Abstract: The present invention relates to a surface sizing composition comprising a metal salt, wherein the metal has at least 3 valence electrons, and an aqueous polymer dispersion, wherein the aqueous polymer dispersion is an aqueous polymer dispersion (A) obtainable by free radical emulsion copolymerizing a first ethylenically unsaturated monomer blend comprising (a) 0 to 75% by weight of at least one optionally substituted styrene, (b) 15 to 100% by weight of at least one C1-C4-alkyl (meth)acrylate, and (c) 0 to 10% by weight of other ethylenically unsaturated copolymerizable monomers, wherein the sum (a)+(b)+(c) is 100%, in the presence of a water-soluble redox system comprising a first free radical initiator for the free radical emulsion copolymerization and an aqueous prepolymer composition (B) obtainable by free radical emulsion copolymerizing in a polymerization solvent comprising C1-6-carboxylic acid and C1-6-carboxylic acid anhydride, a second ethylenically unsaturated monomer blend comprising (i) 5 to 50%
Type:
Grant
Filed:
March 29, 2018
Date of Patent:
February 8, 2022
Assignee:
Kemira Oyj
Inventors:
Anneli Lepo, Tarja Turkki, Elsi Turunen
Abstract: A strength additive system for manufacturing paper, board, tissue or the like includes preferably as separate components, a cationic strength agent, such as a cationic polymer with aldehyde functional groups, and an anionic copolymer obtained by polymerization of a reaction mixture including (meth)acrylamide and anionic monomers, the standard viscosity of the obtained copolymer being in a range of 1.5-5.0 mPas. A method for manufacturing of a paper, board, tissue or the like is further disclosed.
Abstract: A coating structure for a sheet-like substrate, which includes lignocellulosic fibres is disclosed. The structure includes at least one pre-coat layer including at least 70 weight-% of a first styrene (meth)acrylate copolymer polymerised in the presence of a stabiliser, having a glass transition temperature Tg ?20° C. preferably ?10° C., ?30 weight-% of inorganic platy mineral particles and 0.01-2 weight-% of at least one first thickener. The coating structure further includes a top coat layer including at least 50 weight-% of a second styrene (meth)acrylate copolymer polymerised in the presence of a stabiliser having a glass transition temperature Tg ?20° C. preferably ?10° C., ?30 weight-% of inorganic mineral particles, 0.01-5 weight-% of at least one second thickener and 0.5-30 weight-% of an antiblocking agent. Further disclosed is a sheet-like product coated with the coating structure.
Abstract: The present embodiments generally relate to methods for the treatment of tailings, e.g., oil sands tailings, including methods comprising the use of one or more flocculants, one or more coagulants and one or more oxidants to treat said tailings and/or to improve the performance of said one or more flocculants.
Abstract: The present invention relates to a process for in situ the preparation of mixtures of chelating agents by catalyzed reactions of diethanolamine derivatives with maleic acid and then with 2-halocarboxylic acid, to mixtures of chelating agents and methods using such chelating agents.
Type:
Grant
Filed:
June 27, 2018
Date of Patent:
January 18, 2022
Assignee:
Kemira Oyj
Inventors:
Reijo Aksela, Jonas Konn, Anna-Maija Perander, Anna Haarala, Riitta Ilmoniemi, Hanna Hoffren
Abstract: A method is disclosed for monitoring and controlling treatment of a waste water stream. The method includes measuring UV absorbance of a waste water influent and/or waste water effluent, measuring turbidity of the waste water influent and/or waste water effluent, and determining the concentration of dissolved organics in the waste water influent and/or waste water effluent based on the measured UV absorbance. The method includes controlling the dosing of at least one coagulant to the waste water influent based on the measured UV absorbance and/or the determined concentration of the dissolved organics, and optionally based on the measured turbidity, and optionally controlling the dosing of at least one flocculant to the waste water influent based on the measured turbidity.
Type:
Application
Filed:
November 14, 2019
Publication date:
January 13, 2022
Applicant:
Kemira Oyj
Inventors:
Marjatta PIIRONEN, Sakari HALTTUNEN, Iiris JOENSUU, Anne MÄKI
Abstract: A method is disclosed for increasing strength properties, preferably burst strength and SCT strength, of a paper or board product. The paper or board product is manufactured from a fibrous web produced by a multilayer headbox, where an aqueous layer is formed between at least a first and a second fibre layer formed from fibrous stock suspension(s), and where feed water for the aqueous layer includes at least one cationic polymer. The method of the invention includes adding an anionic additive selected from a group comprising anionic synthetic organic polymers, anionic polysaccharides, and any of their combinations to the feed water before formation of the aqueous layer.
