Abstract: A process for producing an omega-functionalized aliphatic carboxylic acid starting from cyclohexanone and omega-functionalized .alpha.-olefins or acrylic esters. The process comprises an addition step, an oxidation step, an isomerization step, and one or more hydrogenation steps. The process allows to use raw materials that are available at low cost and to achieve high selectivity and high yield with industrially simple steps. The process includes the production of new intermediate products, including 2-oxepanone-7-substituted products.
Type:
Grant
Filed:
April 18, 1996
Date of Patent:
June 29, 1999
Assignee:
Industrie Chimiche Caffaro S.P.A.
Inventors:
Livius Cotarca, Paolo Maggioni, Alfonso Nardelli, Stefano Sguassero
Abstract: A process for producing coumarin and substituted coumarins starting from substituted hexahydrocoumarins or from substituted dihydrocoumarins. The process includes dehydrogenation in the presence of catalysts based on metals of Group VIII of the periodic table of the elements and in the presence of at least one easily reducible organic compound. The invention allows to achieve exceptionally high yields that do not require the recycling of the hexahydrocoumarin or of the dihydrocoumarin that are present at the end of the reaction, and also allows to achieve high selectivity and easy purification.
Type:
Grant
Filed:
March 17, 1997
Date of Patent:
February 16, 1999
Assignee:
Industrie Chimiche Caffaro S.P.A.
Inventors:
Stefano Alini, Livius Cotarca, Pietro Delogu
Abstract: A process for producing an omega-functionalized aliphatic carboxylic acid starting from cyclohexanone and omega-functionalized .alpha.-olefins. The process comprises an addition step, an oxidation step, an isomerization step, one or more hydrogenation steps and hydrolysis. The process allows to use raw materials that are available at low cost and to achieve high selectivity and high yield with industrially simple steps. The process includes the production of new intermediate products.
Type:
Grant
Filed:
April 16, 1996
Date of Patent:
February 16, 1999
Assignee:
Industrie Chimiche Caffaro, S.p.A.
Inventors:
Livius Cotarca, Paolo Maggioni, Alfonso Nardelli
Abstract: Process for making paper and cardboard, wherein at least one nitrate or basic nitrate of a trivalent metal is used as sizing agent, so that the process wastewater, after a biological denitrification treatment, can be discharged into the environment without causing pollution problems and/or can be reused at least partially as fresh water, with great savings in consumption.
Abstract: The present invention relates to a process for producing lactones starting from cyclic ketones which comprises an oxidation reaction which is performed in the presence of an optionally substituted cycloaliphatic peracid or of an optionally substituted aliphatic peracid that is immiscible with water. The process allows to obtain high selectivity, does not entail the use of dangerous reagents, and allows excellent economic advantages.