Patents Assigned to Huntsman International LLC
  • Patent number: 11926727
    Abstract: A composition comprising (a) a cationically polymerisable epoxy resin, (b) an initiator for the cationic polymerisation, (c) a microparticle filler, and (d) a nanoparticle filler can be used for the production of thermally stable insulating material for electrical and electronic components.
    Type: Grant
    Filed: December 21, 2021
    Date of Patent: March 12, 2024
    Assignee: HUNTSMAN INTERNATIONAL LLC
    Inventors: Christian Beisele, Werner Hollstein, Andreas Riegger
  • Patent number: 11827784
    Abstract: Functionalized polyacrylate polymer compositions for treating clay or clay bearing aggregates compositions are disclosed. Also disclosed are methods for preparing the functionalized polyacrylate polymer compositions, admixtures containing such polymers and methods for the mitigation of clays in cementitious and aggregate compositions using these polymers.
    Type: Grant
    Filed: October 27, 2017
    Date of Patent: November 28, 2023
    Assignee: Huntsman International LLC
    Inventors: Antonius Wibowo, Ben Wambacq, Xiaohua Fang, Haibo Zhao
  • Patent number: 11814539
    Abstract: A cross-linkable powder for use in a selective laser sintering (SLS) process for additive manufacturing is disclosed as well as a novel manufacturing process to form a 3D object using said cross-linkable powder. The manufacturing process makes it possible to create interlayer covalent bondings between deposited layers of cross-linkable powder such that 3D printed objects are achieved having improved mechanical strength, less object deformation and/or no warping.
    Type: Grant
    Filed: December 19, 2019
    Date of Patent: November 14, 2023
    Assignee: HUNTSMAN INTERNATIONAL LLC
    Inventors: Hugo Verbeke, Bram Vanroy, David Briers
  • Patent number: 11649315
    Abstract: A polyurethane insulation foam composition is disclosed herein. The polyurethane insulation foam comprises: (i) an isocyanate compound; (ii) an isocyanate reactive compound; (iii) water; (iv) a tertiary amine compound; (v) a hydrophilic carboxylic acid compound; (vi) a halogenated olefin compound; and (vii) optionally, other additives.
    Type: Grant
    Filed: September 12, 2018
    Date of Patent: May 16, 2023
    Assignee: HUNTSMAN INTERNATIONAL LLC
    Inventors: Sachchida N. Singh, Lifeng Wu, Khang Nguyen
  • Publication number: 20230057382
    Abstract: The present invention relates to silyl terminated polyurethanes and to intermediates for the preparation thereof. In particular to an allyl-monool-containing initiator, allyl-terminated polyurethane prepolymer and to processes for their preparation. According to another of its aspect, the invention relates to a product obtainable by curing the silyl terminated polyurethane of the invention and to uses thereof.
    Type: Application
    Filed: December 17, 2020
    Publication date: February 23, 2023
    Applicant: Huntsman International LLC
    Inventors: Ya-Mi Chuang, Giulio Martini, Christopher Phanopoulos
  • Publication number: 20230043804
    Abstract: A reactive mixture comprising a Fire, Smoke and Toxicity retardant (FST) composition for making a polyisocyanurate and/or polyurethane (PIR/PUR) comprising material, said FST composition comprising: a) at least one compound having at least one ethylenically unsaturated moiety having a number average equivalent weight<160 g/mol, and b) optionally one or more radical initiator compound characterized in that the onset temperature for radical polymerization (Tonset) of the ethylenically unsaturated compound with or without the radical initiator is 2° C. up to 40° C. lower than the maximum reaction temperature achieved during the process for making the PIR/PUR material (reaction exotherm (Treaction)).
