Patents Assigned to Hodogaya Chemical Co., Ltd.
  • Publication number: 20220149291
    Abstract: It is an object of the present invention to provide an organic EL element including a capping layer constituted by two layers consisting of a first capping layer and a second capping layer that has a refractive index that is higher than that of the first capping layer, in order to improve the light extraction efficiency compared with an organic EL element including a capping layer constituted by a single layer. The present invention provides an organic electroluminescent element at least including an anode, a hole transport layer, a light emitting layer, an electron transport layer, a cathode, and a capping layer arranged in this order, wherein the capping layer has a structure constituted by two layers consisting of a first capping layer and a second capping layer, a refractive index of the second capping layer is higher than a refractive index of the first capping layer throughout a wavelength range from 450 to 650 nm, and the second capping layer contains an arylamine compound having a specific structure.
    Type: Application
    Filed: February 28, 2020
    Publication date: May 12, 2022
    Applicants: HODOGAYA CHEMICAL CO., LTD., SFC CO., LTD.
    Inventors: Yuta HIRAYAMA, Shunji MOCHIZUKI, Takeshi YAMAMOTO, Shuichi HAYASHI, Young-hwan PARK
  • Publication number: 20220119360
    Abstract: An objective of the invention is to provide an organic EL device that combines various materials of the device and a capping layer composed from a material that absorbs sunlight within the wavelength range of 400 nm to 410 nm to prevent impact on materials inside the organic EL device, has a high light absorption coefficient and a high refractive index to significantly improve light extraction efficiency, has excellent stability, durability and light resistance in a thin film, and has no absorption within the wavelength ranges of blue, green and red, to thereby effectively achieve the characteristics of the various materials of the device. The invention is an arylamine compound having a benzazole structure, and is also an organic EL device including a capping layer containing the arylamine compound and a light-emitting layer containing a host and a phosphorescent dopant.
    Type: Application
    Filed: February 21, 2020
    Publication date: April 21, 2022
    Applicants: HODOGAYA CHEMICAL CO., LTD., SFC CO., LTD.
    Inventors: Shunji MOCHIZUKI, Takuya UEHARA, Kouki KASE, Yuta HIRAYAMA, Takeshi YAMAMOTO, Shuichi HAYASHI, Young-Tae CHOI, Se-Jin LEE, Seok-Bae PARK, Tae-Jung YU, Byung-Sun YANG
  • Publication number: 20220102632
    Abstract: [Object] An object of the present invention is to provide, as a material for an organic EL device having high efficiency and a high durability, a material for an organic EL device having excellent injection/transport performance of holes, excellent electron blocking capability, excellent stability in a thin-film state, and an excellent durability, and to further provide an organic EL device having high efficiency, a low drive voltage, and a long lifetime by combining the material and various materials for an organic EL device having excellent injection/transport performance of holes and electrons, excellent electron blocking capability, excellent stability in a thin-film state, and an excellent durability so that the properties of the respective materials can be effectively exhibited.
    Type: Application
    Filed: February 7, 2020
    Publication date: March 31, 2022
    Applicant: HODOGAYA CHEMICAL CO., LTD.
    Inventors: Kazuyuki SURUGA, Takeshi YAMAMOTO, Shunji MOCHIZUKI, Yuta HIRAYAMA, Shuichi HAYASHI
  • Publication number: 20220102635
    Abstract: An organic light-emitting element according to the present invention employs a polycyclic aromatic derivative compound in a light-emitting layer inside the element, and further comprises a capping layer. Thus, the organic light-emitting element can be made highly efficient and can be useful for a device selected from among a flat panel display device, a flexible display device, a monochrome or white flat panel lighting device, and a monochrome or white flexible lighting device.
    Type: Application
    Filed: November 28, 2019
    Publication date: March 31, 2022
    Applicants: SFC CO., LTD., HODOGAYA CHEMICAL CO., LTD.
    Inventors: Sung-hoon JOO, Byung-sun YANG, Su-jin KIM, Ji-hwan KIM, Hyeon-jun JO, Sung-eun CHOI, Bong-ki SHIN, Young-hwan PARK, Shuichi HAYASHI, Takeshi YAMAMOTO, Shunji MOCHIZUKI, Yuta HIRAYAMA
  • Patent number: 11279792
    Abstract: The present invention relates to a method for producing a biopolyether polyol, which is a copolymerization reaction of tetrahydrofuran and 2-methyltetrahydrofuran in a monomer ratio (by mass) of 85/15 to 50/50, and the resulting polyether polyol of 100% plant origin having a number-average molecular weight of 500-5000. In addition, a polyurethane resin, which is the product of a synthetic reaction having as the main reactants the above polyether polyol of 100% plant origin, a polyisocyanate compound, and a chain extender that reacts with isocyanate groups, has a change in storage modulus (E?) in the low temperature range (0° C.) with respect to normal temperature (20° C.) of within 0-15%.
