparent substrate, a working electrode disposed on the substrate and including electrochromic inorganic nanoparticles, a counter electrode, and an electrolyte disposed between the working electrode and the counter electrode, the electrolyte including an electrochromic organic material.
    Type: Grant
    Filed: April 23, 2019
    Date of Patent: February 1, 2022
    Assignee: HELIOTROPE TECHNOLOGIES, INC.
    Inventors: Guillermo Garcia, Amir Bayati
  • Patent number: 11221534
    Abstract: A method of forming an electrochromic (EC) device includes forming a solid-state first electrolyte layer, after forming the solid-state first electrolyte layer, laminating the first solid-state first electrolyte layer between a transparent first substrate and a transparent second substrate such that a transparent first electrode is disposed between the first substrate and a first side of the solid-state first electrolyte layer, and a transparent second electrode is disposed between the second substrate and a second side of the solid-state first electrolyte layer, and applying a sealant to seal the solid-state first electrolyte layer between the first and second substrates and to form the EC device.
    Type: Grant
    Filed: February 27, 2019
    Date of Patent: January 11, 2022
    Assignee: HELIOTROPE TECHNOLOGIES, INC.
    Inventors: Xiaoliang Wang, Evelyn Davies, Pedro Gonzalez, Guillermo Garcia, Amir Bayati, John Bohland
  • Patent number: 11079650
    Abstract: Various embodiments may include methods of controlling a temperature of an electrochromic device. The methods may include determining a current temperature of the electrochromic device which includes a first transparent conductor electrically connected to a working electrode, and a second transparent conductor electrically connected to a counter electrode, and applying the heating current to the first transparent conductor and the second transparent conductor if the current temperature is below a minimum temperature to heat the electrochromic device. Further embodiments may include an electrochromic system including an electrochromic device and a controller configured to control the temperature of the electrochromic device.
    Type: Grant
    Filed: May 23, 2019
    Date of Patent: August 3, 2021
    Assignee: HELIOTROPE TECHNOLOGIES, INC.
    Inventors: David England, Jason K. Holt, Guillermo Garcia, Scott Thomsen, Peter Green, Amir Bayati
  • Patent number: 10983409
    Abstract: An electrochromic device and method, the device including: a first transparent conductor layer; a working electrode disposed on the first transparent conductor layer and including nanostructures; a counter electrode; a solid state electrolyte layer disposed between the counter electrode and the working electrode; and a second transparent conductor layer disposed on the counter electrode. The nanostructures may include transition metal oxide nanoparticles and/or nanocrystals configured to tune the color of the device by selectively modulating the transmittance of near-infrared (NIR) and visible radiation as a function of an applied voltage to the device.
    Type: Grant
    Filed: August 15, 2016
    Date of Patent: April 20, 2021
    Assignee: HELIOTROPE TECHNOLOGIES, INC.
    Inventors: Guillermo Garcia, Jason Holt, Scott Thomsen
  • Patent number: 10955716
    Abstract: An electrochromic device includes an optically transparent first substrate, a first transparent conductor disposed on the first substrate, a counter electrode disposed on the first transparent conductor, an optically transparent, ionically conductive first capping layer disposed on the counter electrode, and configured to permit diffusion of alkali metal ions, and to block the diffusion of organic compounds and carbon, an optically transparent second substrate, a second transparent conductor disposed on the second substrate, a working electrode comprising electrochromic nanoparticles disposed on the second transparent conductor, and an electrolyte disposed between the first capping layer and the working electrode.
    Type: Grant
    Filed: June 4, 2019
    Date of Patent: March 23, 2021
    Assignee: HELIOTROPE TECHNOLOGIES, INC.
    Inventors: Amir Bayati, Xiaoliang Wang, Yashraj Bhatnagar, Janina Motter, Guillermo Garcia, Le Sheng Nicholas Yiu
  • Patent number: 10900277
    Abstract: A monolithic method of forming an electrochromic (EC) pane unit, the method including: forming a first electrode via a solution deposition process, on a first conductive layer disposed on a transparent first substrate, forming an electrolyte layer on the first electrode via a sol-gel process, forming a second electrode on the electrolyte layer via a solution deposition process, and forming a second conductive layer on the second electrode.
