Abstract: The present invention provides a method for improving an identification degree of low-luminosity dispersed-phase particles in a multiphase system. The method comprises: adding additive particles into a multiphase system containing low-luminosity dispersed-phase particles before photographing the multiphase system to obtain an image including the low-luminosity dispersed-phase particles, wherein the refractivity of the additive particles is greater than that of the low-luminosity dispersed-phase particles.

Abstract: Disclosed are an activated carbon adsorption tower and a gas purification device. An activated carbon adsorption tower comprises an adsorption tower body (1), a gas inlet (2) and a gas outlet (3) arranged on the adsorption tower body (1); the adsorption tower body (1) is provided with an activated carbon passage (11), a swash plate (12) and a gas passage in communication with the gas inlet (2) and the gas outlet (3); the gas passage is separated by the swash plate (12) into a U shape or serpentine shape, making the gas passage pass through the same activated carbon passage (11) from the opposite direction at least once; and the activated carbon passage (11) is provided with flowing activated carbon inside and gas holes on the passage wall for communicating with the gas passages on both sides.

Abstract: A nickel lithium ion battery positive electrode material having a concentration gradient, and a preparation method therefor. The material is a core-shell material having a concentration gradient, the core material is a material having a high content of nickel, and the shell material is a ternary material having a low content of nickel. The method comprises: synthesizing a material precursor having a high content of nickel by means of co-precipitation, co-precipitating a ternary material solution having a low content of nickel outside the material precursor having a high content of nickel, aging, washing, and drying to form a composite precursor in which the low nickel material coats the high nickel material, adding a lithium source, grinding, mixing, calcining, and cooling to prepare a high nickel lithium ion battery positive electrode material.

Abstract: The present disclosure provides a fluorescent nanomaterial and a preparation method and applications thereof, and the preparation method comprises: subjecting amphiphilic molecules in a solvent system to an illumination treatment and/or a heat treatment to obtain fluorescent nanomaterials. The preparation of fluorescent nanomaterials provided by the present disclosure is simple in process, simple and easily available in raw materials and requires neither additional addition of a strong acid, a strong alkali, a passivating agent and the like, nor high temperature and high pressure in the preparation process. The whole process is environmentally friendly and pollution-free and the products can be used in various fields.

Abstract: An internal loop airlift reactor (ILAR) for process intensification integrating reaction and separation includes a riser, a downcomer, a hydrocyclone, internals preventing occurrence of dead zone, a gas guide cone, vent holes, and a gas-liquid integrated distributor. The hydrocyclone is arranged at the bottom of the ILAR downcomer; the gas guide cone and the vent holes in the downcomer prevent the gas from entering the hydrocyclone; after the slurry enters the hydrocyclone, the solid-containing slurry enters the riser again from the hydrocyclone underflow, and the solid-free clean product flows out through the hydrocyclone overflow. The ILAR in the present invention has a simple structure and low cost and requires no special liquid-solid separation device. It can achieve gas-liquid-solid three-phase reaction, interphase mass transfer, and solid-liquid separation simultaneously, and is suitable for a gas-liquid-solid three-phase reaction in which the catalyst is solid particles.

Abstract: An internal loop airlift reactor (ILAR) for process intensification integrating reaction and separation includes a riser, a downcomer, a hydrocyclone, internals preventing occurrence of dead zone, a gas guide cone, vent holes, and a gas-liquid integrated distributor. The hydrocyclone is arranged at the bottom of the ILAR downcomer; the gas guide cone and the vent holes in the downcomer prevent the gas from entering the hydrocyclone; after the slurry enters the hydrocyclone, the solid-containing slurry enters the riser again from the hydrocyclone underflow, and the solid-free clean product flows out through the hydrocyclone overflow. The ILAR in the present invention has a simple structure and low cost and requires no special liquid-solid separation device. It can achieve gas-liquid-solid three-phase reaction, interphase mass transfer, and solid-liquid separation simultaneously, and is suitable for a gas-liquid-solid three-phase reaction in which the catalyst is solid particles.

Abstract: The present invention relates to a method for converting and separating vanadium, titanium, and iron from the vanadium-titanium-iron concentrate in one step, which includes the steps as below. (1) The vanadium-titanium-iron concentrate is mixed and roasted together with addition agent and reducing agent, and thereby vanadium-containing pig iron and vanadium enriched slag are obtained. (2) The vanadium titanium enriched slag is leached in water and filtered, and thereby vanadium-containing solution and titanium slag are obtained. The technical features of the present invention are as below. By the new process of sodium reduction coupling, a new system of low-temperature smelting multiphase reaction separation is constructed. The reduction of iron, sodiumizing of vanadium, and the melting separation process of the vanadium titanium enriched slag and the iron are achieved in one step. Three products, i.e., the vanadium-containing pig iron, the vanadium-containing solution, and the titanium slag are produced.

