Patents Assigned to Hoechst Mitsubishi Kasei Co.
  • Patent number: 5569751
    Abstract: The present invention relates to new useful azo dyestuffs which are free from ionic groups, of the general formula I ##STR1## wherein X.sup.1, X.sup.2, X.sup.3, Y, R, R.sup.1 and R.sup.2 have the meanings given in Claim 1, mixtures of dyestuffs of the general formula I, the preparation of dyestuffs of the general formula I and their use for dyeing and printing hydrophobic fibre materials.
    Type: Grant
    Filed: May 24, 1995
    Date of Patent: October 29, 1996
    Assignee: Hoechst Mitsubishi Kasei Co.
    Inventor: Ulrich Buhler
  • Patent number: 5512063
    Abstract: The present invention relates to the use of phenol- and naphthol-novolak alkoxylate mixed esters which as dyeing auxiliaries in the dyeing of polyester-cellulose blend fabrics prevent soiling of the cellulose portion by the disperse dyestuff and to processes for the continuous dyeing of such blend fabrics using phenol- and naphthol-novolak alkoxylate mixed esters.
    Type: Grant
    Filed: September 16, 1994
    Date of Patent: April 30, 1996
    Assignee: Hoechst Mitsubishi Kasei Co
    Inventor: Hubert Kruse
  • Patent number: 5474579
    Abstract: The present invention relates to mixtures of monoazo dyes, characterised in that they comprise one or more dyes of the general formula I ##STR1## one or more dyes of the general formula II ##STR2## and one or more dyes of the general formula III ##STR3## in which R.sup.1 to R.sup.8 independently of one another, are methyl, ethyl or n-propyl and R.sup.1 and R.sup.2 may each also be i-propyl and Hal is chlorine or bromine, processes for their preparation and their use for the dyeing and printing of hydrophobic synthetic fibre materials and blends thereof with natural fibre materials.
    Type: Grant
    Filed: September 8, 1994
    Date of Patent: December 12, 1995
    Assignee: Hoechst Mitsubishi Kasei Co.
    Inventor: Ulrich Buhler
  • Patent number: 5440024
    Abstract: A monoazo disperse dye for dyeing polyester fibers of the following formula (I): ##STR1## wherein one of R.sup.1 and R.sup.2 is ##STR2## wherein W is hydrogen, halogen, C.sub.1 -C.sub.2 alkyl or alkoxy, the other of R.sup.1 and R.sup.2 is C.sub.1 -C.sub.4 alkyl, or C.sub.2 -C.sub.4 alkyl substituted by cyano, halogen, hydroxy, hydroxyalkoxy, C.sub.1 -C.sub.4 alkoxy, hydroxyalkoxyalkoxy, acetoxalkoxy, acyloxyalkoxyalkoxy alkoxyalkoxy, alkoxycarbonyloxy or acetoxy, and Y is hydrogen or halogen.
    Type: Grant
    Filed: July 13, 1993
    Date of Patent: August 8, 1995
    Assignee: Hoechst Mitsubishi Kasei Co., Ltd.
    Inventors: Kiyoshi Himeno, Toshio Hihara, Wataru Shimizu
  • Patent number: 5425785
    Abstract: The present invention relates to a process for dyeing polyester or polyester-containing textile materials at pH 8 to pH 11 with one or more monoazo dyestuffs of the general formula I ##STR1## in which A, R and X.sup.1 to X.sup.3 are as defined in claim 1.
    Type: Grant
    Filed: August 17, 1994
    Date of Patent: June 20, 1995
    Assignee: Hoechst Mitsubishi Kasei Co.
    Inventors: Ulrich Buhler, Ralf Zerrer
  • Patent number: 5415669
    Abstract: The present invention relates to mixtures of dyes of the general formula I ##STR1## in which R.sup.1 is hydrogen, halogen, (C.sub.1 -C.sub.4) -alkyl or (C.sub.1 -C.sub.4)-alkoxy;R.sup.2 is hydrogen, halogen, cyano, (C.sub.1 -C.sub.4)-alkyl, (C.sub.1 -C.sub.4)-alkoxy, (C.sub.1 -C.sub.4)-alkoxycarbonyl, (C.sub.1 -C.sub.4)-alkylcarbonyloxy or phenyl, which may be substituted or unsubstituted;R.sup.3 is hydrogen, (C.sub.1 -C.sub.4)-alkyl, (C.sub.1 -C.sub.4)-alkoxy or phenyl, which may be substituted or unsubstituted; andR.sup.4 is hydrogen, halogen, (C.sub.1 -C.sub.4)-alkoxy, phenylthio or phenoxy, which may be substituted or unsubstituted, to processes for their preparation and to the use of the dyes of the general formula I and their mixtures with one another for the dyeing and printing of textile hydrophobic synthetic fibre materials and blends thereof with natural fibre materials.
