Patents Assigned to Hercules Incorporated
  • Patent number: 8163134
    Abstract: Methods for making a heterogeneous polymer blend comprising one or more anionic polymers, one or more cationic polymers, and one or more non-ionic polymers, which method comprises (a) adding to a non-neutral solution a first amount of polymerization initiator and one or more anionic or cationic monomers, wherein each monomer has the same charge; (b) adding a second amount of the polymerization initiator and one or more non-ionic monomers; (c) adding a third amount of the polymerization initiator and one or more ionic monomers that are oppositely charged from the monomers of (a); adding stepwise, a fourth amount of the polymerization initiator to react any residual monomer, and (e) neutralizing the resulting polymer blend. Also claimed are heterogeneous polymer blends containing polymers formed from one or more anionic, cationic, and non-ionic monomers, either polymerized in situ or separately and then combined.
    Type: Grant
    Filed: September 18, 2009
    Date of Patent: April 24, 2012
    Assignees: Hercules Incorporated, Specialty Minerals (Michigan) Inc.
    Inventors: Frank J. Sutman, Joseph M. Mahoney, Robert Anthony Gill, Daniel Bruce Evans
  • Patent number: 8160305
    Abstract: A method and an apparatus for measuring the depositability of particulate contaminants present in a pulp or paper mill fluid stream and evaluating interactions of such particulate contaminants with other contaminants collects the particulate contaminants on a suitable substrate, such as a plastic film coated with an adhesive or coated with organic contaminate, placed in contact with the pulp or paper mill fluid stream for at least five minutes up to several hours. The amount of contaminants collected on the substrate is quantified and evaluated by taking one or more scanned images of the substrate with a resolution of at least 2,000 dots per inch (DPI) and analyzing the scanned images with image analysis technique.
    Type: Grant
    Filed: November 24, 2008
    Date of Patent: April 17, 2012
    Assignee: Hercules Incorporated
    Inventors: Mark Laurint, Lloyd Lobo, Catherine Kelly
  • Publication number: 20120076747
    Abstract: The present invention is related to surfactant-based formulations comprising the polyelectrolytes and blends of such polyelectrolytes with non-cellulosic cationic polysaccharide polymers wherein the surfactant is a phosphate ester. The surfactant-based formulations exhibit improved clarity of the resulting formulations, their improved conditioning of keratin substrates, textile substrates, and hard-surface substrates, their improved deposition of dispersed phase materials onto keratin substrates, textile substrates, and hard-surface substrates, their improved lather performance, and their improved rheology in applications such as personal care and household care products and textile applications.
    Type: Application
    Filed: December 6, 2011
    Publication date: March 29, 2012
    Applicant: HERCULES INCORPORATED
    Inventors: Patric Bierganns, Paquita Erazo-Majewicz, Nabil Naouli
  • Patent number: 8101710
    Abstract: This invention relates to a process for preparing polyamine-epihalohydrin resins having reduced levels of residuals. The process comprises (a) charging a membrane separation apparatus with an aqueous composition comprising at least one polyamine-epihalohydrin resin, and (b) separating the aqueous composition into a permeate and a retentate by passing the aqueous composition through the membrane of the membrane separation apparatus. The retentate comprises at least one polyamine-epihalohydrin resin having lower levels of residuals on an equal active component basis than the aqueous composition of (a). The permeate comprises residuals removed from the aqueous composition of (a) and less than 5% by weight of the active component of said at least one polyamine-epihalohydrin resin. The polyamine-epihalohydrin resins having reduced levels of residuals can be used to make wet strength agents, dry strength agents, creping adhesives for paper products, curing agents for wood product adhesives, and other products.
    Type: Grant
    Filed: April 25, 2011
    Date of Patent: January 24, 2012
    Assignee: Hercules Incorporated
    Inventors: Richard J. Riehle, Stephen Vinciguerra
  • Publication number: 20110318285
    Abstract: The present invention relates to a personal care composition additive for use on keratin substrates in order to provide long lasting benefits to the keratin substrate such as in conditioning systems, such as 2/1 shampoo's, leave-on and rinse off conditioners, for hair and skin, or for imparting greater water resistance to such personal care compositions as sunscreens or cosmetics.
    Type: Application
    Filed: June 24, 2011
    Publication date: December 29, 2011
    Applicant: Hercules Incorporated
    Inventors: Paquita ERAZO-MAJEWICZ, Gijsbert Kroon, Thi Hong Lan Le-Pham, Tuttu Maria Nuutinen
  • Patent number: 8076279
    Abstract: The present invention is related to the use of a non-cellulosic cationically modified polysaccharide in cleaning compositions and more particularly to a surfactant based cleansing composition comprising, a surfactant, a non-cellulosic cationically modified polysaccharide and a solvent for use in personal care composition, household care composition or an institutional care composition.
    Type: Grant
    Filed: October 9, 2009
    Date of Patent: December 13, 2011
    Assignee: Hercules Incorporated
    Inventors: Piet Brand, Richard G. Brown, Anita N. Chan, Paquita Erazo-Majewicz, Jashawant J. Modi
  • Patent number: 8052840
    Abstract: Compositions and methods for the removal of resin from wood chips processed in a Kraft pulping process are disclosed. The method is particularly useful for removing triterpene and triterpenoid resin.
