Abstract: Disclosed herein are methods for live-cell imaging, compositions for performing the live cell imaging, and methods for making the composition. The method may comprise contacting a cell with an effective amount of a catenane, irradiating the cell, and detecting exciplex emission from the catenane within the cell. The catenane may comprise two mechanically interlocked macrocycles, each of the two macrocycles comprise an aromatic fluorophore subunit, and the aromatic fluorophores are arranged in a face-to-face [? . . . ?] stack allowing for the exciplex emission.

Abstract: Provided herein are rigid macrocycles comprising a poly(peri-naphthalene) diimide (PPNDI) submit and a second diimide subunit having both high photoluminescent and electron accumulation activities. Also provided herein are methods of preparation of the rigid macrocycles and methods of using the same.

Abstract: Described herein are cyclophanes, compositions, and methods for live cell imaging. The cyclophanes comprise an ordered, cyclic arrangement of a chromophore, a first linker unit, a molecular strut, and a second linker unit. The compositions are capable of being taking up by cells and resist photobleaching under live-cell imaging conditions.

Abstract: Disclosed herein are lithiated cyclodextrin metal organic frameworks and method of making and using the same. A metal organic framework comprising a coordinated network of repeating units extending in three dimensions, wherein the repeating unit comprises a cyclodextrin, a first coordinating metal cation, and a second coordinating metal cation.

Abstract: Cationic radial catenane comprising a central cationic ring and two or more radial cationic rings mechanically interlocked central cationic ring and methods for making the same are disclosed herein.

Abstract: Disclosed herein are crystalline compositions comprising tessellated rigid triangular macrocycles in a two-dimensional plane and methods of making the same.

Abstract: Described herein are double-strand chain compositions suitable for use in the preparation of proton conductive membranes. The double-strand chains comprise a plurality of constitutional units joined to each other through two atoms on one side of the constitutional unit and two atoms on the other side of the constitutional unit. Constitutional units comprise a dibenzo-crown ether macrocycle fused with a bicyclic aliphatic linker. Polymers, membranes, and fuel cells comprising the double-strand chain are also described herein.

Abstract: Disclosed herein is a mixed-valence crystal superstructure assembled from a 2:1 host-guest inclusion complex. The complex comprises an aromatic guest encircled by two macrocycles, wherein the complex has an empirical charge greater than 0 and less than 1. Methods of preparing the compositions described herein are also disclosed.

Abstract: A method for fabricating an (Al,Ga,In,B)N or III-nitride semiconductor device, including performing a growth of III-nitride or (Al,Ga,In,B)N material including a p-n junction with an active region and using metal-organic chemical vapor deposition (MOCVD) or chemical vapor deposition; and performing a subsequent regrowth of n-type (Al,Ga,In,B)N or III-nitride material using MOCVD or chemical vapor deposition while utilizing a pulsed delta n-type doping scheme to realize an abrupt, smoother surface of the n-type material and a higher carrier concentration in the n-type material. In another example, the method comprises forming a mesa having a top surface; and activating magnesium in the p-type GaN of the (Al,Ga,In,B)N material through openings in the top surface that expose the p-type GaN's surface. The openings are formed before or after the subsequent regrowth of the tunnel junction.

Abstract: Provided herein are rigid macrocycles comprising a first redox-active subunit and a second redox-active subunit, wherein the first redox-active unit and the second redox-active unit are different subunits. Also provided herein are methods of preparation of the rigid macrocycles and use thereof, for example, in the first of energy generation and storage.

Abstract: A method for fabricating an (Al,Ga,In,B)N or III-nitride semiconductor device, including performing a growth of III-nitride or (Al,Ga,In,B)N material including a p-n junction with an active region and using metal-organic chemical vapor deposition (MOCVD) or chemical vapor deposition; and performing a subsequent regrowth of n-type (Al,Ga,In,B)N or III-nitride material using MOCVD or chemical vapor deposition while utilizing a pulsed delta n-type doping scheme to realize an abrupt, smoother surface of the n-type material and a higher carrier concentration in the n-type material. In another example, the method comprises forming a mesa having a top surface; and activating magnesium in the p-type GaN of the (Al,Ga,In,B)N material through openings in the top surface that expose the p-type GaN's surface. The openings are formed before or after the subsequent regrowth of the tunnel junction.

