Abstract: An improved catalyst for hydrodemetallization of heavy crude oils and residua is disclosed. The catalyst is adopted for fixed bed hydroprocessing units. The invention is characterized for having a large pore diameter catalyst principally for hydrodemetallization of heavy oil and residue in a first reactor of a multi-reactor process. The catalyst has high demetallizing activity and high metal deposition capacity which results in good stability with time on stream (TOS). The hydrorefining catalyst is obtained by kneading a porous starting powder principally composed of gamma-alumina and having a pore capacity of 0.3-0.6 ml/g or larger and a mean pore diameter of 10 to 26 nm, extrudating and calcining, and after that supported with active metals component of elements belonging to groups VIIIB and VIB of the periodic table.

Abstract: A hydrocracking catalyst having a support of a composite of mesoporous materials, molecular sieves and alumina, is used in the last bed of a multi-bed system for treating heavy crude oils and residues and is designed to increase the production of intermediate distillates having boiling points in a temperature range of 204° C. to 538° C., decrease the production of the heavy fraction (>538° C.), and increase the production of gasoline fraction (<204° C.). The feedstock to be processed in the last bed contains low amounts of metals and is lighter than the feedstock that is fed to the first catalytic bed.

Abstract: The present disclosure covers the use of polymers or copolymers having a naphthalene-type unit in their structure as heterogeneous hydrogen transfer agents for hydrogenation, hydrotreatment or reduction reactions. These heterogeneous hydrogen transfer agents may or may not be supported on metallic oxides and may be used in the presence of reducing agents such as hydrogen or methane. These hydrogen donors, being solid at the reaction temperature, may be recovered from the reaction mixture and reused, and are thermally and chemically stable at temperatures up to above 450° C.

Abstract: Ionic liquids of the general formula C+A? where C+ represents an organic cation, specifically, but not limited to the imidazolium, pyridinium, isoquinolinium, ammonium types, which have aliphatic and aromatic substituents, while A? represents a carboxylate, aromatic and aliphatic anion. The ionic liquids are synthesized under conventional heating or microwave irradiation This invention is also related to the application of ionic liquids to remove sulfur compounds of naphthas through a liquid-liquid extraction and the recovery and reuse of ionic liquids by the application of heat, reduced pressure and washing with solvents.

Abstract: The present invention relates an Integral analysis method of inter-well tracer tests, which integrates and performs continuous feedback to each of the major stage (design, operation and interpretation) allowing quantitative interpretation of these tests. It is presented as a tool to investigate the behavior of injection fluids for recovery of hydrocarbons, as well as for the dynamic characterization of reservoirs. The main advantage of this invention is that it allows a greater certainty in the tracer response and a marked improvement in the sensitivity and quantitative analysis of the test results, since the curves fit both with mathematical models and numerical models. Another outstanding attraction of this invention is the reduction in the costs of testing such applications.

Abstract: The object of the present invention relates to a system for measuring the salinity of hydrocarbons at the bottom of an oil well, using the technique of time domain reflectometry (TDR). The system comprises an electromagnetic pulse generator, an oscilloscope for displaying and measuring the frequency, amplitude and wavelength of the signal, a signal amplifier, a computer for processing and storing the information, and a metal wire that functions as a waveguide To transmit the signal from the signal generator to the hydrocarbon to which its salinity is to be determined at the bottom of the well. The signal returns from the bottom of the well to the oscilloscope where the difference between the sent signal and the return signal is measured. This difference allows us to infer the salinity of the hydrocarbon.

Abstract: The present invention is related to the application of terpolymers based on alkyl acrylates as defoamers of gasified crude oils, with densities between 10 and 40° API. The evaluation of terpolymers based on alkyl acrylates at conditions similar to those of gas-liquid separators has shown that the terpolymers are efficient as inhibitors of the foam formation in heavy and super-heavy crude oil, abating the foam between 15 and 50% faster than in non-dosed crude oil (blank). Even some acrylic terpolymers exhibited a greater efficiency as defoamers than that of commercial silicon-based polymers, which promoting the defoaming only 20-25% faster than the blank collapse. The employ of silicones as defoamers presents serious problems as the formation of deposits and the deactivation of catalysts in the refining processes. This situation has provoked that refineries in Mexico and a worldwide ban the application of this kind of inorganic polymers, and new silicon-free defoaming agents are required.