    Type: Grant
    Filed: August 5, 2009
    Date of Patent: November 8, 2011
    Assignee: Hercules Incorporated
    Inventor: Davit E. Sharoyan
  • Publication number: 20110263814
    Abstract: This invention relates to a process for preparing polyamine-epihalohydrin resins having reduced levels of residuals. The process comprises (a) charging a membrane separation apparatus with an aqueous composition comprising at least one polyamine-epihalohydrin resin, and (b) separating the aqueous composition into a permeate and a retentate by passing the aqueous composition through the membrane of the membrane separation apparatus. The retentate comprises at least one polyamine-epihalohydrin resin having lower levels of residuals on an equal active component basis than the aqueous composition of (a). The permeate comprises residuals removed from the aqueous composition of (a) and less than 5% by weight of the active component of said at least one polyamine-epihalohydrin resin. The polyamine-epihalohydrin resins having reduced levels of residuals can be used to make wet strength agents, dry strength agents, creping adhesives for paper products, curing agents for wood product adhesives, and other products.
    Type: Application
    Filed: April 25, 2011
    Publication date: October 27, 2011
    Applicant: HERCULES INCORPORATED
    Inventors: Richard J. Riehle, Stephen Vinciguerra
  • Patent number: 7998311
    Abstract: Size press compositions and methods for producing sized paper products, including liner board, are disclosed. The size press compositions contain at least one non-reactive cationic surface sizing agent, at least one reactive sizing agent, at least one promoter resin, at least one binder, and water. The at least one non-reactive cationic surface sizing agent may be a polymer in the form of a dispersion, an emulsion or a latex with a positive zeta potential below about pH 6. The at least one reactive sizing agent may be a dispersion, an emulsion or a latex including an alkyl ketene dimer or an alkyl succinic anhydride. The at least one promoter resin may be a polyaminoamide-epichlorohydrin resin or poly (dimethyldiallylammonium chloride).
    Type: Grant
    Filed: July 24, 2008
    Date of Patent: August 16, 2011
    Assignee: Hercules Incorporated
    Inventor: Daniel F. Varnell
  • Patent number: 7981477
    Abstract: Pigmented coated paper is prepared by adding a water-soluble hydroxyalkylcellulose (HAC) with an alkyl moiety of 1 to 4 carbons, or water soluble alkylhydroxyalkylcellulose (AHAC) with an alkyl hydrophobe of 1 to 24 carbons to a pigmented wet coating formulation in an amount equal to or greater than 0.15 parts HAC or AHAC based on pigment content of the coating and applying the pigmented wet coating formulation to a moving paper web via roller metering size press, wherein the use of HAC or AHAC in the pigmented coating significantly reduce misting of the coating during application as compared to the control condition with no HAC or AHAC added.
    Type: Grant
    Filed: February 24, 2005
    Date of Patent: July 19, 2011
    Assignee: Hercules Incorporated
    Inventor: Charles L. Burdick
  • Patent number: 7981247
    Abstract: The present invention relates to processes for enhancing a refiner's production rate and/or reducing the specific energy consumption for a freeness target through the use of lubricant(s) or carrier(s)/frictionizer(s), respectively.
    Type: Grant
    Filed: April 1, 2010
    Date of Patent: July 19, 2011
    Assignee: Hercules Incorporated
    Inventors: Eric Oswaldo Fernandez, Mark Edward Laurint
  • Patent number: 7973004
    Abstract: The present invention relates to aqueous formulations useful in useful in personal care, oral care, household and institutional applications which contain polymers comprised of water soluble synthetic backbone with covalently connected hydrophobic ends can deliver ‘salt-like’ rheology to surfactant formulations containing surfactant concentrations at which thickening by salt is not effective.
    Type: Grant
    Filed: February 12, 2010
    Date of Patent: July 5, 2011
    Assignee: Hercules Incorporated
    Inventor: Konstantin A. Vaynberg
  • Patent number: 7960497
    Abstract: The embodiments of the process of the present invention relate to the preparation of alkyl ketene dimers (AKD), where the process combines at least one polyamine with a fatty acid chloride in a molar ratio of less than one mole of polyamine to one mole of fatty acid chloride thereby forming an alkyl ketene dimer/amine salt that is subsequently separated into an organic dimer layer and an aqueous salt layer.
    Type: Grant
    Filed: January 3, 2007
    Date of Patent: June 14, 2011
    Assignee: Hercules Incorporated
    Inventor: David A. Gerstenhaber
  • Publication number: 20110129880
    Abstract: In this invention, a process for producing fermentable sugars derivable from biomass that contains polysaccharide, such as cellulose, which has been made increasingly accessible as a substrate for enzymatic degradation or other methods of depolymerization. The process of the present invention increases accessibility of polysaccharides, typically present in biomass and produces polysaccharides with increased accessibility. The polysaccharides with increased accessibility may be subsequently saccharified to yield fermentable sugars. These fermentable sugars are subsequently able to be fermented to produce various target chemicals, such as alcohols, aldehydes, ketones or acids.