Type:
Grant
Filed:
June 13, 2018
Date of Patent:
January 4, 2022
Assignee:
Kemira Oyj
Inventors:
Mikko Virtanen, Kimmo Strengell, Juan Cecchini, Matti Hietaniemi
Abstract: A surface treatment composition is disclosed including anionic polyacrylamide, which has a weight average molecular weight, MW, in the range of 100 000-2 000 000 g/mol, and free glyoxal. Further disclosed is a use of the surface treatment composition, a method for producing paper, board or the like and a paper product.
Type:
Grant
Filed:
September 26, 2018
Date of Patent:
December 28, 2021
Assignee:
Kemira Oyj
Inventors:
Yuping Luo, Junhua Chen, Zheng Dang, Jennifer Riser
Abstract: Compositions for cleaning equipment, preferably paper or carpet making equipment, and methods of cleaning equipment, preferably paper or carpet making equipment using the said composition. The cleaning composition comprises of one or more fatty acid methyl esters, preferably vegetable oil methyl ester, more preferably soybean oil methyl ester, one or more alkene carbonate, preferably propylene carbonate; one of more surfactants, preferably nonionic surfactants; and one or more glycol ether and/or dibasic ester containing solvents.
Abstract: The invention relates to a method for producing paper, board or the like. The method comprises obtaining a fibre stock comprising lignocellulosic fibres and adding a retention agent system comprising a cationic synthetic polymer to the fibre stock and forming a fibrous web from the fibre stock and drying the web. Microfibrillated non-wood cellulose is added to the fibre stock as a component of the retention agent system and sequentially with the cationic synthetic polymer.
Type:
Grant
Filed:
March 29, 2018
Date of Patent:
November 2, 2021
Assignee:
Kemira Oyj
Inventors:
Tom Lundin, Kaisa Karisalmi, Heikki Sojakka
Abstract: The invention relates to use of a composition comprising a cationic surfactant, which comprises a primary or secondary ammonium head group and a linear unsubstituted C12-alkyl tail, for inducing germination of bacterial endospores in pulp suspension for making of paper, board or the like. The invention relates also to a method for quantitatively reducing bacterial endospores in pulp suspension for making of paper, board or the like. The method comprises obtaining of aqueous pulp suspension, and administering the said composition to the pulp suspension. The cationic surfactant is allowed to interact with bacterial endospores in the pulp suspension. Germination of endospores and destroying microorganisms is thus induced.
Abstract: The invention relates to a use of a water-soluble polymer product comprising amphoteric polyacrylamide, which has neutral or cationic net charge at pH 7, a weight-average molecular weight of 2 500 000-18 000 000 g/mol and a total ionicity of 4-28 mol-%. The polymer product is used for controlling deposit formation caused by hydrophobic substances in manufacture of paper or board, where a fibre web is formed from an aqueous suspension of fibres. The invention relates also to a method for controlling deposit formation caused by hydrophobic substances in manufacture of paper or board, where a fibre web is formed from an aqueous suspension of fibres, as well as to produced paper or board.
Type:
Application
Filed:
November 22, 2017
Publication date:
September 30, 2021
Applicant:
KEMIRA OYJ
Inventors:
Matti Hietaniemi, Asko Karppi, Maarit Latvanen, Elsa Olmos
Abstract: The present invention relates to a coagulant composition comprising a coagulant and a carbon source compound, wherein the coagulant is selected from the group iron and aluminium salts, or any combination thereof. The carbon source includes methanol, ethanol or glycol. The present invention further relates to a method of treating wastewater, e.g. containing nitrogen and/or phosphate, including providing the coagulant composition to wastewater before, during and/or after a biological treatment step, and the use of the coagulant composition in wastewater treatment.
Abstract: The invention relates to a method for producing paper, board or the like. The method comprises obtaining a thick stock comprising cellulose fibres, forming a fibrous web and drying of drying the fibrous web. A strength agent system, which comprises at least one synthetic or natural polymer, or their mixture, and microfibrillated parenchymal cellulose material originating from non-wood sources, is added to the thick stock. The invention relates also to paper or board produced by the method.