    Type: Application
    Filed: December 22, 2020
    Publication date: February 9, 2023
    Applicant: Huntsman International LLC
    Inventors: Rene Alexander Klein, Nima Esmaeili, Nadja Kathrin Richter, Rajesh Kumar Gajendran, Xiaodong Guo, Thomas Julien Joncheray, Jan Vandenbroeck
  • Publication number: 20230021509
    Abstract: A polyisocyanurate and/or polyurethane (PIR/PUR) comprising material having improved Flame, Smoke and/or Toxicity (FST) retardancy is disclosed and a method for forming said PIR/PUR comprising material. The PIR/PUR material is comprising at least 0.2 wt % of compounds having a number average equivalent weight <160 g/mol and at least one non-polymerized ethylenically unsaturated moiety based on the total weight of the PIR/PUR comprising material, and optionally 0.01 wt % up to 1 wt % of one or more radical initiator compounds based on the total weight of the PIR/PUR comprising material.
    Type: Application
    Filed: December 22, 2020
    Publication date: January 26, 2023
    Applicant: Huntsman International LLC
    Inventors: Rene Alexander Klein, Nima Esmaeili, Nadja Kathrin Richter, Rajesh Kumar Gajendran, Xiaodong GUO, Thomas Julien Joncheray, Jan Vandenbroeck
  • Patent number: 11555091
    Abstract: This invention generally provides composition for making a polyurethane foam with reduced aldehyde emission and more specially to composition useful in means of transport such as interior part of cars, wherein composition is comprising: (a) a polyfunctional isocyanate; (b) an isocyanate reactive composition; and (c) a compound of the formula (I) or (II), wherein the compound (c) is present by weight percentage in the composition in an amount ranging from about 0.001 to about 10, preferably from about 0.01 to about 5, and more preferably from about 0.05 to about 2 based on the total weight of the composition. The compositions can reduce aldehyde emission, especially acetaldehyde emission in the PU foam and has no obvious influence on the mechanic properties of the foam.
    Type: Grant
    Filed: December 13, 2018
    Date of Patent: January 17, 2023
    Assignee: Huntsman International LLC
    Inventors: Pengfei Wu, Lies Bonami, Yuefan Zhang, Joris Karel Peter Bosman, Xuerong Zhu, Ingrid Welvaert
  • Patent number: 11548973
    Abstract: A trimerization catalyst composition suitable for making a polyisocyanurate comprising (insulation) foam, said composition comprising at least a trimerization catalyst compound selected from one or more organic salts from alkoxides wherein said organic salt is selected from alkali metal, earth alkali metal, a transition metal such as Ti and/or quaternary ammonium organic salts.
    Type: Grant
    Filed: March 31, 2015
    Date of Patent: January 10, 2023
    Assignee: Huntsman International LLC
    Inventors: Hugo Verbeke, Anja Anneke Vanhalle
  • Patent number: 11548997
    Abstract: The invention is related to a method for reducing the emission of acetaldehyde and/or propionaldehyde from a polyurethane or polyurea foam, by using a reaction mixture comprising at least one isocyanate reactive component selected from the group consisting of a polyether polyol, a polyester polyol, a polyether polyamine and a polyester polyamine; an isocyanate component; and cyanoacetamide.
    Type: Grant
    Filed: February 6, 2017
    Date of Patent: January 10, 2023
    Assignee: Huntsman International LLC
    Inventors: Ingrid Welvaet, Geert Lodewijk Dries, Joris Karel Peter Bosman
  • Patent number: 11530188
    Abstract: A catalyst composition comprising at least a catalyst compound selected from multi metal cyanide compounds for the selective production of oxazolidinone compounds by reacting an isocyanate compound with an epoxide compound and oxazolidinone comprising materials obtained using said catalyst compound.