    Type: Grant
    Filed: October 20, 2017
    Date of Patent: January 26, 2021
    Assignee: HELIOTROPE TECHNOLOGIES, INC.
    Inventors: Jason Holt, Guillermo Garcia, Scott Thomsen
  • Patent number: 10698287
    Abstract: An electrochromic device includes a light transmissive first substrate, a working electrode disposed on the first substrate, a light transmissive second substrate facing the first substrate, a counter electrode disposed on the second substrate, and a lithium-rich anti-perovskite (LiRAP) material disposed between the first and second substrates. The LiRAP material includes an ionically conductive and electrically insulating LiRAP material.
    Type: Grant
    Filed: June 13, 2018
    Date of Patent: June 30, 2020
    Assignee: HELIOTROPE TECHNOLOGIES, INC.
    Inventors: Adrian Winoto, Douglas Weir, Guillermo Garcia, Jason K. Holt, Amir Bayati, Bonil Koo, Hai Wang
  • Patent number: 10359680
    Abstract: An electrochromic device may include a working electrode that includes a high temperature stable material and nanoparticles of an active core material, a counter electrode, and an electrolyte deposited between the working electrode and the counter electrode. The high temperature stable material may prevent fusing of the nanoparticles of the active core material at temperatures up to 700° C. The high temperature stable material may include tantalum oxide. The high temperature stable material may form a spherical shell or a matrix around the nanoparticles of the active core material. A method of forming an electrochromic device may include depositing a working electrode onto a first substrate, in which the working electrode comprises a high temperature stable material and nanoparticles of an active core material, and heat tempering the working electrode and the first substrate.
    Type: Grant
    Filed: December 12, 2017
    Date of Patent: July 23, 2019
    Assignee: HELIOTROPE TECHNOLOGIES, INC.
    Inventors: Guillermo Garcia, Jason Holt, Scott Thomsen
  • Patent number: 10331003
    Abstract: An electrochromic (EC) privacy window includes an EC pane unit including a first EC device having a bright state and a dark state, and a privacy device facing the EC pane unit and having a bright state and a privacy state configured to attenuate visible radiation transmitted through the window. In some embodiments, when the privacy device is in the privacy state, the window has transmitted haze of greater that 80%. In other embodiments, when the privacy device is in the privacy state and the first EC device is in the dark state, the window has a visible transmittance of about 0.1% or less.
    Type: Grant
    Filed: September 22, 2017
    Date of Patent: June 25, 2019
    Assignee: HELIOTROPE TECHNOLOGIES, INC.
    Inventors: Jason Holt, Guillermo Garcia, Scott Thomsen, David England
  • Patent number: 10310352
    Abstract: An electrochromic system and method for controlling photochromic darkening of an electrochromic device, the system including an EC device, a control unit, a voltage detector, and a power supply. The EC device includes a working electrode, a counter electrode, a solid-state polymer electrolyte disposed therebetween, and an ionically conductive and electrically insulating protective layer disposed between the electrolyte and the working electrode. The control unit is configured to control a sweep voltage applied between the working and counter electrodes, such that the sweep voltage is applied when an open circuit voltage (OCV) between the working and counter electrodes is less than a threshold voltage.
    Type: Grant
    Filed: January 27, 2017
    Date of Patent: June 4, 2019
    Assignee: HELIOTROPE TECHNOLOGIES, INC.
    Inventors: Guillermo Garcia, Sourav Basu, Jason Holt
  • Patent number: 10203582
    Abstract: An electrochromic system and method for controlling photochromic darkening of an electrochromic device, the system including an EC device, a control unit, a voltage detector, and a power supply. The EC device includes a working electrode, a counter electrode, a solid-state polymer electrolyte disposed therebetween, and a Bragg reflector configured to selectively reflect UV radiation away from the working electrode. The control unit is configured to control a sweep voltage applied between the working and counter electrodes, such that the sweep voltage is applied when an open circuit voltage (OCV) between the working and counter electrodes is less than a threshold voltage.