Abstract: The invention relates to a method of preparing a catalytic composition comprising at least one non-noble metal from group VIII and at least one metal from group VIB of the periodic table. The invention also relates to the catalytic composition thus produced, which has a high specific activity in reactions involving the hydroprocessing of light and intermediate fractions, preferably in reactions involving the hydrotreatment of hydrocarbon streams, including hydrodesulphurisation (HDS), hydrodenitrogenation (HDN) and hydro-dearomatisation (HDA).

Abstract: The present invention relates to a process for obtaining materials with Metal Organic atomic structure and called MOF (MOF: Metal Organic Framework) type MIL-101 (Cr) and MIL-101-Cr-MX+ (MIL: Material from Institute Lavoisier), where MX+ can be any metal cation, such as Mg2+, Al3+ or Ti4+, using for its synthesis metal epoxides and alkoxides, avoiding the use of hydrofluoric acid (HF) or bases as synthesis controlling agents. The process of the present invention for the preparation of materials MOF MIL-101 (Cr) and MOF MIL-101-Cr-MX+ where MX+ can be any metal cation, such as Mg2+, Al3+ or Ti4+, consisting of: a) Synthesizing MOF MIL-101 (Cr) with epoxides, or Synthesizing MOF MIL-101-Cr-MX+ with metal alkoxides; and b) Purifying the synthesized MOF. in order to obtain 100% pure materials, with a controlled mesoporosity associated with a hysteresis P/P0 from 0.7 to 0.99, BET surface area from 2,500 to 3,500 m2/g, pore volume from 1.1 to 2.2 cm3/g, and pore diameter from 15 to 55 nm.

Abstract: A process for reducing sulfur, nitrogen, metals and asphaltene contents, while increasing the yield of distillable fractions in heavy hydrocarbons, by using a cooled light fraction as a liquid quench stream. The light fraction is obtained by splitting heavy hydrocarbons into a heavy fraction, and a light fraction which may be injected at spaced locations along a system of fixed-bed reactors series that comprises a first hydrodemetallization (HDM)/hydrodeasphaltenization (HDAs) step, followed by a second hydrodesulfurization (HDS)/hydrodenitrogenation (HDN)/hydrocracking step. The metal and asphaltene rich heavy fraction have contact with the entire catalyst system, while the light fraction is injected as side feed and quench stream(s) into the second reactor, where it is treated in admixture with the heavy fraction for elimination of the impurities of the light fraction.

Abstract: Density measurement of mixtures of heavy and light crudes using the vibrating tube densitometer technique determine incompatibility in the crudes mixture containing asphaltenes by determining the incipient point of asphaltenes incompatibility threshold in the mixtures of crudes.

Abstract: The present invention is related to formulations consisting by block copolymers ?,?-di-aryl or alkyl sulfonates of poly(ethylene oxide)w-poly(propylene oxide)-poly(ethylene oxide)w of bis-ammonium and block copolymers ?,?-di-amine of poly(ethylene oxide)w-poly(propylene oxide)-poly(ethylene oxide)w, that are effective in the dewatering and desalting crude whose specific gravities are within the range of 14 to 23° API.

Abstract: Compositions consisting of block copolymers ?,?-di-aryl or alkyl sulfonates of poly(ethylene oxide)w-poly(propylene oxide)-poly(ethylene oxide)w of bis-ammonium and block copolymers ?,?-di-amine of poly(ethylene oxide)w-poly(propylene oxide)-poly(ethylene oxide)w, are provided that are effective in the dewatering and desalting crude oils whose specific gravities are within the range of 14 to 20° API. A method of dewatering and desalting heavy crude oil adds a mixture of the copolymer bifunctionalized with an aliphatic or aromatic secondary amine and a copolymer bifunctionalized with an aliphatic or aromatic tertiary amine.