    Type: Grant
    Filed: March 29, 2018
    Date of Patent: March 22, 2022
    Assignee: HODOGAYA CHEMICAL CO., LTD.
    Inventors: Yohei Goto, Tsuyoshi Sato, Yuo Maruyama
  • Patent number: 11283026
    Abstract: A compound that emits fluorescence and delayed fluorescence is provided as a material for an organic electroluminescent device of high efficiency, and an organic photoluminescent device and an organic electroluminescent device of high efficiency and high luminance are provided using this compound. The compound of general formula (1) having a tetraazatriphenylene ring structure is used as a constituent material of at least one organic layer in an organic electroluminescent device that includes a pair of electrodes, and one or more organic layers sandwiched between the pair of electrodes.
    Type: Grant
    Filed: April 15, 2015
    Date of Patent: March 22, 2022
    Assignees: Hodogaya Chemical Co., Ltd., Kyulux, Inc.
    Inventors: Chihaya Adachi, Takuma Yasuda, Katsuyuki Shizu, Takehiro Takahashi
  • Patent number: 11273110
    Abstract: A dye for hair coloration that has a long shelf life and is excellent in heat resistance, and a method for producing the dye for hair coloration, are provided. A dye for hair coloration represented by the following general formula (1), the dye for hair coloration having a proportion of a polyatomic anion (An) or impurities derived from An of 1% by mass or less: wherein in the formula (1), D represents a cationic moiety of the dye for hair coloration; An represents a polyatomic anion; and a and b each independently represent a value of 0 to 1.
    Type: Grant
    Filed: February 25, 2021
    Date of Patent: March 15, 2022
    Assignee: HODOGAYA CHEMICAL CO., LTD.
    Inventors: Keigo Naito, Tetsuya Yoshida
  • Publication number: 20220077403
    Abstract: The present invention provides various organic electroluminescent elements using a material for a capping layer and a material for a luminous layer, in which the material for a capping layer uses an arylamine material that exhibit excellent stability and durability in the form of a thin film, especially a specific amine compound having a high refractive index and having a high absorbance within a wavelength range from 400 nm to 410 nm in the absorption spectrum at a concentration of 10?5 mol/L; and in which the material for a luminous layer uses a compound containing a heterocyclic compound that has a specific fused ring structure.
    Type: Application
    Filed: December 18, 2019
    Publication date: March 10, 2022
    Applicants: Hodogaya Chemical Co., Ltd., SFC CO., LTD.
    Inventors: Yuta HIRAYAMA, Takeshi YAMAMOTO, Shunji MOCHIZUKI, Shuichi HAYASHI, Se-Jin LEE, Oun-Gyu LEE, Bong-Ki SHIN
  • Publication number: 20220052273
    Abstract: An object of the present invention is to provide, as a material for a highly efficient and highly durable organic EL element, an organic compound that has excellent properties, including excellent electron-injecting/transporting capability, hole-blocking capability, and high stability in the form of a thin film. Another object of the present invention is to provide a highly efficient and highly durable organic EL element by using this compound. The present invention focuses on the properties of the benzazole ring, which has affinity for electrons, and specifically focuses on the capability of its nitrogen atom to coordinate to a metal and also on excellent heat resistance. The inventors have thus designed and chemically synthesized various compounds having a benzazole ring structure, and then experimentally produced organic EL elements including the compounds, followed by thoroughly evaluating the characteristics thereof.
    Type: Application
    Filed: February 12, 2020
    Publication date: February 17, 2022
    Applicant: HODOGAYA CHEMICAL CO., LTD.
    Inventors: Kouki KASE, Si-In KIM, Ji-Yung KIM, Yuta HIRAYAMA, Kazuyuki SURUGA, Shuichi HAYASHI
  • Publication number: 20220052268
    Abstract: An object of the present invention is to provide, as a material for a highly efficient and highly durable organic EL element, an organic compound having excellent properties, including excellent electron-injecting/transporting capability, hole-blocking capability, and high stability in the form of a thin film. Another object of the present invention is to provide a highly efficient and highly durable organic EL element by using this compound. The present invention provides a compound having a pyrimidine ring structure that is designed and chemically synthesized with the focus on the properties of the pyrimidine ring, which has affinity for electrons, specifically with the focus on the capability of the nitrogen atoms to coordinate to a metal and excellent heat resistance. Various organic EL elements including the compound were experimentally produced, followed by evaluation of the characteristics of those elements. From the results, it was found that the organic EL elements have favorable characteristics.
    Type: Application
    Filed: October 15, 2019
    Publication date: February 17, 2022
    Applicant: HODOGAYA CHEMICAL CO., LTD.