    Type: Grant
    Filed: January 27, 2017
    Date of Patent: February 12, 2019
    Assignee: HELIOTROPE TECHNOLOGIES, INC.
    Inventors: Guillermo Garcia, Sourav Basu, Jason Holt
  • Patent number: 10156764
    Abstract: An electrochromic system and method for controlling photochromic darkening of an electrochromic device, the system including an EC device, a control unit, a voltage detector, and a power supply. The EC device includes a working electrode, a counter electrode, and a solid-state polymer electrolyte disposed therebetween. The control unit is configured to control a sweep voltage applied between the working and counter electrodes, such that the sweep voltage is applied when an open circuit voltage (OCV) between the working and counter electrodes is less than a threshold voltage.
    Type: Grant
    Filed: January 27, 2017
    Date of Patent: December 18, 2018
    Assignee: HELIOTROPE TECHNOLOGIES, INC.
    Inventors: Guillermo Garcia, Sourav Basu, Jason Holt
  • Patent number: 9864250
    Abstract: An electrochromic device may include a working electrode that includes a high temperature stable material and nanoparticles of an active core material, a counter electrode, and an electrolyte deposited between the working electrode and the counter electrode. The high temperature stable material may prevent fusing of the nanoparticles of the active core material at temperatures up to 700° C. The high temperature stable material may include tantalum oxide. The high temperature stable material may form a spherical shell or a matrix around the nanoparticles of the active core material. A method of forming an electrochromic device may include depositing a working electrode onto a first substrate, in which the working electrode comprises a high temperature stable material and nanoparticles of an active core material, and heat tempering the working electrode and the first substrate.
    Type: Grant
    Filed: October 13, 2015
    Date of Patent: January 9, 2018
    Assignee: HELIOTROPE TECHNOLOGIES, INC.
    Inventors: Guillermo Garcia, Jason Holt, Scott Thomsen
  • Patent number: 9798214
    Abstract: Methods of charging an electrochromic device includes post assembly charging using a sacrificial redox agent, lithium diffusion into an electrode from a lithium layer or salt bridge charging, or pre assembly charging using proton photoinjection into an electrode.
    Type: Grant
    Filed: February 17, 2016
    Date of Patent: October 24, 2017
    Assignee: HELIOTROPE TECHNOLOGIES INC.
    Inventors: Guillermo Garcia, Jason Holt, Evelyn Rosen, Brett Helms
  • Patent number: 9791760
    Abstract: An electrochromic device includes a nanostructured transition metal oxide bronze layer that includes one or more transition metal oxide and one or more dopant. The electrochromic device also includes nanoparticles containing one or more transparent conducting oxide (TCO), a solid state electrolyte, a counter electrode, and at least one protective layer to prevent degradation of the one or more nanostructured transition metal oxide bronze. The nanostructured transition metal oxide bronze selectively modulates transmittance of near-infrared (NIR) and visible radiation as a function of an applied voltage to the device.
    Type: Grant
    Filed: October 13, 2015
    Date of Patent: October 17, 2017
    Assignee: HELIOTROPE TECHNOLOGIES, INC.
    Inventors: Guillermo Garcia, Bonil Koo, Ivano Gregoratto, Sourav Basu, Evelyn Rosen, Jason Holt, Scott Thomsen
  • Patent number: 9785031
    Abstract: An electrochromic device includes a nanostructured transition metal oxide bronze layer that includes one or more transition metal oxide and one or more dopant, a solid state electrolyte, and a counter electrode. The nanostructured transition metal oxide bronze selectively modulates transmittance of near-infrared (NIR) spectrum and visible spectrum radiation as a function of an applied voltage to the device.
    Type: Grant
    Filed: March 27, 2015
    Date of Patent: October 10, 2017
    Assignees: HELIOTROPE TECHNOLOGIES, INC., THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
    Inventors: Tracy M. Mattox, Bonil Koo, Guillermo Garcia, Delia J. Milliron, Luca De Trizio, Clayton Dahlman