Abstract: The present invention relates to the application of polymeric resins and TiO2 doped with polymeric resins as coatings for external metal surfaces for industrial use, mainly by selecting the following metals: stainless steel, carbon steel and copper. Focuses specifically on the synthesis of a polymeric resin waterborne corrosion consisting of nano-structured polymer particles formed with two or more acrylic monomers, vinyl or styrenic a functionalizing agent and a crosslinking agent from 1.0 to 20% wt. each. Doping addition is made of the same polymeric resins, which are incorporated in nanotubes of titanium dioxide in concentrations ranging from 50 to 10,000 ppm. The polymeric resin is water based corrosion synthesized by emulsion polymerization techniques and is during the synthesis process is introduced nanotube loading of titanium dioxide (which are synthesized according to U.S. Pat. No. 7,645,439 B2), which allowing the dispersion in the polymer matrix.

Abstract: The present invention relates to a process for breaking of preferred, but not exclusive, oil-in-water emulsions (O/W) and water separation from crude oil emulsions using surfactants as demulsifying agents derived from natural or synthetic amino acids, which are water soluble. The surfactants are of the methanesulfonate series of glycine ester derivatives with hydrocarbon chains, preferably between C10 and C16, at a concentration between 450 and 900 ppm, at a temperature range of 30 to 60° C. The removal of water from the crude oil by using natural or synthetic amino acid-based demulsifiers is highly efficient (about 80%) and complemented with the action of an electric field typically used in electrostatic separators in crude oil terminals ad oil refineries, increasing the efficiency of water separation substantially, and enabling the production of dehydrated crude oil for further processing.

Abstract: The present invention relates to the synthesis of linear aromatic polyimides and the production of membranes for the separation of gases. Specifically, polyimides featuring in their chemical structure, in the part derived from a diamine, 4-fluoro-4?,4?-diaminotriphenylmethane, and an aromatic dianhydride derived from tetracarboxylic acid. Polyimides are soluble in amidic solvents such as N,N?-dimethylformamide, N,N?-dimethylacetamide, N-methyl-2-pyrrolidone, etc., which are processed as dense membranes by controlled evaporation of the solvent. The resulting membranes are capable of separating at least a gaseous mixture constituted by two components such as H2/CH4, He/N2, H2/CO2, O2/N2, CO2/CH4 and CO2/N2.

Abstract: The present invention is related to formulations including one or more block copolymers with low polydispersity and bifunctionalized with amines, and an ionic liquid. A method of demulsifying, dehydrating, and desalting crude oils having API gravity ranging between 8 to 30 admixes the formulation with the crude oil in an amount effective to demulsify, dehydrate and/or desalt the crude oils.

Abstract: Random terpolymers are characterized for being tolerant to high concentrations of divalent ions, such as calcium, magnesium, strontium and barium, and that for their application in the reservoir or production rig, treated water, sea water and/or connate water can be used as means of transportation. Furthermore, the terpolymer also can be used to inhibit and disperse mineral scales presents in cooling system and boiler employed in the chemical and oil industry. Also, random terpolymers of the present invention have the characteristic of complying with environmental standards established internationally and are classified as particularly non-toxic, so it can be used in pipes and equipment of the petrochemical industry and with the use characteristic freshwater and seawater from offshore and onshore facilities.

Abstract: A high powered current generator for electromagnetic inspection of hydrocarbon pipelines from an AC stabilized with rectangular waveform and whose measurements and interpretation are used for evaluating the condition of the lining of the pipelines of five main modules: self-programmable regulated voltage power source module; power source reference decoupling module; H Bridge inverter module; feedback module, and control and processing module. The generator was specifically designed as part of the instrumentation of (TIEMS); which supplies an electric current in the pipeline to produce electromagnetic radiation along the hydrocarbon pipeline. This energy is detected by antennas for obtaining the location of the pipeline and the electric current flowing therein. The generator produces an alternating current at a frequency that can be set within the range of 0.1 Hz to 1 KHz. However, to simplify the job of the operating personnel, default values of 0.1, 0.2, 0.

Abstract: The present invention is related to formulations including one or more block copolymers with low polydispersity and bifunctionalized with amines, and an ionic liquid. A method of demulsifying, dehydrating, and desalting crude oils having API gravity ranging between 8 to 30 admixes the formulation with the crude oil in an amount effective to demulsify, dehydrate and/or desalt the crude oils.