    Inventors: Kouki KASE, Si-In KIM, Yuta HIRAYAMA
  • Patent number: 11251373
    Abstract: A high molecular weight compound according to the present invention includes a substituted triarylamine structural unit represented by the following general formula (1), where AR1, AR2, and L each independently represent a divalent aromatic hydrocarbon group or a divalent aromatic heterocyclic group, n is an integer of 1 to 3, Ar1 and Ar2 each independently represent an aryl group or a heteroaryl group, and R1, R2, and R3 each independently represent a hydrogen atom, a heavy hydrogen atom, a fluorine atom, a chlorine atom, a cyano group, a nitro group, an alkyl group having 1 to 6 carbon atoms, an alkyloxy group having 1 to 6 carbon atoms, a cycloalkyl group having 5 to 10 carbon atoms, a cycloalkyloxy group having 5 to 10 carbon atoms, an alkenyl group having 2 to 6 carbon atoms, an aryl group, an aryloxy group, or a heteroaryl group.
    Type: Grant
    Filed: November 29, 2017
    Date of Patent: February 15, 2022
    Assignee: HODOGAYA CHEMICAL CO., LTD.
    Inventors: Kazunori Togashi, Hideyoshi Kitahara, Mari Kaneko, Junichi Izumida
  • Patent number: 11239439
    Abstract: To provide a light-emitting material of a light emitting layer, particularly a dopant material or a host material of a light emitting layer emitting delayed fluorescence, or a material suitable for a hole blocking layer, as a material for an organic electroluminescent device having a high efficiency, and also to provide an organic photoluminescent device or an organic electroluminescent device having a high efficiency and a high luminance, particularly an organic EL device suppressed in the roll-off phenomenon, by using the material. A material for an organic electroluminescent device, containing a benzonitrile derivative of the following general formula (1), and an organic electroluminescent device containing a pair of electrodes and one layer or plural layers including at least a light emitting layer intervening between the electrodes, the organic electroluminescent device using the material.
    Type: Grant
    Filed: March 14, 2016
    Date of Patent: February 1, 2022
    Assignees: Hodogaya Chemical Co., Ltd., Hirata Corporation, Kyulux, Inc.
    Inventors: Chihaya Adachi, Jun-Ichi Nishide, Yasuhide Hiraga, Takehiro Takahashi
  • Patent number: 11217754
    Abstract: According to the present invention, there is provided an organic electroluminescent device which has an anode, a hole transport layer, a luminous layer, an electron transport layer, and a cathode arranged in order of description. The device is characterized in that: the hole transport layer includes a specific arylamine compound, and that the luminous layer includes a specific indenoindole derivative or a specific carbazole derivative. The organic EL device of the present invention has improved efficiency of hole transport from the hole transport layer to the luminous layer and also improved efficiency of electron transport from the electron transport layer to the luminous layer, in comparison to conventional organic EL devices.
    Type: Grant
    Filed: July 27, 2015
    Date of Patent: January 4, 2022
    Assignees: HODOGAYA CHEMICAL CO., LTD., SFC CO., LTD.
    Inventors: Shuichi Hayashi, Naoaki Kabasawa, Shunji Mochiduki, Se-Jin Lee, Oun-gyu Lee, Bong-Ki Shin
  • Publication number: 20210395269
    Abstract: An object of the present invention is to provide, as a material for a highly efficient and highly durable organic EL element, an organic compound having excellent properties, including excellent electron-injecting/transporting capability, hole-blocking capability, and high stability in the form of a thin film. Another object of the present invention is to provide a highly efficient and highly durable organic EL element by using this compound. The compound having an azabenzoxazole ring structure of the present invention has excellent heat resistance, and good electron-transporting capability. An organic EL element having an electron-transporting layer, a hole-blocking layer, a light-emitting layer, or an electron-injecting layer including the compound had favorable element characteristics.
    Type: Application
    Filed: November 26, 2019
    Publication date: December 23, 2021
    Applicant: HODOGAYA CHEMICAL CO., LTD.
    Inventors: Kouki KASE, Si-In KIM, Ji-Yung KIM, Yuta HIRAYAMA
  • Publication number: 20210399224
    Abstract: An object of the present invention is to provide, as a material for a highly efficient and highly durable organic EL element, an organic compound having excellent hole-injecting/transporting capability, electron-blocking capability, stability in the form of a thin film, and durability. Furthermore, another object of the present invention is to provide an organic EL element having high efficiency, a low driving voltage, and a long lifespan, by combining the organic compound with various materials for organic EL elements so as to effectively exhibit the properties of the individual materials, the materials having excellent hole/electron-injecting/transporting capability, electron-blocking capability, stability in the form of a thin film, and durability. The arylamine compound having a specific structure according to the present invention has excellent hole-injecting/transporting capability, stability in the form of a film, and durability.