Abstract: The present invention provides a system and method for purifying vanadium pentoxide. Industrial grade vanadium pentoxide is converted to vanadium oxytrichloride by low temperature fluidizing chlorination, wherein chlorinating gas is preheated via heat exchange between fluidizing gas and chlorination flue gas, and an appropriate amount of air is added to enable a part of carbon powder to combust so as to achieve a balanced heat supply during the chlorination, thereby increasing the efficiency of chlorination and ensuring good selectivity in low temperature chlorination. The vanadium oxytrichloride is purified by rectification, and then subjected to plasma oxidation, thereby obtaining a high-purity vanadium pentoxide product and chlorine gas. The chlorine gas is returned for low temperature chlorination.

Abstract: The present invention provides an online measuring method of particle (such as bubbles, droplets and solid particles) velocity in multiphase reactor. The method based on an online multiphase measuring instrument includes the following steps: (1) the online multiphase measuring instrument is placed into the multiphase reactor, and then a particle image produced by two or more exposures are obtained; (2) the actual size of individual pixel in the particle image is determined; (3) valid particles are determined in the depth of field; (4) then the centroid coordinates are conversed to the actual length of the coordinates (xt,i, yt,i) and (xt+?t,i, yt+?t,i) using the actual size of individual pixel. Thus, the instantaneous velocity of particles can be calculated by V i = ( x t + ? ? ? t , i - x t , i ) 2 + ( y t + ? ? ? t , i - y t , i ) 2 ? ? ? t .

Abstract: A composite-coated lithium iron phosphate in a three-dimensional nanonetwork layered structure and a preparation method therefor, and a lithium ion battery, wherein a composite is prepared by compounding a conducting polymer, graphene and a carbon nano tube. The preparation method for the coated lithium iron phosphate comprises the following steps: doping the composite and anhydrous ferric phosphate in situ in the process of preparing the anhydrous ferric phosphate, serving as a lithium iron phosphate precursor, then mixing the composite in-situ doped anhydrous ferric phosphate, a lithium source, a traditional carbon material and a solvent to obtain slurry, spray drying the slurry, and calcining to obtain the composite-coated lithium iron phosphate in a three-dimensional nanonetwork layered structure. The preparation method is simple and has a wide raw material source, low cost and very broad practical application prospect.

Abstract: The present invention provides a vaccine formulation, a preparation method therefor and a use thereof. The vaccine formulation comprises a vaccine carrier and an antigen component, wherein the vaccine carrier is obtained by hydrothermal transformation of microorganisms. The vaccine formulation of the present invention is obtained by compounding the vaccine carrier obtained by hydrothermal transformation of microorganisms with the antigen component.

Abstract: A system for fluidized bed reduction of powdered iron ore. Use of high-gas-velocity processing accelerates iron ore reduction speed and greatly improves the gas-treatment capabilities of a unit-cross-sectional fluidized bed. Use of parallel connections involving reduced coal gas lessens the volume of gas passing through a single-stage fluidized bed. Use of serial/parallel-connection processing involving reduced coal gas increases the coal gas utilization rate. The invention achieves the highly-effective reduction of powdered iron ore in a fluidized bed under near-atmospheric pressure. A reduction method based on the present system is also disclosed.

Abstract: An online multiphase measuring method of concentration and diameter distribution of dispersed phase particles in a multiphase reactor is provided in the present invention. The method is based on an online multiphase measuring instrument. The method described herein includes the following steps: (1) the online multiphase measuring instrument is placed in a multiphase system, and an image of the particles in the multiphase system is obtained; (2) valid particles are determined as: the particle that its Grad(?) is greater than or equal to Grad(?l/2) is labeled as a valid one; (3) the particle diameter is calculated by di=10×ni/N10; according to the equation ? = V c V = ? i n ? 1 6 ? ? ? ? d i 3 S × l , the concentration of the valid particles is calculated. The concentration and diameter of bubbles, droplets or solid particles can be obtained in real time and online measurement. The accuracy of this method is high.

Abstract: A system and method for fluidized reduction of iron ore powder. Use of oxidation increases the iron ore reduction rate. Use of high-gas-velocity processing accelerates iron ore reduction speed and greatly improves the gas-treatment capabilities of a unit-cross-sectional fluidized bed. Use of parallel-connections involving reduced coal gas lessens the volume of gas passing through a single-stage fluidized bed. The invention achieves the highly-effective reduction of iron ore powder in a fluidized bed under near-atmospheric pressure.