    Type: Grant
    Filed: January 19, 1993
    Date of Patent: May 16, 1995
    Assignee: Hoechst Mitsubishi Kasei Co.
    Inventors: Ulrich Buhler, Hubert Kruse, Erwin Dietz
  • Patent number: 5389109
    Abstract: The present invention relates to a process for the preparation of highly thermomigration-resistant dyeings on fiber materials composed entirely or in part of polyester, in which the fiber materials, after dyeing, are subjected to a heat treatment, characterized in that dyeing is carried out with one or more dyes of the general formula I ##STR1## in which R.sup.1 and R.sup.2 independently of one another, are methyl and ethyl.
    Type: Grant
    Filed: November 23, 1992
    Date of Patent: February 14, 1995
    Assignee: Hoechst Mitsubishi Kasei Co.
    Inventor: Ulrich Buhler
  • Patent number: 5340930
    Abstract: A monoazodye of the following formula (I): ##STR1## wherein R.sup.1 is hydrogen, methyl or chlorine, R.sup.2 is hydrogen or methyl, R.sup.3 is C.sub.1 -C.sub.5 alkyl, R.sup.4 is phenyl, benzyl, phenoxy, C.sub.1 -C.sub.5 alkoxy, C.sub.1 -C.sub.5 alkyl or benzyloxy, provided that when R.sup.4 is alkyl, the total number of carbon atoms of R.sup.3 and R.sup.4 is at least 4.The monoazo dye of the present invention can be used to dye fibers such as polyester fibers, blended yarn products or combined filament yarn products such as polyester fibers with natural fibers.
    Type: Grant
    Filed: June 3, 1992
    Date of Patent: August 23, 1994
    Assignee: Hoechst Mitsubishi Kasei Co., Ltd.
    Inventors: Kiyoshi Himeno, Ryouichi Sekioka
  • Patent number: 5332404
    Abstract: A disperse dye mixture comprising a monoazo dye of the following formula (1) and a monoazo dye of the following formula (2) blended thereto in an amount of from 0.1 to 10 times by weight of the dye of the formula (1): ##STR1## wherein each of X.sup.1 and X.sup.2 which are independent of each other, is nitro, cyano, sulfomethyl or halogen, each of Y.sup.1, Y.sup.2, Z.sup.1 and Z.sup.2 which are independent of one another, is hydrogen, cyano, nitro, trifluoromethyl, halogen or sulfomethyl, each of W.sup.1 and W.sup.2 which are independent of each other, is hydrogen, halogen, C.sub.1 -C.sub.2 alkyl or alkoxy, and each of R.sup.1 and R.sup.2 which are independent of each other, is C.sub.1 -C.sub.4 alkyl, or C.sub.2 -C.sub.4 alkyl which is substituted by cyano, halogen, hydroxy, hydroxyalkoxy, C.sub.1 -C.sub.4 alkyl, hydroxyalkoxyalkoxy, acyloxyalkoxy, acyloxyalkoxyalkoxy or alkoxyalkoxy.
    Type: Grant
    Filed: December 10, 1992
    Date of Patent: July 26, 1994
    Assignee: Hoechst Mitsubishi Kasei Co., Ltd.
    Inventors: Kiyoshi Himeno, Toshio Hihara, Hirotsugu Tsumura, Yoshiharu Hamano
  • Patent number: 5304222
    Abstract: A disperse dye mixture comprising from 20 to 80% by weight of a red disperse dye of the following formula (A) and from 20 to 80% by weight of a red disperse dye of the following formula (B): ##STR1## wherein R.sup.1 is --C.sub.2 H.sub.5 or --C.sub.2 H.sub.4 OCOCH.sub.3, R.sup.2 is --C.sub.2 H.sub.4 OCOCH.sub.3 or --C.sub.2 H.sub.4 CN, and R.sup.3 is hydrogen or --CH.sub.3.
    Type: Grant
    Filed: June 17, 1992
    Date of Patent: April 19, 1994
    Assignee: Hoechst Mitsubishi Kasei Co., Ltd.