    Type: Grant
    Filed: October 10, 2018
    Date of Patent: December 20, 2022
    Assignee: Huntsman International LLC
    Inventors: Hugo Verbeke, Elisabeth Els Mercier, Lies Bonami, Peter Karel Joris Bosman, Giacomo Giannini
  • Patent number: 11505639
    Abstract: This invention generally provides blocked isocyanate compositions and more specially blocked isocyanate compositions useful in aminoplastic resins, phenoplastic resins or latex resins for composite wood products, wherein the blocked isocyanate composition is obtained by adding alkylene carbonate to a blocked isocyanate (A), wherein the blocked isocyanate (A) is obtained by reacting a secondary amine (a1) with a reaction product (a2) of a polyfunctional isocyanate and a monofunctional hydroxyl containing compound, wherein the monofunctional hydroxyl containing compound is a polyethylene oxide polymer with terminal hydroxyl group, polyoxyethylene-polyoxypropylene monols or a mixture thereof, wherein the portion of blocked isocyanate (A) by weight percentage of the blocked isocyanate composition is between 50 and 90, preferably between 60 and 80. The compositions are stable at room temperature when mixed with active hydrogen containing compounds.
    Type: Grant
    Filed: May 31, 2017
    Date of Patent: November 22, 2022
    Assignee: Huntsman International LLC
    Inventors: Graig Gordon Lovel, David McDaid, Travis Scott McCallum, Shan Li Sheng, Cheng-Dar Liu
  • Publication number: 20220363858
    Abstract: A reactive mixture and method for making a thermoplastic polyurethane (TPU) flexible foam having a predominantly open-cell structure (open-cell content of ?50% by volume calculated on the total volume of the foam and measured according to ASTM D6226-10) and an apparent density below 200 kg/m3.
    Type: Application
    Filed: November 9, 2020
    Publication date: November 17, 2022
    Applicant: Huntsman International LLC
    Inventors: Jan Vandenbroeck, Steve Andre Woutters, Rajesh Kumar Gajendran, Martino Dossi, Rene Alexander Klein, Mark Joseph Brennan
  • Patent number: 11434311
    Abstract: A process for providing one or more thermoset polymeric materials onto an object is disclosed wherein said process comprises at least the following steps: Providing a polymeric composition having a viscosity >10 Pa.s at room temperature comprising at least one cross-linkable polymeric material; and then Optionally heating the polymeric composition to achieve a liquid cross-linkable polymeric composition having a viscosity below 4 Pa.
    Type: Grant
    Filed: January 4, 2017
    Date of Patent: September 6, 2022
    Assignee: HUNTSMAN INTERNATIONAL LLC
    Inventors: Giacomo Giannini, Johan Van Dyck, Kevin Van Looy, Hugo Verbeke
  • Patent number: 11434328
    Abstract: The invention is related to a method for preparing polyether polyols, wherein the method comprises the steps of: a) providing a crude polyether polyols and a base catalyst; b) mixing the crude polyether polyols mixture with an acid thereby providing a neutralized polyether polyols mixture; c) removing water from the neutralized polyether polyols mixture, thereby providing a dehydrated neutralized polyether polyols mixture comprising polyether polyols and a suspension of the crystallized salts suspended in the polyether polyols; d) separating the polyether polyols from the crystallized salt by filtration resulting in a filtration cake comprising crystallized salts and remaining polyether polyols around the crystals; e) removing polyether polyols from the filter, leaving a filtration cake; f) redissolving the filtration cake obtaining a mixture of a salt solution and the remaining polyether polyols; and separating and removing the remaining polyether polyols from the salt solution.
    Type: Grant
    Filed: January 18, 2018
    Date of Patent: September 6, 2022
    Assignee: HUNTSMAN INTERNATIONAL LLC
    Inventors: Paul Anton Termorshuizen, Hector Cantero
  • Patent number: 11434344
    Abstract: A (super)hydrophobic isocyanate based organic aerogel/xerogel/cryogel having a water contact angle of at least 90° comprising: a cross-linked porous network structure made of polyurethane and/or polyisocyanurate and/or polyurea, and hydrophobic compounds having before the gelling step at least one isocyanate-reactive group and no isocyanate groups Characterized in that said hydrophobic compounds are covalently bonded within the porous network of the aerogel/xerogel/cryogel and wherein said bondings are created during the gelling step of the formation of the isocyanate based organic aerogel/xerogel/cryogel cross-linked porous network structure.