    Type: Application
    Filed: November 26, 2019
    Publication date: December 23, 2021
    Applicant: HODOGAYA CHEMICAL CO., LTD.
    Inventors: Kazuyuki SURUGA, Takeshi YAMAMOTO, Shunji MOCHIZUKI, Kouki KASE, Jae-Geon LIM
  • Patent number: 11196004
    Abstract: A high molecular weight compound according to the present invention includes a substituted triarylamine structural unit represented by a general formula (1) below, where Ar1 and Ar2 are a divalent aromatic hydrocarbon group or a divalent aromatic heterocyclic group, R1 and R2 represent a hydrogen atom, a heavy hydrogen atom, a fluorine atom, a chlorine atom, a cyano group, a nitro group, an alkyl group, a cycloalkyl group, an alkenyl group, an alkyloxy group, or a cycloalkyloxy group, X, Y and Z are, on the condition that at least one of them is an aryl group or a heteroaryl group, an aryl group, a heteroaryl group, or a group similar to the groups represented by R1 and R2 above.
    Type: Grant
    Filed: March 9, 2018
    Date of Patent: December 7, 2021
    Assignee: HODOGAYA CHEMICAL CO., LTD.
    Inventors: Kazunori Togashi, Hideyoshi Kitahara, Junichi Izumida, Mari Kaneko
  • Patent number: 11158813
    Abstract: To provide an organic EL device having (1) high luminous efficiency and high power efficiency, (2) low turn on voltage, (3) low actual driving voltage, and (4) a long lifetime, by combining various materials for an organic EL device, which are excellent in hole injection/transport performances, electron injection/transport performances, electron blocking ability, stability in a thin-film state, and durability, so as to allow the respective materials to effectively reveal their characteristics. In the organic EL device having at least an anode, a hole transport layer, a light emitting layer, an electron transport layer and a cathode in this order, the hole transport layer includes an arylamine compound of the following general formula (1), and the electron transport layer includes a compound of the following general formula (2) having a benzazole ring structure.
    Type: Grant
    Filed: March 15, 2018
    Date of Patent: October 26, 2021
    Assignee: Hodogaya Chemical Co., Ltd.
    Inventors: Naoaki Kabasawa, Shuichi Hayashi, Kazuyuki Suruga, Shunji Mochizuki
  • Patent number: 11158811
    Abstract: In the organic electroluminescent device having at least an anode, a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer and a cathode in this order, the hole injection layer includes an arylamine compound of the following general formula (1) and an electron acceptor. In the formula, Ar1 to Ar4 may be the same or different, and represent a substituted or unsubstituted aromatic hydrocarbon group, a substituted or unsubstituted aromatic heterocyclic group, or a substituted or unsubstituted condensed polycyclic aromatic group.
    Type: Grant
    Filed: December 1, 2015
    Date of Patent: October 26, 2021
    Assignees: Hodogaya Chemical Co., Ltd., SFC Co., Ltd.
    Inventors: Shuichi Hayashi, Naoaki Kabasawa, Daizou Kanda, Shunji Mochizuki, Soon-wook Cha, Sang-woo Park, Ju-man Song, Kyung-seok Jeon
  • Publication number: 20210267861
    Abstract: A dye for hair coloration that has a long shelf life and is excellent in heat resistance, and a method for producing the dye for hair coloration, are provided. A dye for hair coloration represented by the following general formula (1), the dye for hair coloration having a proportion of a polyatomic anion (An) or impurities derived from An of 1% by mass or less: wherein in the formula (1), D represents a cationic moiety of the dye for hair coloration; An represents a polyatomic anion; and a and b each independently represent a value of 0 to 1.
    Type: Application
    Filed: February 25, 2021
    Publication date: September 2, 2021
    Applicant: HODOGAYA CHEMICAL CO., LTD.
    Inventors: Keigo NAITO, Tetsuya YOSHIDA
  • Patent number: 11104759
    Abstract: The present invention relates to a polyol for a crosslinkable polyurethane resin composition, containing a high molecular polyol represented by the following formula (1) or (2), in which the high molecular polyol is a condensate of a polyfunctional carboxylic acid (A) with a bifunctional polyether polyol (B), the high molecular polyol has a number average molecular weight (Mn) in a range of 1,000 to 10,000, and the polyol for a crosslinkable polyurethane resin composition has a content of the high molecular polyol of 0.1 wt % to 15 wt %.
    Type: Grant
    Filed: June 13, 2019
    Date of Patent: August 31, 2021
    Assignee: HODOGAYA CHEMICAL CO., LTD.
    Inventors: Akihiro Matsumoto, Yuo Maruyama