    Inventors: Ryouichi Sekioka, Kouichi Seto
  • Patent number: 5292872
    Abstract: A Monoazo dye of the general formula I ##STR1## in which X is methyl, chlorine or bromineR.sup.1 is ethyl, n-propyl, i-propyl, n-butyl or i-butylR.sup.2 is methyl, ethyl, n-propyl, i-propyl, n-butyl or i-butyl andn is 2 or 3,mixtures containing dyes of the general formula I and the preparation of these dyes and their mixtures and their use for the dyeing of hydrophobic synthetic materials, in particular for automotive cover fabrics.
    Type: Grant
    Filed: November 24, 1992
    Date of Patent: March 8, 1994
    Assignee: Hoechst Mitsubishi Kasei Co.
    Inventor: Ulrich Buhler
  • Patent number: 5290931
    Abstract: Water-insoluble naphthalic acid imide dyestuffs of the following formula: ##STR1## wherein D is ##STR2## wherein R.sup.1 is C.sub.1 -C.sub.8 alkyl which may be substituted, R.sup.2 is hydrogen, halogen, lower alkyl, lower alkoxy or cyano, X is oxygen or sulfur, and m is 0 or 1; A is phenylene, alkylene, aralkylene or --C.sub.2 H.sub.4 OC.sub.2 H.sub.4 --; B is oxygen, sulfur or ##STR3## wherein R.sup.3 is hydrogen or lower alkyl; Y is a 6-membered nitrogen-containing heterocyclic ring having at least one active halogen atom; and n is 0 or 1.
    Type: Grant
    Filed: September 4, 1992
    Date of Patent: March 1, 1994
    Assignee: Hoechst Mitsubishi Kasei Co., Ltd.
    Inventors: Kiyoshi Himeno, Toshio Hihara
  • Patent number: 5278294
    Abstract: A monoazodye of the following formula (I): ##STR1## wherein X is CN, Cl or Br, one of R.sup.1 and R.sup.2 is phenyl and the other is --C.sub.2 H.sub.4 OC.sub.2 H.sub.4 OR.sup.3, wherein R.sup.3 is C.sub.1 -C.sub.5 alkyl, formyl, C.sub.2 -C.sub.6 alkylcarbonyl or C.sub.2 -C.sub.6 alkoxycarbonyl.
    Type: Grant
    Filed: May 26, 1992
    Date of Patent: January 11, 1994
    Assignee: Hoechst Mitsubishi Kasei Co., Ltd.
    Inventors: Kiyoshi Himeno, Ryouichi Sekioka
  • Patent number: 5248314
    Abstract: The present invention relates to a process for the HT dyeing of polyester or polyester-containing textile materials at pH 8 to pH 11, characterised in that one or more monoazo dyes are used of the general formula I ##STR1## where Hal is chlorine or bromine,R is alkyl of 3 to 7 carbon atoms, andR.sup.1 and R.sup.2 are each independently of the other linear alkyl of 2 to 5 carbon atoms or allyl.
    Type: Grant
    Filed: October 26, 1992
    Date of Patent: September 28, 1993
    Assignee: Hoechst Mitsubishi Kasei Co.
    Inventor: Ulrich Buhler
  • Patent number: 5242467
    Abstract: A reactive dye mixture which comprises, as dye components, from 10 to 57% by weight of C.I. Reactive Orange 16 and from 90 to 43% by weight of C.I. Reactive Orange 7.
    Type: Grant
    Filed: August 28, 1992
    Date of Patent: September 7, 1993
    Assignee: Hoechst Mitsubishi Kasei Co., Ltd.
    Inventors: Yuji Yamada, Mitsuhiro Suzuki, Kensuke Suzuki
  • Patent number: 5201922
    Abstract: A disperse dye mixture comprising from 20 to 80% by weight of an orange disperse dye of the following formula (A) and from 20 to 80% by weight of an orange disperse dye of the following formula (B), as dye components: ##STR1##
    Type: Grant
    Filed: December 12, 1991
    Date of Patent: April 13, 1993
    Assignee: Hoechst Mitsubishi Kasei Co., Ltd.
    Inventors: Kouichi Seto, Riyouichi Sekioka
  • Patent number: 5114431
    Abstract: A disperse dye mixture comprising a red disperse dye of the following formula (A): ##STR1## and at least one red disperse dye of the following formula (B): ##STR2## wherein R.sup.1 is C.sub.2 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy C.sub.2 -C.sub.3 alkyl or C.sub.1 -C.sub.4 alkoxyethoxyethyl, in a weight ratio of (B)/(A) of from 0.1 to 5.
    Type: Grant
    Filed: February 12, 1991
    Date of Patent: May 19, 1992
    Assignee: Hoechst Mitsubishi Kasei Co., Ltd.
    Inventors: Riyouichi Sekioka, Kouichi Seto