    Type: Application
    Filed: November 2, 2010
    Publication date: June 2, 2011
    Applicant: Hercules Incorporated
    Inventors: Herbert T. Conners, Patrick J. Cowan, John C. Gast, Robert P. O'Flynn O'Brien
  • Patent number: 7943705
    Abstract: Polyamidoamine (PAE) resins are prepared from polyamidoamine made with excess amine, which are reacted with a specifically defined amount of difunctional crosslinker. The amount of difunctional crosslinker used is based on the polyamidoamine amine number and reduced specific viscosity (RSV). The PAE resin is prepared by first synthesizing a polyamidoamine from a polyamine and a polycarboxylic acid or polycarboxylic acid derivative, wherein the polyamine is present in a molar excess, said molar excess being from about 1.02 to 2.00, then reacting the polyamidoamine with difunctional crosslinker, wherein the weight % of difunctional crosslinker to polyamidoamine solids is no more than about 0.308(amine number/RSV)—9.18 or 385(amine number/RSV)—5.20, wherein the amine number is expressed as the milliequivalents of amine per gram of polyamidoamine solids and the RSV is the reduced specific viscosity measured at 2% concentration in 1M NH4Cl expressed in deciliters per gram.
    Type: Grant
    Filed: January 18, 2008
    Date of Patent: May 17, 2011
    Assignee: Hercules Incorporated
    Inventor: Anthony J. Allen
  • Patent number: 7932349
    Abstract: This invention relates to a process for preparing polyamine-epihalohydrin resins having reduced levels of residuals. The process comprises (a) charging a membrane separation apparatus with an aqueous composition comprising at least one polyamine-epihalohydrin resin, and (b) separating the aqueous composition into a permeate and a retentate by passing the aqueous composition through the membrane of the membrane separation apparatus. The retentate comprises at least one polyamine-epihalohydrin resin having lower levels of residuals on an equal active component basis than the aqueous composition of (a). The permeate comprises residuals removed from the aqueous composition of (a) and less than 5% by weight of the active component of said at least one polyamine-epihalohydrin resin. The polyamine-epihalohydrin resins having reduced levels of residuals can be used to make wet strength agents, dry strength agents, creping adhesives for paper products, curing agents for wood product adhesives, and other products.
    Type: Grant
    Filed: September 17, 2007
    Date of Patent: April 26, 2011
    Assignee: Hercules Incorporated
    Inventors: Richard J. Riehle, Steven Vinciguerra
  • Patent number: 7932309
    Abstract: A water-borne coating composition containing an ether derivative of raw cotton linters (RCL), a latex polymer, and water in which the ether derivative RCL provides improved rheological properties when compared to analogous cellulose ether compounds produced from more refined cellulose sources while not substantially degrading the coating composition's aesthetic qualities.
    Type: Grant
    Filed: November 2, 2006
    Date of Patent: April 26, 2011
    Assignee: Hercules Incorporated
    Inventors: Paul C. Gillette, Arjun C. Sau
  • Patent number: 7902312
    Abstract: Several Michael addition adducts of vinylamines with ?,?. -unsaturated alkyl carbonyl compounds including amides, esters and acids, particularly acrylamide are presented. Additionally, a process for producing these Michael addition adducts is described. These adducts are generally useful in the manufacture of paper and are particularly useful as dry strength additives to make paperboard products using a papermaking machine.
    Type: Grant
    Filed: May 18, 2007
    Date of Patent: March 8, 2011
    Assignee: Hercules Incorporated
    Inventors: Qu-Ming Gu, Ronald R. Staib
  • Publication number: 20110048281
    Abstract: The present invention relates to a film coating composition used for film coating pharmaceutical tablets, nutritional supplements, confectionary forms and the like. The film coating composition comprises a water soluble film former such as hydroxypropylcellulose, hydroxypropylmethylcellulose, hydroxyethylcellulose, starches, modified starches and the like and one or more hydrophobic compounds, such as metal salt of higher fatty acids, higher fatty alcohol, natural wax either from vegetable, animal origin or synthetic wax. Optionally, the film coating composition may include plasticizers, colorants, such as pigments and/or flow aids.
    Type: Application
    Filed: August 26, 2010
    Publication date: March 3, 2011
    Applicant: HERCULES INCORPORATED
    Inventors: Thomas DURIG, Divya TEWARI
  • Patent number: 7893115
    Abstract: An oil-in-water emulsion useful as a defoamer for pulp and paper mill applications is described. The defoamer has an oil blend (of a triglyceride oil or a mixture of triglyceride oils and silicone), a stabilizing agent (to make the oil blend stable in the emulsion), hydrophobic silica particles, surfactants, dispersants, and other components. The emulsion is usable directly at low concentrations to control foam.
    Type: Grant
    Filed: December 8, 2005
    Date of Patent: February 22, 2011
    Assignee: Hercules Incorporated
    Inventors: Huai N. Cheng, Eric O. Fernandez, John M. Sheepy