Abstract: Provided herein are substituted haloimidazole crystals, the substituted haloimidazole crystal comprising a substituted haloimidazole compound wherein the substituents are selected from the group consisting of hydrogen, an alkyl, and a halogen. The substituted haloimidazole crystals may further comprise second substituted haloimidazole. The substituted haloimidazole crystals may be piezoelectric, ferroelectric, flexible, or any combination thereof. Also provided herein are methods for preparing substituted haloimidazole crystals.

Abstract: The invention provides a method and system for automatically detecting semantic errors in a text. In order to detect the semantic errors in the text, the method generates a first set of features and a second set of features corresponding to each word in the text. A first set of features corresponds to statistical features of a word and a second set of features for a word corresponds to the features generated for a plurality of words surrounding the word in the text using matrix factorization techniques. The method, then, combines a first set of features and a second set of features to generate a third set of features corresponding to each word in the text. Thereafter, the method utilizes an Artificial Neural Network (ANN) model to detect semantic validity of each word based on a corresponding third set of features.

Abstract: Provided herein are rigid macrocycles comprising a poly(peri-naphthalene) diimide (PPNDI) submit and a second diimide subunit having both high photoluminescent and electron accumulation activities. Also provided herein are methods of preparation of the rigid macrocycles and methods of using the same.

Abstract: A 3D structure of the graphite-titanium-nanocomposite complex and a method of preparing the graphite-titanium-nanocomposite complex are disclosed. The Graphite-titanium-nanocomposite complex includes a metal core associated with the two phases, amine functionalized graphite, and amine functionalized titanium. The method of preparation includes amine functionalizing of graphite and titanium with coupling agents to produce amine functionalized titanium and graphite, further mixing with a metal ion solution for synthesizing an ion complex. Trisodium citrate solution and sodium borohydride solution is added to the ion complex to prepare a 3D structure of the graphite-titanium-nanocomposite complex, employed as a catalyst.

Abstract: Disclosed herein are crystalline compositions comprising tessellated rigid triangular macrocycles in a two-dimensional plane and methods of making the same.

Abstract: The invention provides a method and apparatus for purifying water. The apparatus includes a water still for receiving water and a hot air maintained in a heat-exchanging relationship to obtain a hot water and a cold air. The apparatus also includes one or more water purification units configured to receive the hot water from the water still in which the hot water is further heated using thermal energy received from one or more thermal energy sources to obtain steam and waste matter. A water purification unit of the one or more water purification units includes a waste matter remover for removing the waste matter from the water purification unit. The water still includes a heat-exchanging unit configured to receive the steam from the one or more water purification units. The steam received at the heat-exchanging unit is condensed to obtain purified water within the heat-exchanging unit using the cold air.

Abstract: The invention provides a Low-voltage Differential Signaling (LVDS) receiver circuit that comprises a folded-cascode operational transconductance amplifier (OTA) that includes a pair of input branches and a pair of output branches. The pair of input branches of the folded-cascode OTA includes a p-channel metal-oxide semiconductor (PMOS) input transistor pair connected to a first supply voltage domain. The pair of output branches includes an output circuit connected to a second supply voltage domain. The LVDS receiver circuit further includes a common-mode feedback circuit connected to the pair of output branches of the folded-cascode OTA that controls the second supply voltage domain. The LVDS receiver circuit further includes a regenerative buffer circuit connected to the pair of output branches of the folded-cascode OTA and an output generated from the pair of output branches of the folded-cascode OTA directly operates the regenerative buffer circuit to produce a distortion-free output signal.

Abstract: A III-nitride tunnel junction with a modified p-n interface, wherein the modified p-n interface includes a delta-doped layer to reduce tunneling resistance. The delta-doped layer may be doped using donor atoms comprised of Oxygen (O), Germanium (Ge) or Silicon (Si); acceptor atoms comprised of Magnesium (Mg) or Zinc (Zn); or impurities comprised of Iron (Fe) or Carbon (C).

Abstract: A laboratory equipment having an inlet and outlet tube for gas to enter and exit using specific shaped tubes with multi-outlet apertures in form of a network to allow the gas to enter the drying chamber to dry the material. The specific shaped tubes are in crescent shape and cross each other to have maximum surface area exposure to the drying chamber and effectively contact the material that is being dried. A gas inlet valve and outlet valve control the flow, pressure and temperature of the gas that is being used for drying the material to make nano material. A method of using the laboratory equipment with special gas inlet tubes is used for drying the material in form a slurry to make dry nano material.