    Type: Grant
    Filed: October 12, 2016
    Date of Patent: September 6, 2022
    Assignee: HUNTSMAN INTERNATIONAL LLC
    Inventors: Thomas Julien Joncheray, Jan Vandenbroeck, Gilles Jean Geumez
  • Patent number: 11434320
    Abstract: Polyisocyanurate (PIR) and/or polyurethane (PUR) comprising insulation foams having significantly improved long term insulation values are disclosed as well as a processing method to fabricate said improved insulation foams and use of the improved insulation foams for thermal insulation.
    Type: Grant
    Filed: April 30, 2019
    Date of Patent: September 6, 2022
    Assignee: HUNTSMAN INTERNATIONAL LLC
    Inventors: Thomas Julien Joncheray, Jan Vandenbroeck, Linda Carillo, Kristof Dedecker, Gilles Jean Geumez
  • Patent number: 11407912
    Abstract: The present invention relates to a colorant mixture comprising (A) at least one blue- or black-dyeing disperse dye of formula wherein R1 denotes hydrogen or halogen, R2 and R3 are each independently of the other hydrogen; C1-C8-alkyl which is unsubstituted or substituted with hydroxy, cyano, C1-C4alkoxy or halogen; —(CH2)n—O—(CH2)mR4, wherein R4 denotes hydrogen or C1-C8-alkyl, n is a number from 2 to 6 and m is a number from 0 to 6; C5-C24aryl which is unsubstituted or substituted with hydroxy, carboxy, cyano, C1-C8alkyl, C1-C4alkoxy or halogen; or C6-C30aralkyl which is unsubstituted or substituted with hydroxy, cyano, C1-C4alkyl, C1-C8alkoxy groups or halogen; and (B) at least one yellow-, orange- or red-dyeing disperse dye, solvent dye, vat dye or pigment; and to the use thereof in dyeing or printing cellulose or cellulose blend fibre materials.
    Type: Grant
    Filed: March 1, 2018
    Date of Patent: August 9, 2022
    Assignee: Huntsman International LLC
    Inventors: Veronique Hall-Goulle, Luc Nueffer, Damien Schoehn, Olivier Brack, Willem Van Daal, Siro Dalle Nogare, Kurt Plattner
  • Patent number: 11389820
    Abstract: Method of designing and manufacturing a distributor bar for use in a production line comprising a mixing head for providing a viscous foamable liquid mixture, a laminator with a predefined speed of at least 20 m/min, the distributor bar having a central inlet fluidly connected to a number of outlets via a main channel. The method comprises: choosing (3001) a geometry for the distributor bar and defining a set of geometrical parameters; assigning (3002) values to said parameters; creating (3003) a virtual model; simulating (3005) flow in said model by performing a Computational Fluid Dynamics simulation (CFD), taking into account (3004) a non-Newtonian shear thinning model; e) evaluating the simulated flow; building (2007) a physical distributor bar. A distributor bar, a production line, and a computer program product.
    Type: Grant
    Filed: May 6, 2019
    Date of Patent: July 19, 2022
    Assignee: HUNTSMAN INTERNATIONAL LLC
    Inventor: Mark Joseph Brennan
  • Patent number: 11325326
    Abstract: A process for the preparation of a fiber reinforced composite article that facilitates manufacturing of composite articles with reduced cycle times, said composite articles exhibiting high fibre content, low void content and excellent visual and mechanical properties, and capable of use for the construction of mass transportation vehicles, in particular, in the automotive and aerospace industries.
    Type: Grant
    Filed: February 4, 2016
    Date of Patent: May 10, 2022
    Assignee: Huntsman International LLC
    Inventors: Duncan Howland, Stephan Costantino, Klaus Ritter, Guillaume Dirrig