Abstract: A system and method for producing a 3.5-valence high-purity vanadium electrolyte, comprising hydrolyzing high-purity vanadium oxytrichloride into vanadium pentoxide in a fluidized bed, and reducing vanadium pentoxide into a low-valence vanadium oxide having an average vanadium valence of 3.5 adding water and a sulfuric acid solution under a microwave field applied externally for dissolution at a low temperature, to obtain a 3.5-valence high-purity vanadium electrolyte. The preparation of vanadium pentoxide by means of gas-phase hydrolysis in the fluidized bed is of short process and high efficiency. By providing an internal member within the reduction fluidized bed, the precise regulation of the valence state of the reduction product is achieved, and the special chemical effect of the microwave field is used to promote dissolution of the vanadium oxide and activate the vanadium ions, thereby greatly improving the activity of the electrolyte.

Abstract: A system and method for producing a high-purity and high-activity vanadium electrolyte, comprising converting high-purity vanadium oxytrichloride into an ammonium salt in a fluidized bed by gas phase ammoniation, then in another fluidized bed, reducing the ammonium salt into a low-valence vanadium oxide having an average vanadium valence of 3.5, adding clean water and sulfuric acid for dissolution, and further performing activation by ultrasound to obtain a 3.5-valence vanadium electrolyte which can be directly used in a new all-vanadium redox flow battery stack. The method of producing an ammonium salt containing vanadium in the fluidized bed by gas phase ammoniation is of short process and high efficiency. Precise regulation of the valence state of the reduction product is implemented by arranging an internal member in the reduction fluidized bed, and ultrasonication is used to activate the vanadium ion, thereby greatly improving the activity of the electrolyte.

Abstract: A system and method for preparing a high-purity vanadium electrolyte, comprising preparing a low-valence vanadium oxide with vanadium oxytrichloride by ammonium salt precipitation and fluidization reduction, and preparing the high-purity vanadium electrolyte at a low temperature by adding a sulfuric acid solution and clean water under the conditions of ultrasound-assisted dissolution and activation. Efficient utilization of heat is achieved through heat exchange between the ammonium salt and the reduction tail gas and heat exchange between the reduction product and fluidized nitrogen gas. Ammonia gas in the reduction tail gas is recovered for precipitation of vanadium to achieve the recycling of ammonia gas. An internal member is arranged in the reduction fluidized bed to realize the precise regulation of the valence state of the reduction product.

Abstract: A system and method for preparing a vanadium battery high-purity electrolyte, comprising preparing a low-valence vanadium oxide with a valence of 3.5 with liquid phase hydrolysis and fluidization reduction with vanadium oxytrichioride, adding clean water and sulfuric acid for dissolution, and further performing ultraviolet activation to obtain the vanadium electrolyte, for use in an all-vanadium redox flow battery stack. The high-temperature tail gas in the reduction fluidized bed is combusted for preheating the vanadium powder material, to recover the sensible heat and latent heat of the high-temperature tail gas, and the sensible heat of the reduction product is recovered through heat transfer between the reduction product and the fluidized nitrogen gas. An internal member is arranged in the reduction fluidized bed to realize the precise regulation of the valence state of the reduction product, and ultraviolet is used to activate the vanadium ions, improving the activity of the electrolyte.

Abstract: A system and method for preparing a high-activity specific-valence electrolyte of an all-vanadium redox flow battery. A vanadium-containing material is reduced into a low-valence vanadium oxide with an average valence in the range of 3.0-4.5 through precise control of fluidization, then water and sulfuric acid are added for dissolution, and microwave field is further adopted for activation, so as to obtain a specific-valence vanadium electrolyte. Efficient utilization of heat is achieved through heat exchange between the vanadium-containing material and reduction tail gas and heat exchange between the reduction product and fluidized nitrogen gas. An internal member and feed outlets at different heights are arranged in a reduction fluidized bed to achieve precise control over the valence state of the reduction product, and the special chemical effect of the microwave field is used to activate the vanadium ions, thereby improving the activity of the electrolyte greatly.

Abstract: The present invention provides carbon quantum dots, preparation method and uses thereof. The preparation method of the carbon quantum dots comprises the following steps: (1) preparing a dispersion of carbon based material; (2) mixing a solution of halogenated quinone with the dispersion of carbon based material and preparing a dispersion of carbon based-halogenated quinone composite material by halogenated quinone grafting method; (3) adding a solution of H2O2 to the dispersion of carbon based-halogenated quinone composite material and carrying out reaction thereof, obtaining reaction products; (4) carrying out solid-liquid separation to the reaction products, with the resulting filtrate continuing to react, thus obtaining a dispersion of carbon quantum dots. This method adopts metal-free catalytic oxidation, the process of which is safe, convenient and low-cost, and is performed under a mild reaction condition without adding additional substances which are difficult to be separated.