Type:
Grant
Filed:
July 16, 2020
Date of Patent:
September 28, 2021
Assignee:
Kemira Oyj
Inventors:
Kaisa Karisalmi, Tom Lundin, Mikko Virtanen, Antti Laukkanen, Jason McKee
Abstract: The invention relates to an arrangement for continuous production of polymer including a polymerisation reactor. The reactor includes a first pulley and a second pulley arranged at a distance from each other, which distance, defining a longitudinal first direction, and a flexible endless belt having a first edge section and a second edge section, which belt, is arranged to travel over the first pulley and the second pulley as a flat belt. The reactor further includes a supporting structure, which is arranged to support the flexible endless belt between the first pulley and the second pulley, whereby the supporting structure is arranged to form the flexible endless belt into a trough section by deviating the first edge section and the second edge section of the flexible endless belt away from the first direction. The trough section has a width-to-height ratio <1.2.
Abstract: A water-based barrier coating composition suitable for use as a barrier coating is disclosed which includes an aqueous polymer composition obtainable by free radical (co)polymerizing an ethylenically unsaturated monomer blend having an optionally substituted styrene, at least one C1-C4-alkyl (meth)acrylate, other ethylenically unsaturated copolymerizable monomers, degraded starch polyvinyl alcohol (PVA), a plasticizer; a composition having C16-C18 alkenyl ketene dimer, optionally as a mixture with rosin, of a gelling agent; and optionally a filler.
Abstract: A method for treating tailings substrate from mining or oil sands separation process, the tailings substrate comprising an aqueous phase with suspended solid particulate material. In the method, a flocculating agent is added to the tailings substrate, flocs are allowed to form and the formed flocs are separated from the aqueous phase. The flocculating agent comprises a degraded polyacrylamide comprising at least anionic units and having a process water viscosity reduced by 25-99%, preferably 50-99%, compared to a substantially similar polyacrylamide that has not been degraded by a degradation agent, measured at a shear rate 1 s?1 as a 0.4-0.8 weight-% solution of polymer in process water.
Type:
Grant
Filed:
August 10, 2020
Date of Patent:
September 7, 2021
Assignee:
KEMIRA OYJ
Inventors:
Thomas Fenderson, Miguel Pelaez, Igal Maasen, Yuping Luo
Abstract: A method for manufacturing a multi-layered fibrous web is disclosed, which includes at least two fibrous layers, where each layer is formed from one or more fibre stocks. The fibrous layers are combined prior to subjecting the multilayered fibrous web to wet-pressing and drying. At least one layer of the multi-layered fibrous web is formed from a fibre stock including at least 50 weight-% of a chemi-thermomechanical pulp (CTMP), a hardwood kraft pulp and/or a recycled fibre material calculated from a thick stock applied to a particular layer approach system. A first strength component and a second strength component are added to the fibre stock. The first strength component includes a cationic strength agent and the second strength component includes a synthetic amphoteric polymer composition having a net charge from ?3 to +1 meq/g (dry), at a pH of 7.
Type:
Application
Filed:
July 10, 2019
Publication date:
August 26, 2021
Applicant:
Kemira Oyj
Inventors:
Matti HIETANIEMI, Asko KARPPI, Jukka RAUTIAINEN
Abstract: The present invention relates to a process for treating pulp comprising a step, wherein the pulp is treated with distilled percarboxylic acid, such as distilled per-carboxylic acid (dPAA), and peroxide, such as hydrogen peroxide.
Type:
Grant
Filed:
June 27, 2017
Date of Patent:
July 27, 2021
Assignee:
KEMIRA OYJ
Inventors:
Leif Robertsén, Veli-Matti Vuorenpalo, Anna-Maija Perander, Pentti Pekonen, Jonas Konn
Abstract: A cationic glyoxylated polyacrylamide polymer composition having improved storage stability for use in manufacture of paper, board or the like, which aqueous composition includes a glyoxylated polyacrylamide polymer having a cationic charge density in a range of 0.8-1.8 meq/g of dry polymer in dry content of 5-15% and a buffering acid. The aqueous composition has pH in a range of 2.2-4.0 and a viscosity of less than 80 mPas measured at 25° C. by using a Brookfield viscometer after 30 days storage at 35° C. or after 60 days storage at 23° C.
Type:
Grant
Filed:
July 5, 2017
Date of Patent:
July 20, 2021
Assignee:
Kemira Oyj
Inventors:
Asko Karppi, Matti Hietaniemi, Martina Halinen, Salla Timperi, Vladimir Grigoriev, Mikko Virtanen